MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015

Transcription

1 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: Identification of the substance/mixture and of the company/enterprise 1.1 Product identifier: Aluminum sodium oxide in solution Commercial name SODAL 52 L Reg No Relevant identified uses of the substance or mixture, and uses advised against Identified uses: Formulation. Flocculant or coagulant in water treatment. Production of zeolites and other compounds of aluminum. Production of building materials. Chemical agent process and / or intermediate. Preparation of pulp, paper, cardboard. Cleaning agent. Flame retardant agent. Production and processing of pigments. Production paints, coatings, inks, adhesives, etc. Uses advised against: none 1.3 Details of the supplier of the safety data sheet: BRAIA S.r.l. Via Mameli, Millesimo (SV) Tel Fax braia@braia.it 1.4 Emergency phone number: Tel (Mon-Fri business hours) TC: braia@braia.it 2. Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008: Corrosion (Category 1A) Substances corrosive to metals (Category 1) Hazard statements: 1/50

2 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: H314 - Causes severe skin burns and eye damage H290 - May be corrosive to metals Label elements: Pictogram, Signal Word Code(s): Danger Hazard statement Code(s): H314 - Causes severe skin burns and eye damage H290 - May be corrosive to metals. Precautionary statements: Prevention P260 - Do not breathe dust/fumes/gas/mist/vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection. Reaction P IF SWALLOWED: Rinse mouth. Do NOT induce vomiting P IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P IF INHALED: Remove person to fresh air and keep comfortable for breathing. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing. P310 - Immediately call a POISON CENTER OR doctor P390 - Absorb spillage to prevent material damage. Storage P405: Store locked up. Contains: Aluminum sodium oxide 2.3 Other hazards: 3. Composition/Information on ingredients 3.1 Substances Chemical composition: Aluminum sodium oxide in water solution Name Concentration (C) Classification Regulation EC/1272/2008 Aluminum sodium oxide Cas N <C<50% Skin Corr. 1A H314 2/50

3 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: CE N Met Corr 1 H290 Reach N Sodium hydroxide (stabilizer) <10% Skin Corr.1A H314 Cas N Met Corr 1 H290 CE N Index N The full text of hazard statements is specified in section First-aid measures 4.1 Description of first aid measures Inhalation Remove the injured from the contaminated area and in a well-ventilated and comfortable with the chest lifted. Keep warm (blanket). Apply artificial respiration if necessary. If you experience symptoms of the respiratory seek medical attention. Skin contact Take off contaminated clothing. Wash thoroughly with soap and water. If symptoms persist, consult a doctor. Wash contaminated clothing before using them. Eyes contact Rinse immediately with plenty of water for at least 15 minutes, keeping opened eyes. Consult immediately eye specialist. Ingestion If victim is fully conscious, rinse mouth, give water to drink fresh milk or water and magnesium. DO NOT induce vomiting. Keep warm (blanket). Provide for the urgent transport to a hospital. Other Appropriate intervention or consultation with the doctor. Means for specific and immediate treatment to be made available in the workplace: emergency showers, eyewash fountains and water intakes for washing the floor in case of losses Most important symptoms and effects, both acute and delayed not available 4.3. Indication of any immediate medical attention and special treatment needed In case of inhalation: If you experience symptoms of the respiratory seek medical attention. In case of skin: If it is an extended contact or the contact occurred with a hot solution, to provide emergency transport to hospital. 3/50

4 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: In case of eye contact: Consult urgently a doctor specialist, go immediately to the emergency room. In case of ingestion: Get medical emergency, go immediately to the emergency room. 5. Fire-fighting measures 5.1 Extinguishing media Advised extinguishing agents: CO 2, chemical powder, foam, nebulized water. Fight larger fires with water spray or alcohol resistant foam. Extinguishing prohibited: none 5.2. Special hazards arising from the substance or mixture The product under fire condition may develop irritant/toxic gas 5.3. Advice for firefighters Wear the complete fire equipment all the time. Water used in fire-fighting has to be disposed following Local regulation. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid contact with eyes and skin. In the case of vapor formation use adequate respiratory protection. Supply good ventilation. Remove people not involved in the operations of intervention. Eliminate or exclude any source of ignition Environmental precautions Collect the product in suitable container for disposal. Notify authorities if product enters sewer or public waters Methods and material for containment and cleaning up Cover the spillage with inert absorbent material (sand, diatomite, acid binders, universal binders, sawdust). 6.4 Reference to other sections Refer to paragraphs 7, 8 and 13 for more information. 7. Handling and storage 7.1. Precautions for safe handling Used equipment in material unassailable by the product. Respect the normal 4/50

