COMPO liquid fertilizer Basfoliar 36 Extra

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1 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Fertilizer 1.3 Details of the supplier of the safety data sheet Company : COMPO GmbH & Co. KG Gildenstraße 38 D Münster Telephone : / Telefax : / address : info@compo.de 1.4 Emergency telephone number Central Safety & Environment Telephone: Hazards identification 2.1 Classification of the substance or mixture Classification (REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Classification(67/548/EEC,1999/45/EC) Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. 2.2 Label elements Labelling(REGULATION (EC) No 1272/2008) Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. Labelling according to EC Directives (1999/45/EC) Further information : In accordance with EC directives or respective national laws, the product does not need to be classified nor labelled. 2.3 Other hazards According to our experience and to the information provided to us, the product does not have any harmful effects if it is used and handled as specified. 1/8 Print Date:

2 3. Composition/information on ingredients 3.2 Mixtures Chemical nature : Liquid mixture of organic and inorganic salts of fertilzers. Hazardous components Chemical Name CAS-No. EC-No. Registration number Ammonium Nitrate Classification (67/548/EEC) O; R 8 Xi; R36 Classification (REGULATION (EC) No 1272/2008) Ox. Sol. 3; H272 Eye Irrit. 2; H319 Concentration [%] >= 10 - <= 45 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures If inhaled : Keep patient calm, remove to fresh air, seek medical attention. If unconscious place in recovery position and seek medical advice. In case of lung irritation, first treatment with dexametason aerosol (spray). In case of skin contact : Wash off with soap and water. In case of eye contact : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed : Clean mouth with water and drink afterwards plenty of water. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : No information available. 4.3 Indication of any immediate medical attention and special treatment needed Treatment : Treat symptomatically. 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media : Water Unsuitable extinguishing media : Foam Dry chemical Carbon dioxide (CO2) Sand 2/8 Print Date:

3 5.2 Special hazards arising from the substance or mixture Specific hazards during firefighting : At temperatures above 130 C, dangerous decomposition gases can be emitted: Nitrogen monoxide, nitrogen dioxide, dinitrogenoxide, ammonia 5.3 Advice for firefighters Special protective equipment : In the event of fire, wear self-contained breathing apparatus. for firefighters Further information : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : No special precautions required. 6.2 Environmental precautions Environmental precautions : Do not empty into drains. Retain and dispose of contaminated wash water. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). 6.4 Reference to other sections For personal protection see section Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Keep away from direct sunlight. Protect against heat. Do not allow to dry. Advice on protection against fire and explosion : Keep away from heat and sources of ignition. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers : Keep away from heat. Keep away from sources of ignition - No smoking. Protect from contamination. Advice on common storage : Store well away from other substances. German storage class : 12 Non Combustible Liquids Storage temperature : 5-35 C 7.3 Specific end uses 3/8 Print Date:

4 : Always read the label and product information before use. 8. Exposure controls/personal protection 8.1 Control parameters DNEL : This information is not available. PNEC : This information is not available. 8.2 Exposure controls Personal protective equipment Hand protection : For prolonged or repeated contact use protective gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Recommended preventive skin protection Eye protection : Avoid contact with eyes. Tightly fitting safety goggles Hygiene measures : At the end of the shift the skin should be cleaned and skincare agents applied. Environmental exposure controls General advice : Do not empty into drains. Retain and dispose of contaminated wash water. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : various Odour : odourless ph : ca. 5,7, 20 C Density : ca. 1,345 g/cm³, 20 C Water solubility : soluble Thermal decomposition : Stable at normal ambient temperature and pressure., Do not allow evaporation to dryness. 9.2 Other information 10. Stability and reactivity 10.1 Reactivity 4/8 Print Date:

