Safety Data Sheet. according to Regulation (EC) No. 1907/2006 LEYCO-CHASSIS

Transcription

1 Print date: Product code: 163 Page 1 of 6 SECTION 1: Identification of the substance/mixture and of the company/undertaking Product identifier Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture cleaning agent Details of the supplier of the safety data sheet Company name: Street: Place: Industriestraße 155 D Köln Telephone: ++49 (0) Telefax:++49 (0) inkemann@leyde.com Contact person: Eckart Inkemann Telephone: ++49 (0) Internet: Responsible Department: Eckart Inkemann Emergency telephone: 0049 (0) SECTION 2: Hazards identification Classification of the substance or mixture Label elements Indications of danger : Corrosive R-phrases: Causes burns. Danger symbols: C - Corrosive C - Corrosive R phrases 34 Causes burns. S phrases 02 Keep out of the reach of children. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 2 After contact with skin, wash immediately with plenty of water. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 37/39 Wear suitable gloves and eye/face protection. Other hazards Harmful by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to respiratory system. SECTION 3: Composition/information on ingredients Mixtures

2 Print date: Product code: 163 Page 2 of 6 Hazardous components EC No. CAS No. Index No. REACH No Chemical name Classification GHS classification phosphoric acid... %, orthophosphoric acid... % C R34 Skin Corr. 1B; H314 nonionic surfactants Xn R22-41 Quantity > 30 % 5-10 % anionic surfactants Xn R % sulphuric acid... % C R35 Skin Corr. 1A; H % (2-Butoxyethoxy)ethanol (vgl. Butyldiglykol) Xi R Eye Irrit. 2; H319 Full text of R- and H-phrases: see section % SECTION 4: First aid measures Description of first aid measures General information Take off contaminated clothing and shoes immediately. Symptoms of poisoning may only appear several hours later. Keep under medical supervision for at least 4 hours. After inhalation Move to fresh air. Oxygen or artificial respiration if needed. If symptoms persist, call a physician. After contact with skin Wash off immediately with soap and plenty of water. After contact with eyes Flush eye(s) immediately with plenty of water. Consult a physician. After ingestion Call a physician immediately. Immediately give large quantities of water to drink. Move to fresh air. SECTION 5: Firefighting measures Extinguishing media Suitable extinguishing media "Use dry chemical, CO2, water spray or ""alcohol"" foam." Extinguishing media which must not be used for safety reasons Do not use a solid water stream as it may scatter and spread fire. Advice for firefighters In the event of fire, wear self-contained breathing apparatus.

3 Print date: Product code: 163 Page 3 of 6 SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Evacuate personnel to safe areas. Environmental precautions Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Neutralise with Use personal protective equipment. Ensure adequate ventilation. SECTION 7: Handling and storage Precautions for safe handling Advice on safe handling Provide appropriate exhaust ventilation at machinery and at places where dust can be generated. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep tightly closed. SECTION : Exposure controls/personal protection Control parameters Exposure limits (EH40) CAS No. Chemical name ml/m³ mg/m³ F/ml Category Origin Orthophosphoric acid - 1 TWA ( h) WEL Exposure controls - 2 STEL (15 min) WEL Protective and hygiene measures Keep away from food, drink and animal feeding stuffs. Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of workday. Avoid contact with the skin and the eyes. Hand protection protective gloves : butylrubber PVC or other plastic material gloves( 0,5 mm ) Polyvinyl alcohol or nitrile-butyl rubber gloves ( 0,35 mm ) Break through time > h Eye protection tightly fitting safety goggles SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical state: Colour: Odour: liquid brown characteristic ph-value (at 20 C): < 1,0 Test method Changes in the physical state Melting point: Boiling point: < 0 C 100 C

4 Print date: Product code: 163 Page 4 of 6 Flash point: Ignition temperature: Vapour pressure: (at 20 C) Vapour pressure: (at 50 C) Density (at 20 C): Water solubility: (at 20 C) SECTION 10: Stability and reactivity Reactivity Exothermic reaction Possibility of hazardous reactions Incompatible with strong bases and oxidising agents Exothermic reaction Conditions to avoid No decomposition if used as directed. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50/oral/rat = 1530 mg/kg ( Phosphorsäure ) Additional information on tests Ingestion of aqueous solution causes gastrointestinal burns. SECTION 12: Ecological information not applicable not applicable 23 hpa < 110 hpa 1,25 g/cm³ miscible Persistence and degradability The surfactants contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No. 64/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their request or at the request of a detergent manufacturer. Further information May cause long-term adverse effects in the aquatic environment. Neutralisation is normally necessary before waste water is discharged into water treatment plants. SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Do not flush into surface water or sanitary sewer system. Dispose of as special waste in compliance with the Control of Pollution (Special Waste) Regulations 190. Waste disposal number of waste from residues/unused products WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics; aqueous washing liquids and mother liquors Classified as hazardous waste. Waste disposal number of used product WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics; aqueous washing liquids and mother liquors Classified as hazardous waste.

5 Print date: Product code: 163 Page 5 of 6 Contaminated packaging Clean container with water. SECTION 14: Transport information Land transport (ADR/RID) UN number: Hazard label: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. ( Schwefelsäure ) Classification code: Limited quantity: Hazard-no.: Tunnel restriction code: C1 LQ7 0 E Other applicable information (land transport) : 274 : 3 Inland waterways transport UN number: Hazard label: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. ( Schwefelsäure Lösung ) Classification code: Limited quantity: C1 LQ7 Other applicable information (inland waterways transport) : 274 Marine transport UN number: Hazard label: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S.( Sulphuric acid solution )

6 Print date: Product code: 163 Page 6 of 6 Special Provisions: Limited quantity: EmS: 223, L F-A, S-B Other applicable information (marine transport) : 223, 274, 944 Air transport UN/ID number: Hazard label: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: Other applicable information (air transport) : Y1 : A3 1 L 1 5 L L SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Water contaminating class (D): 2 - water contaminating SECTION 16: Other information Full text of R-phrases referred to under sections 2 and 3 22 Harmful if swallowed. 34 Causes burns. 35 Causes severe burns. 36 Irritating to eyes. 3 Irritating to skin. 41 Risk of serious damage to eyes. Full text of H-Statements referred to under sections 2 and 3 H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. Further Information The information is based on present level of our knowledge. It does not, however, give assurances of product properties and establishes no contract legal rights. The receiver of our product is singulary responsible for adhering to existing laws and regulations. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)