Bayer Environmental Science
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1 Revision Date: 08/15/2006 SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION Product Name MSDS Number EPA Registration No Product Use For control of nematodes. Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC USA For MEDICAL, TRANSPORTATION or other EMERGENCY call: (24 hours/day) For Product Information call: SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Average % by Weight Fenamiphos SECTION 3. HAZARDS IDENTIFICATION NOTE: Please refer to Section 11 for detailed toxicological information. Emergency Overview Danger! Poison. Fatal if swallowed. Fatal if absorbed through the skin. Causes irreversible eye damage. May be fatal if inhaled. Do not get in eyes, on skin, or on clothing. Do not breathe vapours or spray mist. Keep away from food and drink. Cholinesterase inhibitor. Physical State Odor Appearance Routes of Exposure Immediate Effects Eye Skin liquid mild sulfur-like amber Eye contact, Skin contact, Skin Absorption, Inhalation, Ingestion Corrosive - causes irreversible eye damage. Do not get in eyes. Fatal if absorbed through the skin. May cause slight irritation. Page 1 of 8 Bayer Environmental Science A Business Group of Bayer CropScience
2 Ingestion Inhalation Medical Conditions Aggravated by Exposure Fatal if swallowed. May be fatal if inhaled. No specific medical conditions are known which may be aggravated by exposure to this product. Any disease, medication or prior exposure which reduces normal cholinesterase activity may increase susceptibility to the toxic effects of the active ingredient. Skin contact may aggravate existing skin disease. SECTION 4. FIRST AID MEASURES General Eye Skin Ingestion Inhalation Notes to Physician Signs and Symptoms Hazards Treatment When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Hold eye open and rinse slowly and gently with water for minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Wash off immediately with plenty of water for at least 15 minutes. Take off contaminated clothing and shoes immediately. Call a physician or poison control center immediately. Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. The following symptoms may occur: nausea salivation lacrimation blurred vision constriction of pupils abdominal pain diarrhoea dizziness sweating vomiting Cholinesterase inhibitor. ANTIDOTE: Administer atropine sulfate in large therapeutic doses. Repeat as necessary to the point of tolerance. The product inhibits cholinesterase resulting Page 2 of 8
3 in stimulation of the central nervous system, the parasympathetic nervous system, and the somatic motor nerves. Do not give morphine. Watch for pulmonary edema, which may develop in serious cases of poisoning even after hours. At first sign of pulmonary edema, the patient should be placed in an oxygen tent and treated symptomatically. SECTION 5. FIRE FIGHTING MEASURES Flash point 64 C / 147 F Suitable Extinguishing Media Fire Fighting Instructions carbon dioxide (CO2), dry chemical, water Keep unnecessary people away, isolate hazard area and deny entry. Dike area to prevent runoff and contamination of water sources. Keep out of smoke. Fight fire from upwind position. Equipment or materials involved in pesticide fires may become contaminated. Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Methods for Cleaning Up Additional Advice Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Remove all sources of ignition. Refer to protective measures listed in sections 7 and 8. Dike area to prevent runoff. Clean up immediately, observing precautions outlines in Section 8. Take up with absorbent material (e.g. sand, diatomaceous earth or a proprietary absorbent material). Place in a container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations. Contaminated soil may have to be removed and disposed. Place contaminated material in appropriate container for disposal. Information regarding waste disposal, see section 13. Do not allow product to contact vegetation. Do not allow product to enter streams, sewers or other waterways. Contact Bayer for further assistance if necessary. SECTION 7. HANDLING AND STORAGE Handling Procedures Storing Procedures Handle and open container in a manner as to prevent spillage. Store in a cool, dry place and in such a manner as to prevent cross Page 3 of 8
4 contamination with other pesticides, fertilizers, food, and feed. Do not freeze. Keep away from heat and sources of ignition. Store in original container and out of the reach of children, preferably in a locked storage area. Work/Hygienic Procedures Handle in accordance with good industrial hygiene and safety practice. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove clothing immediately if pesticide gets inside. Then wash thoroughly and put on clean clothing. SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION General Protection Engineering Controls Eye/Face Protection Hand Protection Body Protection Respiratory Protection Exposure Limits These recommendations provide general guidance for handling this product. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. While developing safe handling procedures, do not overlook the need to clean equipment and piping systems for maintenance and repairs. Waste resulting from these procedures should be handled in accordance with Section 13: Disposal Considerations. Use only with adequate ventilation/personal protection. Chemical resistant goggles must be worn. Wear suitable gloves. Wear long-sleeved shirt and long pants and shoes plus socks. Wear a respirator approved for pesticides by the National Institute for Occupational Safety and Health (NIOSH). This product contains material which are Trade Secret and may have Occupational Exposure Limits. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor amber liquid mild sulfur-like Specific Gravity 1.00 at 20 C Page 4 of 8
