: ZERO All-in-One Dishwasher Tablets Citrus Nordic Swan

Transcription

1 ZERO All-in-One Dishwasher Tablets Citrus Nordic Swan Date of issue: 2/03/2018 Revision date: 2/03/2018 Supersedes: 8/01/2018 Version: 1.2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Product code Type of product : Mixture : : DW30127WAW : Detergent 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Use of the substance/mixture Function or use category : Consumer use : Machine dishwashing detergent : Cleaning/washing agents and additives Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier ECOVER CO-ORDINATION CENTER Steenovenstraat 1A 2390 Malle - Belgium T +32 (0) F +32 (0) sds@peopleagainstdirty.com 1.4. Emergency telephone number Emergency number : customer careline UK ; customer careline DE ; customer careline BE SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Serious eye damage/eye irritation, Category 2 Full text of H statements : see section 16 H319 Adverse physicochemical, human health and environmental effects Causes serious eye irritation Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) : Signal word (CLP) Hazard statements (CLP) Precautionary statements (CLP) EUH-statements GHS07 : Warning : H319 - Causes serious eye irritation. : P102 - Keep out of reach of children. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P101 - If medical advice is needed, have product container or label at hand. : EUH208 - Contains Subtilisin( ). May produce an allergic reaction Other hazards 2/03/2018 EN (English) SDS Ref.: ECOVER212 1/7

2 SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Sodium carbonate (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) Sodium percarbonate (CAS-No.) (EC-No.) (REACH-no) Eye Irrit. 2, H Ox. Sol. 2, H272 Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Fatty alcohol alkoxylate (CAS-No.) Eye Irrit. 2, H319 Aquatic Chronic 3, H412 Silicic acid, sodium salt (CAS-No.) (EC-No.) Subtilisin (CAS-No.) (EC-No.) (EC Index-No.) (REACH-no) Full text of H-statements: see section 16 1-<3 Skin Corr. 1B, H314 Eye Dam. 1, H318 STOT SE 3, H335 Met. Corr. 1, H290 0,1-1 STOT SE 3, H335 Skin Irrit. 2, H315 Eye Dam. 1, H318 Resp. Sens. 1, H334 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center or a doctor if you feel unwell Most important symptoms and effects, both acute and delayed Symptoms/effects after eye contact : Eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of fire : carbon dioxide (CO2), powder, alcohol-resistant foam, water spray. Dry powder. Foam. : None known Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection" Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Mechanically recover the product. 2/03/2018 EN (English) SDS Ref.: ECOVER212 2/7

3 Other information : Dispose of materials or solid residues at an authorized site Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 1,2,3-Propanetriol(glycerin) ( ) : Store in a well-ventilated place. Keep cool. United Kingdom Local name Glycerol United Kingdom WEL TWA (mg/m³) 10 mg/m³ mist 8.2. Exposure controls Personal protective equipment: Avoid all contact with skin, eyes, or clothing. Avoid all unnecessary exposure. Accidental release of the contents: Gloves, Safety glasses. Hand protection: Type Material Permeation Thickness (mm) Penetration Standard Nitrile rubber (NBR), Natural rubber, Neoprene rubber (HNBR), Butyl rubber 6 (> 480 minutes) 0.5 mm EN 374 Eye protection: Wear eye/face protection. Chemical goggles or safety glasses. EN 166 Skin and body protection: No special clothing/skin protection equipment is recommended under normal conditions of use Respiratory protection: No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation Environmental exposure controls: Avoid release to the environment. Other information: Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : tablet. Colour : white. Odour : lemon. Odour threshold ph ph solution : 10,2-11,2 Relative evaporation rate (butylacetate=1) Melting point Freezing point : Boiling point 2/03/2018 EN (English) SDS Ref.: ECOVER212 3/7

4 Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : : : Non flammable. : : Soluble in water. : : 9.2. Other information VOC content : 0 % SECTION 10: Stability and reactivity Reactivity Even when properly stored, the sodium carbonate peroxide will lose his activity. Therefore it is recommended to consume the product within a year Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Strong bases. Strong acids. Strong oxidizing agents. Strong reducing agents Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (inhalation) Sodium carbonate ( ) LD50 oral LD50 dermal LC50 inhalation rat (Dust/Mist - mg/l/4h) Sodium percarbonate ( ) LD50 oral LD50 dermal Subtilisin ( ) LD50 oral Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity 4090 mg/kg bodyweight > 2000 mg/kg bodyweight 2300 mg/l 1034 mg/kg bodyweight > 2000 mg/kg bodyweight 1800 mg/kg bodyweight : Causes serious eye irritation. STOT-single exposure 2/03/2018 EN (English) SDS Ref.: ECOVER212 4/7

5 STOT-repeated exposure Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general Acute aquatic toxicity Chronic aquatic toxicity Sodium carbonate ( ) LC50 fish 1 EC50 other aquatic organisms 1 Sodium percarbonate ( ) LC50 fish 1 EC50 other aquatic organisms 1 Subtilisin ( ) LC50 fish 1 EC50 other aquatic organisms 1 : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 300 mg/l 265 mg/l waterflea > 70 mg/l 4,9 mg/l waterflea 8,2 mg/l 0,868 mg/l waterflea Persistence and degradability Persistence and degradability Bioaccumulative potential Bioaccumulative potential Sodium carbonate ( ) Log Pow -6, Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN This product doesn't contain any persistent substances. The surface active components used in this product fulfill all of the biodegradability requirements of EC regulation 648/2004 (Detergents Regulation). The surface active components used in this product are anaerobically biodegradable. This product does not contain any bioaccumulating substances. : Dispose of contents/container in accordance with licensed collector s sorting instructions UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) : : : : : : : : : : 2/03/2018 EN (English) SDS Ref.: ECOVER212 5/7

6 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : IMDG Transport hazard class(es) (IMDG) : IATA Transport hazard class(es) (IATA) : ADN Transport hazard class(es) (ADN) : RID Transport hazard class(es) (RID) Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) Environmental hazards Dangerous for the environment Marine pollutant Other information : : : : : : : No : No : No supplementary information available Special precautions for user - Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport Transport in bulk according to Annex II of Marpol and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 0 % Detergent Regulation : Labelling of contents: Component oxygen-based bleaching agents 5-15% non-ionic surfactants <5% enzymes % 2/03/2018 EN (English) SDS Ref.: ECOVER212 6/7

7 National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Indication of changes: Section Changed item Change Comments 3.2 Composition/information on ingredients Modified Full text of H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Met. Corr. 1 Corrosive to metals, Category 1 Ox. Sol. 2 Oxidising Solids, Category 2 Resp. Sens. 1 Respiratory sensitisation, Category 1 Skin Corr. 1B Skin corrosion/irritation, Category 1B Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 H272 H290 H302 H314 H315 H318 H319 H334 H335 H412 EUH208 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation May intensify fire; oxidiser. May be corrosive to metals. Harmful if swallowed. Causes severe skin burns and eye damage. Causes skin irritation. Causes serious eye damage. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Harmful to aquatic life with long lasting effects. Contains Subtilisin( ). May produce an allergic reaction. Classification and procedure used to derive the classification for mixtures according to Regulation (EC) 1272/2008 [CLP]: Eye Irrit. 2 H319 Calculation method Concentration limits SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 2/03/2018 EN (English) SDS Ref.: ECOVER212 7/7