3.2. Mixture Name Product identifier % Classification (GHS-US)

Transcription

1 Date of issue: 08/05/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Identification Product form : Mixture Product name : Zinc Sulfate 10% 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet MarVista Resources 745 North Ave. Corcoran, Ca USA T : Various industrial and agricultural applications 1.4. Emergency telephone number Emergency number : 24 Hour Emergency HAZMAT Response: (800) : EPA National Response Center: (800) SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture Classification (GHS-US) Eye Irrit. 2B H320 - Causes eye irritation Full text of H-phrases: see section Label elements GHS-US labeling Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Warning : H320 - Causes eye irritation : P264 - Wash skin thoroughly after handling P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification (GHS-US) zinc sulfate, monohydrate (CAS No) Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact : If you feel unwell, seek medical advice (show the label where possible). : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. 08/18/2015 EN (English US) Page 1

2 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion : May cause eye irritation. : May cause slight irritation. : May cause slight irritation to the skin. : mild eye irritation. : May cause gastrointestinal discomfort Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard Reactivity : Water spray. Dry powder. Foam. Carbon dioxide. : Non-flammable. : The product is non-reactive under normal conditions of use, storage and transport Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8 Exposure controls/personal protection" " Environmental precautions Avoid release to the environment Methods and material for containment and cleaning up For containment Methods for cleaning up Other information 6.4. Reference to other sections : Dam up the liquid spill. Collect spillage. : Take up liquid spill into absorbent material. : Dispose of materials or solid residues at an authorized site. For further information refer to section 8 : Exposure-controls/personal protection"". SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Store in a well-ventilated place. Keep cool. : Strong oxidizers. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection : Ensure good ventilation of the work station. : Protective gloves. : Safety glasses. 08/18/2015 EN (English US) 2/6

3 Skin and body protection Respiratory protection Environmental exposure controls : Wear suitable protective clothing. : In case of insufficient ventilation, wear suitable respiratory equipment. : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold : Liquid ph : 4-5 Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Specific gravity / density : Mixture contains one or more component(s) which have the following colour(s): White Colourless to white : There may be no odour warning properties, odour is subjective and inadequate to warn of overexposure. Mixture contains one or more component(s) which have the following odour(s): Odourless : : 1.38 g/ml Solubility : Water: Solubility in water of component(s) of the mixture : : 35 g/100ml : 59 g/100ml Log Pow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. Other information SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport Chemical stability Stable under normal conditions Possibility of hazardous reactions No dangerous reactions known under normal conditions of use Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Strong oxidizers Hazardous decomposition products Sulfur oxides. 08/18/2015 EN (English US) 3/6

4 SECTION 11: Toxicological information Information on toxicological effects Acute toxicity ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion SECTION 12: Ecological information Toxicity Ecology - general LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia mg/kg body weight ph: 4-5 : Causes eye irritation. ph: 4-5 : May cause slight irritation. : May cause slight irritation to the skin. : mild eye irritation. : May cause gastrointestinal discomfort. : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 1.7 mg/l (96 h; Poecilia reticulata; Anhydrous form) 0.56 mg/l (48 h; Daphnia magna; Anhydrous form) 2.4 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Anhydrous form) 1 mg/l (24 h; Daphnia magna; Anhydrous form) Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable Bioaccumulative potential BCF fish 1 BCF fish 2 Bioaccumulative potential (Cyprinus carpio; Anhydrous form) (Cyprinus carpio; Test duration: 8 weeks) Bioaccumable Mobility in soil Other adverse effects Effect on the global warming : No known ecological damage caused by this product. 08/18/2015 EN (English US) 4/6

5 SECTION 13: Disposal considerations Waste treatment methods Sewage disposal recommendations Ecology - waste materials SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport TDG Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations : Prevent liquid from entering sewers, watercourses, underground or low areas. : Avoid release to the environment. Not listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations National regulations US State regulations SECTION 16: Other information Full text of H-phrases: Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category Eye Dam. 1 Serious eye damage/eye irritation Category Eye Irrit. 2B Serious eye damage/eye irritation Category 2B H302 Harmful if swallowed H318 Causes serious eye damage H320 Causes eye irritation H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects 08/18/2015 EN (English US) 5/6

6 NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. SDS US (GHS HazCom 2012) All information contained in this is furnished free of charge and is intended for your evaluation. In our opinion the information is, as of the date of this, reliable, however, it is your responsibility to determiine the suitability of the information for your use. You are advised not to construe the information as absolutely complete since additonal information may be necessary or desirable when particular, exceptional or variable conditions or circumstances exist or because of applicable laws or government regulations. Therefore, you should use this information only as a supplement to other informations gathered by you, and you must make independent determinations of the suitability and completeness of the information from all souces to assure both proper use of the material described herein and the safety and health of employees. Accordingly, no guarantee is expressed or implied as to the results to be obtained based upon your use of the information. 08/18/2015 EN (English US) 6/6