Hazards Classification in accordance with Regulation (EC) no. 1272/2008

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1 MATERIAL SAFETY DATA SHEET Drawn up in accordance with Regulation (EU) no. 453/2010 Masa szpachlowa do drewna akrylowa biała i kolorowa SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY 1B1.1. Product identifier Trade name: 0BMasa szpachlowa do drewna akrylowa biała i kolorowa 1.2. Relevant identified uses of the substance or mixture and uses advised against Ready to use putty for levelling voids and irregularities. It can be used on mineral plasters, drywalls, concrete, wood and wood-based materials indoors and outdoors. Uses advised against: none known Details of the supplier of the safety data sheet Company name: HIRSCH-POL Sp. z o. o. Address: Myślęcinek ul. Krucza Osielsko Telephone / Fax: Telephone/fax no. : / Emergency telephone number: workdays, Monday-Friday, 8 am 4 pm SECTION 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Hazards Classification in accordance with Regulation (EC) no. 1272/2008 stemming from physiochemical properties: for humans: The mixture does not fulfil the classification criteria in accordance with Regulation (EC) no. 1272/2008 for the environment: 2.2. Elements of marking Pictograms: Signal words: Hazard statements: Precautionary statements: P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. Supplementary label elements: EUH 208 Contains a post-reaction mixture 5-Chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2- Methyl-4-isothiazolin-3-one [EC no ] (3:1). May produce an allergic reaction Other hazards No data Masa szpachlowa do drewna akrylowa biała i kolorowa 1 of 7

2 SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures UClassification pursuant to Regulation (EC) no. 1272/2008 (CLP) USubstance name UProduct identifier UHazard class UHazard Statements UConcentration limits/ M Coefficient U% by weight Dolomite (calcium magnesium carbonate) CAS no.: EC no.: Index no.: Registration no.: The product is exempt from registration pursuant to article 2, item 7b of resolution no. 1907/2006 REACH Not classified 50-70% The mixture does not contain other substances with regard to which the highest admissible concentration in a workplace was determined or substances that are a health or an environment hazard if their concentration exceeds the limits stipulated in regulations. List of Hazard Statements see section 16 of the Material Safety Data Sheet (if mentioned) SECTION 4. FIRST AID MEASURES 4.1. Description of first aid measures Inhalation: Remove person to fresh air, keep the person warm and calm. In case of symptoms, get medical attention. Skin contact: Take off all contaminated clothing and shoes and wash it before reuse. Rinse contaminated skin with water and soap. In case of symptoms, get medical attention. Eye contact: Rinse contaminated eyes with plenty of water for 15 minutes, keep eyes wide open. Remove contact lenses if present. In case of symptoms, get medical attention. Ingestion: Rinse mouth with water, provide with 1-2 glasses of water to drink. Never administer anything orally to an unconscious person. In case of disturbing symptoms, get medical attention Most important symptoms and effects, both acute and delayed Inhalation: no data Skin contact: The product contains a post-reaction mixture 5-Chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-Methyl-4-isothiazolin-3-one [EC no ] (3:1). May produce an allergic reaction. Eye contact: no data Ingestion: no data 4.3. Indication of any immediate medical attention and special treatment needed Present the material safety data sheet, label or packaging to medical staff providing first aid. SECTION 5. FIRE FIGHTING MEASURES 5.1. Extinguishing media Suitable extinguishing media Non-flammable product, use extinguishing media appropriate for burning materials. Unsuitable extinguishing media: 5.2. Special hazards arising from the substance or mixture Smoke and dangerous gases, including carbon oxides, may form during a fire Masa szpachlowa do drewna akrylowa biała i kolorowa 2 of 7

