TEST SPECIFICATIONS RESULTS. i.e 0.42 TO 1.2 mm i.e 0.42 TO 1.2 mm

Transcription

1 THERMAX LIMITED, VILLAGE PAUDH,POST MAJGAON(VIA PATALGANGA) TALUKA KHALAPUR, DISTRICT RAIGAD INDIA TEL : (02192) 76010/36/37/39/41/42 FAX : (02192) CHEMICAL DIVISION Certified Report DATE : SAMPLE OF CERTIFICATE OF ANALYSIS CUSTOMER ORDER NUMBER NUMCHOKE MARKETING NOT APPLICABLE PRODUCT TULSION A-722 MP BATCH NO SAMPLE COA QUANTITY - TEST SPECIFICATIONS RESULTS TOTAL EXCHANGE CAPACITY (MEQ/ML) 1.0 MEQ/ML MIN 1.04 MEQ/ML WATER RETENTION (%) 60 +/-3 % % SCREEN DISTRIBUTION 16 TO 40 US MESH 16 TO 40 US MESH i.e 0.42 TO 1.2 mm i.e 0.42 TO 1.2 mm WE CERTIFY THAT THIS SHIPMENT CONSIST OF MATERIAL HAVING THE ANALYTICAL VALUE SHOWN ABOVE. Q.A.INCHARGE THERMAX LIMITED HEAD OFFICE : THERMAX LIMITED 97-E,BHOSARI INDUSTRIAL AREA,PUNE ,INDIA. REGD OFFICE : D 13, MIDC INDUSTRIAL AREA, CHINCHWAD, PUNE , INDIA.

2 TULSION A-722 MP STYRENIC MACROPOROUS STRONG BASE ANION EXCHANGE RESIN FOR SUGAR DECOLOURIZATION AND ORGANIC REMOVAL. Tulsion A-722MP is a polystyrenic Macroporous strong base (Type-I) anion exchange resin, with matrix containing quaternary ammonium groups, supplied as moist spherical beads in the Chloride form. Tulsion A-722MP has excellent physical characteristics due to its macro porous nature, is used for de-colorization of sugars solutions, where the concentrations of the coloring bodies are relatively high. This resin is easily regenerable by using alkaline brine solution. This resin is generally used in combination with Tulsion A-30MP acrylic strong base for the removal of residual color from the treated sugar solution. The advantages of this resin are exceptional physical and chemical stability leading to long life, high operating capacity and low rinse requirements. It is suited for use in a wide range of ph and elevated temperature conditions.

3 TYPICAL CHARACTERISTICS: Type : Macroporous Strong base anion exchange resin Matrix structure : Polystyrene Copolymer Functional group : Quaternary ammonium Type I Physical form : Moist Spherical Beads Ionic form : Chloride Screen Size USS (wet) : 16 to 50 Particle size (95% min) : 0.4 to 1.2 mm Effective size (mm) : 0.55 to 0.65 Total Exchange Capacity : 1.0 meq/ ml (min). Moisture content : 60 3% ph range : 0 to 14 Solubility : Insoluble in all common solvents Backwash settled density : 670 to 720 g/l) Temperature stability (max) : 80 C TYPICAL OPERATING CONDITIONS: Operating Temperature flow rate Typical Operating Service flow rates Regenerant Used Regeneration Concentration Regeneration level Regeneration flow rate Regeneration and rinse temperature Slow Rinse with DM water Fast Rinse with DM water Sweetening on volume Sweetening off volume C Service 8 to 10 BV Max 2-5 BV/hr 10% Alkaline brine 10% NaCl + 2 % NaOH g / L BV/hr C At regeneration flow rate with 5 BV of DM water or till the conductivity at the outlet is 20 to 25 us / cm At service flow rate with 2 BV DM water or till the conductivity at the outlet is 5 to 6 us / cm. 1.5 to 2 BV (approx) 1.5 to 2 BV (approx)

