Safety data sheet according to 1907/2006/EC, Article 31

Transcription

1 Page 1/7 1 Identification of the substance/mixture and of the company/undertaking Product identifier Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the mixture Stamp pad ink Details of the supplier of the safety data sheet Manufacturer/Supplier: Noris-Color GmbH Ziegelhüttener Str. 1 D KULMBACH GERMANY Phone: / Fax: / info@noris-color.de Further information obtainable from: Laboratory/Product safety Emergency telephone number: See Manufacturer/Supplier Australia / New Zealand Supplier: Pelikan Artline Pty Ltd 2 Coronation Ave, Kings Park, NSW 2148 AUSTRALIA Phone: (02) Fax: (02) custsupp@pelikanartline.com.au 2 Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 3 H226 Flammable liquid and vapour. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. Label elements Labelling according to Regulation (EC) No 1272/2008 The product is classified and labelled according to the CLP regulation. Hazard pictograms GHS02 Signal word Warning Hazard statements H226 Flammable liquid and vapour. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P241 Use explosion-proof electrical/ventilating/lighting/equipment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P240 Ground/bond container and receiving equipment. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin P501 Other hazards Results of PBT and vpvb assessment PBT: Not applicable. with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations. (Contd. on page 2)

2 Page 2/7 vpvb: Not applicable. (Contd. of page 1) 3 Composition/information on ingredients Chemical characterisation: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: EINECS: CAS: EINECS: (2-methoxymethylethoxy)propanol substance with a Community workplace exposure limit 1-methoxy-2-propanol Flam. Liq. 3, H226; STOT SE 3, H336 CAS: EC number: C.I. Solvent Blue 70 Aquatic Chronic 3, H412 CAS: Basic Blue 7 EINECS: Acute Tox. 3, H301; Eye Dam. 1, H318; Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Additional information: For the wording of the listed risk phrases refer to section % 10-25% 2,5% 2,5% 4 First aid measures Description of first aid measures After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Rinse out mouth and then drink plenty of water. If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water with full jet Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: No special measures required. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Do not flush with water or aqueous cleansing agents (Contd. on page 3)

3 Page 3/7 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. (Contd. of page 2) 7 Handling and storage Handling: Precautions for safe handling No special precautions are necessary if used correctly. Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep container tightly sealed. Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: (2-methoxymethylethoxy)propanol WEL Long-term value: 308 mg/m³, 50 ppm Sk methoxy-2-propanol WEL Short-term value: 560 mg/m³, 150 ppm Long-term value: 375 mg/m³, 100 ppm Sk Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Wash hands before breaks and at the end of work. Respiratory protection: Not necessary if room is well-ventilated. Protection of hands: The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. (Contd. on page 4)

4 Page 4/7 Eye protection: (Contd. of page 3) Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: According to product specification Odour: Characteristic Odour threshold: Not determined. ph-value: Not determined. Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 120 C Flash point: 54 C Flammability (solid, gaseous): Not applicable. Ignition temperature: 270 C Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible. However, this can only occur when the temperature is very high and not under normal circumstances. The following explosion limits contribute to single substances in this mixture that can produce dangerous vapours and not to the mixture. Explosion limits: Lower: 1,1 Vol % Upper: 20,0 Vol % Vapour pressure at 20 C: 12 hpa Density at 20 C: 1,01325 g/cm³ Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Not miscible or difficult to mix. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Kinematic: Not determined. Not determined. Solvent content: Organic solvents: 75,3 % VOC (EC) % Solids content: 24,7 % (Contd. on page 5)

5 Page 5/7 Other information No further relevant information available. (Contd. of page 4) 10 Stability and reactivity Reactivity No further relevant information available. Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. 11 Toxicological information Information on toxicological effects Acute toxicity Based on available data, the classification criteria are not met. Primary irritant effect: Skin corrosion/irritation Based on available data, the classification criteria are not met. Serious eye damage/irritation Based on available data, the classification criteria are not met. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met. Carcinogenicity Based on available data, the classification criteria are not met. Reproductive toxicity Based on available data, the classification criteria are not met. STOT-single exposure Based on available data, the classification criteria are not met. STOT-repeated exposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met. 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Ecotoxical effects: Remark: Harmful to fish Additional ecological information: General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Harmful to aquatic organisms Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. (Contd. on page 6)

6 Page 6/7 Waste disposal key: Recommendation: (waste containing organic solvents) Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. (Contd. of page 5) 14 Transport information UN-Number ADR, IMDG, IATA UN1263 UN proper shipping name ADR 1263 PAINT IMDG, IATA PAINT Transport hazard class(es) ADR, IMDG, IATA Class 3 Flammable liquids. Label 3 Packing group ADR, IMDG, IATA III Environmental hazards: Marine pollutant: No Special precautions for user Warning: Flammable liquids. Danger code (Kemler): 30 EMS Number: F-E,S-E Transport in bulk according to Annex II of Marpol and the IBC Code Transport/Additional information: ADR Limited quantities (LQ) 5L Transport category 3 Tunnel restriction code D/E Not applicable. UN "Model Regulation": UN1263, PAINT, 3, III 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Directive 2012/18/EU Named dangerous substances - ANNEX I None of the ingredients is listed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H226 Flammable liquid and vapour. (Contd. on page 7)

7 Page 7/7 H301 Toxic if swallowed. H318 Causes serious eye damage. H336 May cause drowsiness or dizziness. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. (Contd. of page 6) Department issuing MSDS: Product safety Contact: Hr. Wendland Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonised System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) PBT: Persistent, Bioaccumulative and Toxic vpvb: very Persistent and very Bioaccumulative Flam. Liq. 3: Flammable liquids, Hazard Category 3 Acute Tox. 3: Acute toxicity, Hazard Category 3 Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1 STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1 Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1 Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3