3 5.3. Advice for fire fighters SECTION 6. Wear self-contained breathing apparatus and protective clothing ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protective equipment determined in section 8 of the material safety data sheet Environmental precautions Avoid release to soil and water systems (sewage systems, water reservoirs, etc.) 6.3. Methods and material for containment and cleaning up Suck up or collect mechanically, sand can be used to absorb the substance/mixture. Place in a container for waste. Flush contaminated area with water. Clean up in accordance with national regulations References to other sections Refer to section 8 and 12 of the material safety data sheet. SECTION 7. HANDLING AND STORAGE OF SUBSTANCES AND MIXTURES 7.1. Precautions for safe handling Avoid contact with skin and eyes. Avoid breathing vapour or sprays. Use in places with adequate ventilation. Do not drink or eat when working with the product. Observe the rules of personal hygiene, use personal protective equipment in accordance with section 8 of the material safety data sheet Conditions for safe storage, including information on any incompatibilities Store the product in tightly closed containers in temperature from +5 to +30 o C 7.3. Specific end use(s) SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Permissible exposure limit (PEL): 10mg/m 3 with regard to calcium carbonate (inhalable fraction) Short-term exposure limit (STEL): Ceiling limit (CL): Ordinance of the Minister of Labour and Social Policy of June 6, 2014 on maximum permissible concentration and intensity of harmful factors in the work environment (Journal of Laws of 2014, item 817) DNEL: no data PNEC: no data 8.2. Exposure controls Appropriate engineering controls: Appropriate general ventilation should be used. Eye washes are advisable. Eye/face protection: Wear ventilated (non-fogging) protective goggles or safety glasses with side shields if there is an eye contamination hazard. Skin protection: Not required. Protective work clothing can be used. Hand protection: Not required. Protective work clothing can be used. Respiratory protection: Not required. Thermal hazards: Masa szpachlowa do drewna akrylowa biała i kolorowa 3 of 7

4 Environmental controls: SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties a) Appearance : Thick mass b) Odour : Distinctive c) Odour threshold : No data d) ph : approx. 7 9 e) Freezing/boiling point : approx. 0 o C f) Initial boiling point and boiling point range : approx. 100 o C g) Flash point : h) Evaporation rate : No data i) Flammability (solid, gas) : j) Upper/lower flammability limit or upper/lower : explosiveness limit k) Vapour pressure : No data l) Vapour density : No data m) Density : g/cm3 n) Solubility : Miscible with water o) Partition coefficient n-octanol/water : No data p) Auto-ignition temperature : q) Decomposition temperature : No data r) Viscosity : mpas s) Explosive properties : t) Oxidizing properties : 9.2. Other information No data SECTION 10. STABILITY AND REACTIVITY Reactivity The mixture is non-reactive Chemical stability The mixture is stable in normal environmental conditions, in predictable temperature and under predictable pressure during storing and handling Possibility of hazardous reactions Conditions to avoid Incompatible materials Metal (can cause corrosion); acids (reacts with acids producing CO 2 ) Hazardous decomposition products SECTION 11. TOXICOLOGICAL INFORMATION 11.1 Information of toxicological effects Acute toxicity Masa szpachlowa do drewna akrylowa biała i kolorowa 4 of 7

5 Skin corrosion/irritation The product contains a post-reaction mixture 5-Chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-Methyl-4- isothiazolin-3-one [EC no ] (3:1). May produce an allergic reaction. Serious eye damage/eye irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity: Reproductive toxicity: Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard: SECTION 12. ECOLOGICAL INFORMATION Toxicity: Aquatic environment / Sediment / Land environment: No data for the mixture Persistence and degradability No information on adverse effects or critical hazards Bioaccumulative potential Bioaccumulation is not expected Mobility in soil No data Results of PBT and vpvb assessment The product does not contain ingredients that comply with PBT and vpvb criteria specified in Annex XIII of REACH above the concentration stipulated by provisions Other adverse effects SECTION 13. DISPOSAL CONSIDERATIONS Waste treatment methods Do not dispose of with household waste; do not allow the product to enter the sewer system. Waste should always be reasonably managed (recycled or disposed of) according to the current national rules on waste. UWaste code: Aqueous suspensions containing ceramic material. Packaging classified as packaging waste, subject to disposal and/or recycling by waste owner according to the current national rules on waste. Waste packaging code: Plastic packaging Masa szpachlowa do drewna akrylowa biała i kolorowa 5 of 7