5 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: industrial hygiene practice. Do not smoke, drink or eat during the working processes. During manipulations operate properly protected. Operate in wellventilated areas. During manipulations operate properly protected. Have available the workplace emergency showers, eyewash fountains and localized aspiration Conditions for safe storage, including any incompatibilities Store the containers sealed and in a well-ventilated area. Wear appropriate clothing resistant to basis. Keep separate from strong acids. Store in cool place. Store in airtight containers Specific end use(s) For particular uses of the product, is necessary to refer to the specific information or contact the technical service of the Company. 8. Exposure controls/personal protection 8.1. Control parameters Aluminum sodium oxide PNEC Fresh water 14 mg/l Marine water 1.4 mg/l Intermittent release 4.3 mg/l Water treatment plant 10 mg/l Type TWA/8h STEL/15min Description mg/m 3 ppm mg/m 3 ppm Sodium hydroxide (C) = Ceiling TLV- ACGIH 2 (C) 8.2 Exposure controls Against corrosive properties of the product and according to the type of work, you must use adequate personal protection equipment. Do not eat, drink or smoke while handling it. Wash your hands thoroughly with soap and water before meals and take a shower after work shift. Work clothes should be washed separately and stored in a separate place. Minimize worker exposure through the installation of appropriate technical measures in the cases provided by the scenarios. Individual protection The DPI s choise must be done on the basis of the test s results obtained according to the rule EN 374 5/50

6 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: Hand protection: If required in the exposure scenarios, using protective gloves resistant to the basic properties of the product. The glove material has to be impermeable and resistant to the product. Choose the material on consideration of the penetration times, rates of diffusion and the degradation. The choice must be made as a function also of other processing characteristics and varies from manufacturer to manufacturer. (Efficiency 90%) Eye protection : safety goggles tight Skin protection: closed work clothing Respiratory protection: protective mask in the cases provided by the attached exposure scenarios 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical and chemical properties Value Determination method Appearance amber liquid Odour odorless Odour threshold not available ph >11 Melting point/freezing point < -8 C Initial boiling point and boiling range not available Flash point not flammable Evaporation rate not available Flammability (solid, gas) not pertinent Upper/lower flammability or explosive limits not pertinent Vapour pressure not available Vapour density not available Density 1,50 ± 0,03 g/cm 3 20 C Solubility miscible in water Water solubility completely miscible Partition coefficient: n-octanol/water not available Auto-ignition temperature not available Decomposition temperature not available Viscosity mpas Explosive properties not explosive Oxidising properties not oxidizing 9.2. Other information VOC (Directive 1999/13/CE) : -% 6/50

7 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: Stability and reactivity Reactivity Are possible exothermic reactions in contact with strong oxidizing agents and strong acids Chemical stability The product is stable in normal conditions of use and storage Possibility of hazardous reactions The presence of carbon dioxide may cause precipitation of aluminum hydroxide. Corrosive in contact with metals: free hydrogen by reaction with metals. Exothermic reaction with strong acids. It can react violently with acrolein, acrylonitrile, and allyl alcohol. Heating with trichlorethylene form explosive mixtures of dichloroacetylene. It reacts with ammonium compounds liberating ammonia Conditions to avoid Keep away from strong bases, oxidizing agents; Corrosive in contact with metals. Do not heat to avoid thermal decomposition. The product can be corrosive to metals Incompatible materials Some plastics, leather and some fabrics are degraded by contact with the mixture alkaline earth metals in powder form: lead, zinc, aluminum, brass, and tin; acids; nitrile; ammonium compounds, cyanide, magnesium, organic nitro compounds, organic combustible substances, phenols and oxidizing agents Hazardous decomposition products Due to thermal decomposition or in the event of a fire vapours may be produced potentially dangerous to health Toxicological information Information on toxicological effects Acute effects: Corrosive product: Causes severe skin burns and eye damage. Relative toxicity to the substance contained: Aluminum sodium oxide Acute toxicity : Based on the tests the substance has shown a low toxicity by oral, dermal and inhalation 7/50