4 BACKWASH FLOW RATE : M 3 /hr/m 2 Vs % of bed expansion Flow-rate: m/hr Regeneration Temp C ----> SERVICE FLOW RATE: M 3 /hr/ M 2 Vs Pressure loss M H 2 O/ M resin bed depth Flow-rate: Regeneration m/hr Temp C ----> TESTING : The sampling and testing of ion exchange resins is done as per standard testing procedures, namely ASTMD-2187 and IS-7330, PACKING : Super Sack 1000 lit Super Sack 35 cft MS drums 180 lit. Fiber Drums 7 cft HDPE lines Bags 25 lit. HDPE Lined Bags 1 cft For Handling, Safety and Storage requirements please refer to the individual Material Safety Data Sheets available at our offices. The data included herein are based on test information obtained by Thermax Limited. These date are believed to be reliable, but do not imply any warranty or performance guarantee. Tolerances for characteristics are per BIS/ASTM. We recommend that the user should determine the performance of the product by testing on his own processing equipment. For further information, please contact: THERMAX LIMITED CHEMICAL DIVISION An ISO 9001 Company 97-E, GENERAL BLOCK, M.I.D.C. BHOSARI, PUNE , INDIA TEL. : +91(20) , FAX : +91(20) resins@thermaxindia.com Website : USA Office : THERMAX INC Grand River Avenue, Novi, Michigan U.S.A. Tel : Fax : In view of our constant endeavour to improve the quality of our products, we reserve the right to change their specifications without prior

5 Thermax Limited Chemical Division MATERIAL SAFETY DATA SHEET 1. Chemical Product & Company Identification Trade Name Brand Name & Code A-722 MP Tulsion Validation Date Company Identification M/s. Thermax Limited, Chemical Division, 97-E, General Block, MIDC Industrial Area, Bhosari, Pune [ India ] 24 hour emergency assistance , Fax Composition / Information on ingredients Component CAS % by Wt. Exposure guidelines Styrene DVB copolymer with Quaternary amine groups None established Water None established 3. Hazards Identification Potential Health Effects Skin Eyes Inhalation Ingestion Physical / Chemical Effects Prolonged or repeated exposure not likely to cause any significant skin irritation. Skin adsorption is unlikely due to physical properties. Solid or dust may cause irritation corneal injury due to mechanical action. Vapors are unlikely due to physical properties. No adverse effects are anticipated from inhalation. Single dose oral LD50 has not been determined. Single dose oral toxicity is believed to be very low. No hazardous anticipated from ingestion incidental to industrial exposure. These effects have not been studied thoroughly. 4. First Aid Measures Skin Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Eyes Inhalation Ingestion Flush eyes thoroughly with water for at least 15 minutes occasionally lifting upper and lower eyelids. Get medical aid from preferably an ophthalmologist. If inhaled remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. If swallowed, wash out mouth with water provided person is conscious. Call a physician. Page 2 of 4

6 Thermax Limited Chemical Division 5. Fire fighting Measures Flash point Auto ignition temperature 427 Deg. C [ 800 Deg. F ] LEL UEL Fire Extinguishing Media Basic Fire fighting Procedure Unusual Fire & Explosion Hazards Water spray, Carbon dioxide, Dry chemical powder or appropriate foam. Keep people away. Isolate fire area and deny unnecessary entry. Cool surroundings with water to localize fire zone. Wear MSHA / NIOSH approved, pressure demand self contained breathing apparatus / equipment. Emits toxic fumes under fire conditions. 6. Accidental Release Measures Personnel precautions Environmental precautions Spilled material may cause a slipping hazard. Use appropriate safety equipment as indicated in point no. 8, Exposure controls / personnel protection. Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See point no. 12, Ecological information. 7. Handling and Storage Handling precautions Storage conditions Avoid contact with skin / eyes. Avoid prolonged or repeated exposure. Wash thoroughly after handling. Store in a cool enclosed place. Avoid repeated freeze thaw cycles. 8. Exposure controls / Personnel protection Eye protection Use safety eyeglasses or chemical safety goggles as described by OSHA s eye & face protection regulations in 29 CFR or European standard EN 166. Skin & body protection Respiratory protection Wear appropriate gloves and clean body covering clothing to prevent skin exposure. No respiratory protection is needed but whenever necessary always use a NIOSH or European standard EN 149 approved respirator when necessary. Page 3 of 4