5 No dangerous reaction known under conditions of normal use Chemical stability No decomposition if stored and applied as directed Possibility of hazardous reactions Hazardous reactions : Evolution of ammonia under influence of alkalies Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid : None known. : Sulphur, chlorites, chloride, chlorates, Hypochlorites, acid or alkaline reacting substances, flammable oxidizable substances, nitrites, metallic salts, metallic powder, herbicide, chlorinated hydrocarbons, organic compounds Hazardous decomposition products Hazardous decomposition products : Nitrogen monoxide, nitrogen dioxide, dinitrogenoxide, ammonia 11. Toxicological information 11.1 Information on toxicological effects Product Acute oral toxicity : LD50: > mg/kg, rat Skin corrosion/irritation : May irritate skin. Serious eye damage/eye : May irritate eyes. irritation Further information : The product was not tested. The statement was derived from products of similar structure and composition. Components: Ammonium Nitrate : Acute oral toxicity : LD50: > mg/kg, rat, OECD Test Guideline 401 Acute inhalation toxicity : > 88,8 mg/l, No information available., Not relevant because of low vapour pressure., Not relevant because of low dust formation. Acute dermal toxicity : LD50: > mg/kg, rat, OECD Test Guideline 402 Skin corrosion/irritation : rabbit, Result: non-irritant, OECD Test Guideline 404 Serious eye damage/eye : rabbit, Result: Irritant, OECD Test Guideline 405 irritation Respiratory or skin : Result: Does not cause skin sensitization. sensitization Germ cell mutagenicity Genotoxicity in vitro : Result: negative, OECD Test Guideline 471 STOT - repeated exposure : rat, Oral, Exposure time: 28 d, NOAEL: > mg/kg 5/8 Print Date:

6 STOT - repeated exposure STOT - repeated exposure : rat, Oral, Exposure time: 52 w, NOAEL: = 256 mg/kg, OECD Test Guideline 453 : rat, by inhalation, Exposure time: 2 w, NOAEL: >= 185 mg/kg, Repeated Dose Inhalation Toxicity: 28-day or 14-day Study. 12. Ecological information 12.1 Toxicity Toxicity to fish : LC50: 422 mg/l, 48 h, Cyprinus carpio (Carp), static test Toxicity to daphnia and other : EC50: 555 mg/l, 48 h, Daphnia, static test aquatic invertebrates. Toxicity to algae : No observed effect concentration: 83 mg/l, 168 h, Desmodesmus subspicatus (green algae), other, no data available Toxicity to bacteria : EC20: ca. 850 mg/l, 0,5 h, activated sludge, other, no data available, Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. Components: Ammonium Nitrate : Toxicity to fish Toxicity to daphnia and other aquatic invertebrates. Toxicity to algae : LC50: > 100 mg/l, 96 h, various species : EC50: 490 mg/l : LC50: 490 mg/l : EC50: mg/l, other aquatic plant 12.2 Persistence and degradability Biodegradability : Components: Ammonium Nitrate : Biodegradability : 12.3 Bioaccumulative potential Bioaccumulation : Components: Ammonium Nitrate : The product works in the soil as fertilizer and is diminished in a few weeks. The methods for determining the biological degradability are not applicable to inorganic substances. Bioaccumulation is unlikely. 6/8 Print Date:

7 Bioaccumulation : Bioaccumulation is unlikely Mobility in soil Mobility : no data available Distribution among : no data available environmental compartments 12.5 Results of PBT and vpvb assessment Assessment : no data available 12.6 Other adverse effects Additional ecological information : Do not flush into surface water or sanitary sewer system., Additional ecological information, The product has not been tested. The information is derived from the properties of the individual components., At higher ph values, which can be found in natural surface waters, an increase of toxic effects on aquatic organsims may be expected. 13. Disposal considerations 13.1 Waste treatment methods Product Contaminated packaging : Check if agriculture use is possible. Contact manufacturer. : Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport information 14.1 Land transport ADR Remarks : Not classified as dangerous in the meaning of transport regulations Sea transport ADNR Remarks IMDG Remarks : Not classified as dangerous in the meaning of transport regulations. : Not classified as dangerous in the meaning of transport regulations Air transport 7/8 Print Date:

8 IATA-DGR Remarks : Not classified as dangerous in the meaning of transport regulations Special precautions for user 14.5 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Water contaminating class : WGK 1 slightly water endangering (Germany) 15.2 Chemical Safety Assessment A Chemical Safety Assessment is not required for this substance. 16. Other information Full text of R-phrases referred to under sections 2 and 3 R 8 Contact with combustible material may cause fire. R36 Irritating to eyes. Full text of H-Statements referred to under sections 2 and 3. H272 May intensify fire; oxidiser. H319 Causes serious eye irritation. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 8/8 Print Date:

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