8 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: Corrosive/irritation For substance with strongly acidic or basic ph 2 or 11.5 you do not need to test for irritation / corrosion. The substance is classified as corrosive on the basis of ph Respiratory sensitization / skin Animal tests conducted on substances with similar composition does not have shown sensitizing effects. Experimental / calculated data: Skin sensitization test (guinea pig): No sensitizing. OECD Guideline 406 Mutagenicity Experimental tests in vivo and in vitro studies of substances with similar composition showed no mutagenic effects Experimental / calculated data: Ames test: negative OECD Guideline 471 (Bacterial Reverse Mutation Assay) Test for gene mutation in mammalian cells: negative OECD Guideline 476 (In vitro Mammalian Cell Gene Mutation Test) Micronucleus test in mammalian cells: negative OECD Draft proposal for a new Guideline No. 487 (In Vitro Mammalian Cell Micronucleus Test) Developmental Toxicity Animal tests conducted on substances of similar composition have shown no fetal damage and reproductive damage for any of the doses tested. Experimental / calculated data: combined test of fatal and reproductive toxicity (OECD Guideline 422-Combined Repeated Dose Toxicity Study with the Reproduction / Developmental Toxicity Screening Test): NOAEL (P) females: 300 mg Al / kg bw / day NOAEL (F1) male and female: 100 mg Al/ kg bw / day Specific target organ toxicity (single exposure) Animal tests conducted on substances with similar composition showed no organspecific toxicity. Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Oral administration of substances with similar composition repeated the substance does not cause related events. Aspiration Hazard not applicable 12. Ecological information Toxicity: 8/50

9 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: Use this product according to good working practices. Avoid litter. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation. The Aluminum sodium oxide is not stable in environmental ph conditions (between 4-9). The main decomposition products are sodium hydroxide and aluminum hydroxide. The sodium hydroxide can be dangerous to aquatic organisms in water; the aluminum may still be present in various forms depending on the chemical and physical characteristics (ph, temperature, amount of dissolved carbon). LC50: 370 mg/l/48h (Leuciscus idus) LC50: 3.69 mg/l/48h (Ceriodaphnia sp.) EC50: μg/l (Pseudokirchnerella subcapitata) Persistence and degradability: In general, the biodegradability is a process irrelevant for inorganic substances because all processes biotic and abiotic substances tend to turn but not to eliminate it Bioaccumulative potential: The data demonstrate that the product does not give rise to bioaccumulation. Aluminum is one of the main components of the lithosphere (with a rate of about 8%). Human activities contribute insignificantly to the natural presence of aluminum Mobility in soil: The mobility of the aluminum is related to its solubility and in general is greater in soils rich in organic material, for the formation of organometallic complexes, or with acid ph Results of PBT and vpvb assessment: Not PBT; not vpvb Other adverse effects: This product doesn t contain AOX 13. Disposal considerations Waste treatment methods Operate following the current Local or National Laws. The non reclaimed containers have to be disposed as the product. Consider the possibility of burning the product in a suitable inceneritor. 14. Transport information 9/50

10 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: UN number UN proper shipping name SODIUM ALUMINATE SOLUTION Transport hazard class(es) Class : 8 Label : 8 Tunnel restriction code : E Limited quantities : 5 L EmS : F-A, S-B Packing group III Environmental hazards Product is not environmentally hazardous Marine polluting agent : Not Special precautions for user No data available Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code It is not intended to carry bulk 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Danger labelling under directive 1272/2008/EC and following amendments and adjustments Regulation Cas Substance 428/2009 ex CE 1334/2000 Ann /04 Tab.1 Cat /04 Tab.1 Cat /04 Tab.1 Cat Reg. CE1907/2006 Ann. XIV - - Reg. CE1907/2006 (Substances SVHC) /50