7 Thermax Limited Chemical Division 9. Physical and chemical properties Physical state Appearance Odor Moist Yellow colored spherical beads Amine Like Boiling point Melting point Freezing point Vapor density [ Air = 1 ] Vapor 20 0 C Solubility in 30 0 C Insoluble Specific gravity [ H2O = 1 ] 1.1 to 1.2 Evaporation rate [ B. A. = 1 ] % Volatiles 55-65% 10. Stability and reactivity Stability / incompatibility Materials to avoid Stable under recommended storage conditions, see point no. 7, Storage conditions. Product can decompose at elevated temperatures, so avoid temperatures above C / F. Avoid contact with strong oxidizing agents such as Nitric acid. Before using strong oxidizing agents consult sources knowledgeable in handling such materials. The severity of the reaction with oxidizing materials can vary from slight degradation to an explosive reaction. Hazardous decomposition products Hazardous decomposition products depend upon temperature, air supply and the presence of other materials. Hazardous decomposition products may include and not limited to Carbon monoxide, Carbon dioxide, aromatic compounds, Hydrocarbons, Organic sulfonates and sulfur oxides. Hazardous polymerization will not occur. 11. Toxicological information No data available for this material. The information shown below is based on profiles of compositionally similar materials. Acute Skin Eye No relevant information found. Data not available for this material. Acute dermal toxicity value for LD50 rabbit > 5000 mg / Kg based on data for similar compositions. No relevant information found. Ingestion Data not available for this material. Acute oral toxicity value LD50 rat > 5000 mg / Kg based on data for similar compositions. 12. Ecological information Ecotoxicity & bioaccumulation Ecotoxicity is not expected to be acutely toxic, but pellets may mechanically cause adverse effects if ingested by waterfowl or aquatic life. No bioconcentration of polymeric component is expected because of it s high molecular weight. Environmental mobility Environmental degradability In the terrestrial environment, material is expected to remain in the soil. In the aquatic environment, material will sink and remain in the sediment. Based largely / completely on information for copolymer. Surface photodegradation is expected with exposure to sunlight. No appreciable biodegradation is expected. Page 4 of 4

8 Thermax Limited Chemical Division 13. Disposal considerations For used / uncontaminated product, the preferred options include incineration, landfill etc. Used material which has been contaminated with heavy metals or radioactive metals or toxic substances must be treated as per local state and federal regulations. THE THERMAX LTD, CHEMICAL DIVISION HAS NO CONTROL, OVER THE MANAGEMENT PRACTISES OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN IT S INTENDED CONDITION AS DISCRIBED IN POINT NO. 2 OF THIS MSDS. 14. Transport information Hazard Label Non hazardous ADR Non hazardous for Road transport IMDG Non hazardous for Sea transport IATA Non hazardous for Air transport 15. Regulatory information The information shown below is based on profiles of compositionally similar materials. Hazard category Indication of danger Xi Irritant Risk Phrase Safety Phrase 36, Irritating to eyes , In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. 16. Other information If the material gets dried, while rewetting, resin gets swelled Disclaimer: This information relates specifically to the product designated and may not be valid for the product when used in combination with any other materials or products or in a particular process. The information is, to the best of our knowledge and belief, accurate and reliable as of the date compiled. However, no representation, warranty or guarantee is made as to it s accuracy, reliability or completeness. It is the user s responsibility to review this information, satisfy itself as to it s suitability and completeness and pass on the information to it s employees or customers in accordance with applicable federal, state or local hazard communications requirement. We do not accept responsibility for any loss or damage which may occur from the use of this information. Brand name is trade mark of Thermax limited, Chemical Division, Pune, India REV No. : 000 Date : Page 5 of 4