5 SECTION 10. STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Incompatibility Hazardous Decomposition Products Stable under normal conditions. Do not freeze. Hydrolyses in alkaline medium. alkalines amines sulfur dioxide SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity data have been bridged from a similar formulation containing a similar percentage of the active ingredient, fenamiphos. The non-acute information pertains to the technical-grade active ingredient. Acute Oral Toxicity male rat: LD50: 24.8 mg/kg female rat: LD50: 10.6 mg/kg Acute Dermal Toxicity male rabbit: LD50: 75.7 mg/kg female rabbit: LD50: 71.5 mg/kg Acute Inhalation Toxicity male rat: LC50: mg/l Exposure time: 4 h female rat: LC50: mg/l Exposure time: 4 h male rat: LC50: mg/l Exposure time: 1 h Extrapolated from the 4 hr LC50. female rat: LC50: mg/l Exposure time: 1 h Extrapolated from the 4 hr LC50. Skin Irritation Eye Irritation Sensitization Chronic Toxicity rabbit: Slight irritation. rabbit: Corrosive irreversible eye irritant. This product is highly toxic and can be readily absorbed through the mucous membranes of the eye. guinea pig: Non-sensitizing. The principal toxicological effect in rats and dogs following long-term dietary Page 5 of 8
6 exposure to fenamiphos was the inhibition of plasma, red blood cell and/or brain cholinesterase activity. Assessment Carcinogenicity Fenamiphos is not carcinogenic based on oncogenicity studies in rats and mice. ACGIH Fenamiphos Group A4 Group A4 NTP IARC Overall evaluation: 2B OSHA None. Reproductive & Developmental Toxicity REPRODUCTION: Fenamiphos is not a primary reproductive toxicant based on a 2-generation reproduction study in rats. Reproductive effects (e.g., reduced pup body weights) observed in high-dosed animals were secondary to maternal toxicity. DEVELOPMENTAL TOXICITY: Fenamiphos is not a developmental toxicant based on developmental toxicity studies in rats and rabbits. Neurotoxicity Mutagenicity Fenamiphos is not neurotoxic based on neurotoxicity studies in hens and rats. Fenamiphos is not considered mutagenic or genotoxic based on in vitro and in vivo mutagenicity studies. SECTION 12. ECOLOGICAL INFORMATION Environmental Precautions Toxic to fish and wildlife. Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent sites. Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Page 6 of 8
7 SECTION 13. DISPOSAL CONSIDERATIONS General Disposal Guidance Container Disposal RCRA Classification Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Triple rinse containers. Do not re-use empty containers. Consult state and local regulations regarding the proper disposal of container. Follow advice on product label and/or leaflet. The RCRA Classifications may be on the individual component(s) and not necessarily on the product as a whole Naphthalene US. EPA Resource Conservation and Recovery Act (RCRA) Composite List of Hazardous Wastes and Appendix VIII Hazardous Constituents (40 CFR 261): U Naphthalene US. EPA Resource Conservation and Recovery Act (RCRA) U List of Hazardous Wastes (40 CFR (f) and 40 CFR 302 [CERCLA]): U165 SECTION 14. TRANSPORT INFORMATION TRANSPORTATION CLASSIFICATION: Organophosphorus Pesticides, Liquid, Toxic // 6.1 // UN3018 // PG II FREIGHT CLASSIFICATION: Insecticides or Fungicides, N.O.I.; poison, other than gases that are poisonous by Inhalation SECTION 15. REGULATORY INFORMATION EPA Registration No US Federal Regulations TSCA list US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) SARA Title III - Section Notification and Information Fenamiphos SARA Title III - Section Toxic Chemical Release Reporting 0.1% US States Regulatory Reporting Page 7 of 8
8 CA Prop65 This product contains a chemical known to the State of California to cause cancer. This product does not contain any substances known to the State of California to cause reproductive harm. US State Right-To-Know Ingredients Fenamiphos CA, IL, LA, MA, MN, NJ, PA, RI CA, CT, IL, MN, NJ, PA, RI Canadian Regulations Canadian Domestic Substance List Environmental CERCLA 100 lbs Clean Water Section 307 Priority Pollutants None. Safe Drinking Water Act Maximum Contaminant Levels None. International Regulations European Inventory of Existing Commercial Substances (EINECS) Fenamiphos SECTION 16. OTHER INFORMATION NFPA 704 (National Fire Protection Association): Health - 3 Flammability - 2 Reactivity - 1 Others - none 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Revision Date: 08/15/2006 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer. Page 8 of 8
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