6 Act of December 14, 2012 on waste (Journal of Laws no. 0 of 2013, item 21, further amended) Act of June 13, 2013 on the management of packaging and packaging waste (Journal of Laws of 2013, item 888) Ordinance of the Minister of the Environment of September 27, 2001 on waste catalogue (Journal of Laws no. 112, item 1206, further amended) SECTION 14. TRANSPORT INFORMATION UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards The product is not classified as dangerous to the aquatic environment Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Act of February 25, 2011 on chemical substances and their mixtures (Journal of Laws no. 63 of 2011, item 322, further amended) Regulation (EC) No. 1907/2006 of the European Parliament and of the Council of December 18, 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No. 793/93 and Commission Regulation (EC) No. 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (correction OJ L 136 of , further amended) Commission Regulation (EU) No. 453/2010 of May 20, 2010 amending Regulation (EC) No. 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (OJ L 133 of ) Regulation (EC) No. 1272/2008 of the European Parliament and of the Council of December 16, 2008 on classification, labelling and packaging of substances and mixtures - amending and repealing Directive 67/548/EEC and 1999/45/EC, and Regulation (EC) No. 1907/2006 (OJ L 353 of , further amended) Ordinance of the Minister of Economy of December 21, 2005 on essential requirements for personal protective equipment (Journal of Laws no. 259 of 2005, item 2173) Ordinance of the Minister of Health and Social Services of May 30, 1996 on occupational medical examinations, the scope of prophylaxis in health care and medical certificates issued for the purposes provided for in the Labour Code (Journal of Laws no. 69 of 1996, item 332, further amended) Ordinance of the Minister of Labour and Social Policy of July 27, 2004 on occupational health and safety training courses (Journal of Laws no. 180 of 2004, item 1860, further amended) Ordinance of the Minister of Labour and Social Policy of September 26, 1997 on general occupational health and safety regulations (Journal of Laws no. 169 of 1997, item 1650, further amended) Chemical safety assessment A chemical safety assessment was not carried out. Classification was carried out on the basis of data for the ingredients of the mixture. SECTION 16. OTHER INFORMATION Amendments adopted through revisions: Adaptation to the requirements of Annex II of Regulation (UE) no. 453/2010. Key to abbreviations and acronyms: PES Permissible exposure limit STEL Short-term exposure limit CL Ceiling limit DNEL Derived no effect level PNEC Predicted no effect concentration vpvb Very persistent and very bioaccumulative PBT Persistent, bioaccumulative and toxic pollutants LD50 The amount of the substance required to kill 50% of the test animals. LC50 The concentrations of the substance that kills 50% of the test animals Masa szpachlowa do drewna akrylowa biała i kolorowa 6 of 7

7 EC50 The concentration at which growth or activity is inhibited by 50% ADR The European Agreement concerning the International Carriage of Dangerous Goods by Road RID Regulations Concerning the International Transport of Dangerous Goods by Rail Literature references and sources of data: Material Safety Data Sheets of raw materials. Information published on ECHA s website registered substances. List of Hazard Statements and EU Hazard Statements that were not reproduced in full in sections 2-15 of this MSDS: List of Precautionary Statements that were not reproduced in full in sections 2-15 of this MSDS: This Material Safety Data Sheet was drawn up based on data provided by the producer, national laws in force when this MSDS was drawn up and existing knowledge. The information contained in the MSDS should be treated only as aid to safe usage as well as transport, distribution and storage. This MSDS is not a quality certificate. The information contained in the MSDS pertains only to the said product and cannot be transferred to similar products Masa szpachlowa do drewna akrylowa biała i kolorowa 7 of 7

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