11 Commercial name: SODAL 52 L MATERIAL SAFETY DATA SHEET Regulation (EC) 1907/2006 and Regulation (EU) 830/2015 Date of compilation: Revision: 0 of Date of printing: Reg. CE 1907/2006 as regards Ann. - - XVII) 2003/105/CE Ann.1 part /105/CE Ann.1 part Chemical safety assessment A CSA has been carried out. 16. Other information Description of the sentences of risk set out in paragraph 3: H314: Causes severe skin burns and eye damage H290 = May be corrosive to metals. GENERAL BIBLIOGRAPHY: 1 Regulation (EC) 1907/2006 of the European Parliament (REACH) 2. Regulation (EC) 1272/2008 of the European Parliament (CLP) and its amendments 3. Regulation (EC) 790/ Regulation (EC) 830/ The Merck Index. Ed Handling Chemical Safety 7. NIOSH - Registry of Toxic Effects of Chemical Substances 8. INRS - Fiche Toxicologique 9. Patty - Industrial Hygiene and Toxicology 10. NI Sax - Dangerous Properties of Industrial Materials-7, 1989 Edition 11. Website Agency ECHA Directive 2008/68 / EU and ss.mm.- Transport Dangerous Goods (ADR) Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. -This sheet cancels and substitutes any previous edition 11/50

12 EXPOSURE SCENARIO 12/50

13 ES 1: Production of sodium aluminate 1. Title of exposure scenario Production of sodium aluminate Sectors of end-use Chemical Product Category: SU6a,SU6b,SU8,SU9 PC14, PC15, PC20, PC37 Environment: Manufacture of substances ERC 1 Formulation of preparations* ERC 2 Formulation in materials ERC 3 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) Industrial use of reactive processing aids ERC 6a ERC 6b Workers Use in closed, continuous process with occasional controlled exposure PROC 1 Use in closed, continuous process with occasional controlled exposure PROC 2 Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Industrial spraying PROC 7 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8a PROC 8b Treatment of articles by dipping and pouring PROC 13 Production of preparations* or articles by tabletting, compression, extrusion, pelletisation PROC Conditions of use that modify exposure 13/50

14 2.1 Environmental exposure controls: The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use. Following are the measures identified in the risk assessment Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 3. Estimation of exposures and calculation methods Environmental exposure 14/50

15 Worker exposure It not expected exposure of workers in the event of implementation of the measures set out in section 2 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 15/50

16 ES 2: Formulation 1. Title of exposure scenario Use in formulation of preparations Sectors of end-use Chemical Product Category: SU8, SU9, SU10 PC14, PC15, PC20, PC21, PC37 Environment: Manufacture of substances ERC 1 Formulation of preparations* ERC 2 Formulation in materials ERC 3 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) Industrial use of reactive processing aids ERC 6a ERC 6b Workers Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Industrial spraying PROC 7 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8a PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 Treatment of articles by dipping and pouring PROC 13 Use as laboratory reagent PROC 15 Handling of solid inorganic substances at ambient temperature PROC Conditions of use that modify exposure 16/50

17 2.1 Environmental exposure controls: The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use. Following are the measures identified in the risk assessment Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 3. Estimation of exposures and calculation methods Environmental exposure Worker exposure 17/50

18 It not expected exposure of workers in the event of implementation of the measures set out in section 2 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 18/50

19 ES 3: Industrial and professional use as a flocculant or coagulant in water treatment 1. Title of exposure scenario Use as a flocculant or coagulant in water treatment Sectors of end-use Chemical Product Category: SU5,SU6a,SU6b,SU7,SU8,SU23 PC20, PC21,PC26, PC37 Environment: Formulation of preparations* ERC 2 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use of reactive processing aids Wide dispersive indoor use of processing aids in open systems Wide dispersive indoor use of reactive substances in open systems Wide dispersive indoor use which results in the inclusion in a matrix or onto a matrix Wide dispersive outdoor use of processing aids in open systems Wide dispersive outdoor use of reactive substances in open systems Wide dispersive outdoor use which results in the inclusion in a matrix or onto a matrix Transfer of substance or preparation into small containers (dedicated filling line, including weighing) ERC 6b ERC 8a ERC 8b ERC 8c ERC 8d ERC 8e ERC 8f ERC 9a Workers Use in closed process, no likelihood of exposure PROC 1 Uso in un processo chiuso e continuo, con occasionale esposizione controllata PROC 2 Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Industrial spraying PROC 7 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8a PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 19/50

