Issue Date: 21-Oct-2015 Revision Date: 28-Oct-2015 Version 1 1. IDENTIFICATION 2. HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Issue Date: 21-Oct-2015 Version 1 1. IDENTIFICATION Product Identifier Product Name Other means of identification SDS # Oxybrite EMS-022 Recommended use of the chemical and restrictions on use Recommended Use. Details of the supplier of the safety data sheet Supplier Address EMS Detergent Services 390 Herky Street, Suite 4W North Liberty, IA Emergency Telephone Number Company Phone Number (319) Emergency Telephone (24 hr) Chemtrec (North America) (International) Classification 2. HAZARDS IDENTIFICATION Acute toxicity - Oral Category 4 Serious eye damage/eye irritation Category 2 Oxidizing Solids Category 2 Signal Word Warning Hazard Statements Harmful if swallowed Causes serious eye irritation May intensify fire; oxidizer Page 1 / 7

2 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Keep away from heat/sparks/open flames/hot surfaces. No smoking Keep/Store away from clothing/incompatible/combustible materials Take any precaution to avoid mixing with combustibles/incompatible Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Sodium percarbonate Sodium carbonate **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** First Aid Measures 4. FIRST-AID MEASURES Eye Contact Skin Contact Inhalation Ingestion IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops or persists. Remove exposed individual(s) to fresh air for 20 minutes. Consult a physician / poison center if individual's condition declines or if symptoms persist. Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious person. Call a poison center or doctor/physician if you feel unwell. Most important symptoms and effects Symptoms Causes serious eye irritation. Harmful if swallowed. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Page 2 / 7

3 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media. Specific Hazards Arising from the Chemical May intensify fire; oxidizer. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Environmental Precautions Wear protective clothing as described in Section 8 of this safety data sheet. See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Methods for Clean-Up Prevent further leakage or spillage if safe to do so. Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Wear eye/face protection. Conditions for safe storage, including any incompatibilities Storage Conditions Incompatible Materials Keep containers tightly closed in a dry, cool and well-ventilated place. Strong oxidizers. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Appropriate engineering controls Engineering Controls Ensure that eyewash stations and safety showers are close to the workstation location. Individual protection measures, such as personal protective equipment Page 3 / 7

4 Eye/Face Protection Chemical safety glasses or goggles. Refer to 29 CFR for eye and face protection regulations. Skin and Body Protection Respiratory Protection Wear protective gloves and protective clothing. Refer to 29 CFR for appropriate skin and body protection. If exposure limits are exceeded use a NIOSH approved respirator. Refer to 29 CFR for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Appearance Odor Color Odor Threshold Property Values Remarks Method ph Melting Point/Freezing Point Boiling Point/Boiling Range Flash Point Evaporation Rate Flammability (Solid, Gas) Upper Flammability Limits Lower Flammability Limit Vapor Pressure Vapor Density Specific Gravity Water Solubility Solubility in other solvents Partition Coefficient Auto-ignition Temperature Decomposition Temperature Kinematic Viscosity Dynamic Viscosity Explosive Properties Oxidizing Properties Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible Materials Strong oxidizers. Hazardous Decomposition Products None known based on information supplied. 10. STABILITY AND REACTIVITY Page 4 / 7

5 Information on likely routes of exposure Product Information 11. TOXICOLOGICAL INFORMATION Eye Contact Skin Contact Inhalation Ingestion Causes serious eye irritation. Avoid contact with skin and clothing. Avoid inhalation. Harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Sodium percarbonate = 1034 mg/kg ( Rat ) Sodium carbonate = 4090 mg/kg ( Rat ) - = 2300 mg/m 3 ( Rat ) 2 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Ecotoxicity Toxic to aquatic life with long lasting effects. Component Information 12. ECOLOGICAL INFORMATION Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Sodium percarbonate 70: 240 h Chlorella 70.7: 96 h Pimephales emersonii mg/l EC50 promelas mg/l LC50 static Sodium carbonate 242: 120 h Nitzschia mg/l 300: 96 h Lepomis EC50 macrochirus mg/l LC50 static : 96 h Pimephales promelas mg/l LC50 static Crustacea 4.9: 48 h Daphnia pulex mg/l EC50 265: 48 h Daphnia magna mg/l EC50 Persistence/Degradability. Page 5 / 7

6 Bioaccumulation. Mobility Other Adverse Effects Waste Treatment Methods 13. DISPOSAL CONSIDERATIONS Disposal of Wastes Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status This product contains one or more substances that are listed with the State of California as a hazardous waste Chemical Name Sodium percarbonate Sodium carbonate California Hazardous Waste Status Ignitable Corrosive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Proper Shipping Name Sodium carbonate peroxyhydrate Hazard Class 5.1 Packing Group II IATA Proper Shipping Name Sodium carbonate peroxyhydrate Hazard Class 5.1 Packing Group II IMDG Proper Shipping Name Sodium carbonate peroxyhydrate Hazard Class 5.1 Packing Group II Marine Pollutant This material may meet the definition of a marine pollutant International Inventories 15. REGULATORY INFORMATION Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Sodium percarbonate Present X Present Present X Present X X Sodium carbonate Present X Present Present X Present X X Page 6 / 7

7 Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations 16. OTHER INFORMATION NFPA HMIS Health Hazards Health Hazards Flammability Flammability Instability Physical Hazards Special Hazards Personal Protection Issue Date: Revision Date: Revision Note: 21-Oct Oct-2015 New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7