20 Use as laboratory reagent PROC 15 Hand-mixing with intimate contact and only PPE available PROC Conditions of use that modify exposure 2.1 Environmental exposure controls: The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use in the following format Stato fisico Frase di rischio Misure identificate nella valutazione qualitativa Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 3. Estimation of exposures and calculation methods 20/50

21 Environmental exposure Worker exposure It not expected exposure of workers in the event of implementation of the measures set out in section 2 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 21/50

22 ES 4: Using as starting material for the production of zeolites and other compounds of aluminum 1. Title of exposure scenario Using as starting material for the production of zeolites and other compounds of aluminum Sectors of end-use Chemical Product Category: SU8,SU9 PC19, PC20, PC21 Environment: Manufacture of substances ERC 1 Formulation of preparations* ERC 2 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) ERC 6a Workers Use in closed process, no likelihood of exposure PROC 1 Uso in un processo chiuso e continuo, con occasionale esposizione controllata PROC 2 Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8a PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 Production of preparations* or articles by tabletting, compression, extrusion, pelletisation PROC Conditions of use that modify exposure 2.1 Environmental exposure controls: 22/50

23 The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use in the following format Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 3. Estimation of exposures and calculation methods Environmental exposure Worker exposure It not expected exposure of workers in the event of implementation of the measures set out in section 2 23/50

24 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 24/50

25 ES 5: Use in the production of building materials 1. Title of exposure scenario Use in the production of building materials Sectors of end-use Chemical Product Category: SU10,SU13,SU19 PC19, PC20, PC21, PC37 Environment: Manufacture of substances ERC 1 Formulation of preparations* ERC 2 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) Wide dispersive indoor use of processing aids in open systems Wide dispersive indoor use which results in the inclusion in a matrix or onto a matrix Wide dispersive outdoor use of processing aids in open systems Wide dispersive outdoor use which results in the inclusion in a matrix or onto a matrix Wide dispersive outdoor use of articles and durable materials with low release Wide dispersive indoor use of articles and long lasting materials with low release ERC 6a ERC 8a ERC 8c ERC 8d ERC 8f ERC 10a ERC 11a Workers Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Industrial spraying PROC 7 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8a PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 Applicazione con rulli o pennelli PROC 10 25/50

26 Applicazione spray non industriale PROC 11 Treatment of articles by dipping and pouring PROC 13 Production of preparations* or articles by tabletting, compression, extrusion, pelletisation PROC 14 Use as laboratory reagent PROC 15 Hand-mixing with intimate contact and only PPE available PROC Conditions of use that modify exposure 2.1 Environmental exposure controls: The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use in the following format Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection 26/50

27 Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 3. Estimation of exposures and calculation methods Environmental exposure Worker exposure It not expected exposure of workers in the event of implementation of the measures set out in section 2 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 27/50

28 ES 6 Use as a chemical process and / or intermediate 1. Title of exposure scenario Use as a chemical process and / or intermediate Sectors of end-use Chemical Product Category: SU8,SU9,SU13 PC19, PC21 Environment: Manufacture of substances ERC 1 Formulation of preparations* ERC 2 Formulation in materials ERC 3 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) Industrial use of reactive processing aids ERC 6a ERC 6b Uso industriale di sostanze in sistemi chiusi ERC 7 Wide dispersive outdoor use of articles and durable materials with low release Wide dispersive indoor use of articles and long lasting materials with low release ERC 10a ERC 11a Workers Use in closed process, no likelihood of exposure PROC 1 Uso in un processo chiuso e continuo, con occasionale esposizione controllata PROC 2 Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilities Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8a PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 28/50

29 Treatment of articles by dipping and pouring PROC 13 Production of preparations* or articles by tabletting, compression, extrusion, pelletisation PROC 14 Use as laboratory reagent PROC 15 Handling of solid inorganic substances at ambient temperature PROC Conditions of use that modify exposure 2.1 Environmental exposure controls: The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use in the following format Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 29/50

30 3. Estimation of exposures and calculation methods Environmental exposure Worker exposure It not expected exposure of workers in the event of implementation of the measures set out in section 2 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 30/50

31 ES 7 Use in the preparation of the pulp, paper, cardboard 1. Title of exposure scenario Use in the preparation of the pulp, paper, cardboard Sectors of end-use Chemical Product Category: Article categories SU6a,SU6b PC20, PC26 AC8 Environment: Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) Industrial use of reactive processing aids ERC 6a ERC 6b Uso industriale di sostanze in sistemi chiusi ERC 7 Wide dispersive indoor use of processing aids in open systems Wide dispersive indoor use which results in the inclusion in a matrix or onto a matrix Transfer of substance or preparation into small containers (dedicated filling line, including weighing) Wide dispersive indoor use of articles and long lasting materials with low release ERC 8a ERC 8c ERC 9a ERC 11a Workers Use in closed process, no likelihood of exposure PROC 1 Use in closed, continuous process with occasional controlled exposure PROC 2 Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 31/50

32 Use as laboratory reagent PROC 15 Hand-mixing with intimate contact and only PPE available PROC Conditions of use that modify exposure 2.1 Environmental exposure controls: The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use in the following format Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 3. Estimation of exposures and calculation methods 32/50

33 Environmental exposure Worker exposure It not expected exposure of workers in the event of implementation of the measures set out in section 2 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 33/50

34 ES 8 Use as a cleaning agent 1. Title of exposure scenario Use as a cleaning agent Sectors of end-use Chemical Product Category: NA PC35 Environment: Manufacture of substances ERC 1 Formulation of preparations* ERC 2 Formulation in materials ERC 3 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) Industrial use of reactive processing aids Wide dispersive outdoor use of articles and durable materials with low release Wide dispersive indoor use of articles and long lasting materials with low release ERC 6a ERC 6b ERC 10a ERC 11a Workers Use in closed, continuous process with occasional controlled exposure PROC 2 Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 Use as laboratory reagent PROC Conditions of use that modify exposure 34/50

35 2.1 Environmental exposure controls: The aluminum and its soluble compounds are not classified as dangerous for the environment. Aluminum is the most common element in nature (8% of the earth s crust) and is found in large quantities in terrestrial environments and sediments. The relative contribution of the aluminum anthropogenic to natural deposits of aluminum is very low, and therefore, is irrelevant in terms of quantity provided that in terms of toxicity. 2.2 Exposure control of workers Skin corrosion and serious eye damage are the most significant effects on human health identified in the evaluation of chemical safety. For this type of effects you can not get a dose-effect relationship; risk management is then entrusted to a qualitative assessment involving the use of technical measures and personal protective equipment appropriate to protect the health of workers The measures identified may be distinguished according to the physical state and the classification of the product in use in the following format Liquid H315 Handle substance within a closed system Provide for the installation of local exhaust at points of emission Wear a protective mask complies with EN 140 with filter type A or higher in the case of formation of vapor and / or aerosols Wear gloves tested to EN374 and eye protection Apply all the rules of good hygiene in the workplace Implement control procedures for the proper management of the technical and operational conditions required 3. Estimation of exposures and calculation methods Environmental exposure Worker exposure 35/50

36 It not expected exposure of workers in the event of implementation of the measures set out in section 2 4. Guide for the conformity assessment of the use of DU against the terms established in the scenario - fitting parameters of the use of the substance in relation to the specific individual conditions (scaling) Environmental exposure Worker exposure Input parameters to perform scaling: Warnings to perform scaling 36/50

37 ES 9 Use as a flame retardant 1. Title of exposure scenario Use as a flame retardant Sectors of end-use Chemical Product Category: Article categories SU8, SU 9, SU19 PC9b, PC19 AC 4, AC 5, AC7, AC8, AC10, AC11, AC13 Environment: Manufacture of substances ERC 1 Formulation of preparations* ERC 2 Formulation in materials ERC 3 Industrial use of processing aids in processes and products, not becoming part of articles ERC 4 Industrial use resulting in inclusion into or onto a matrix ERC 5 Industrial use resulting in manufacture of another substance (use of intermediates) Industrial use of reactive processing aids Wide dispersive outdoor use of articles and durable materials with low release Wide dispersive indoor use of articles and long lasting materials with low release ERC 6a ERC 6b ERC 10a ERC 11a Workers Use in closed, continuous process with occasional controlled exposure PROC 2 Use in closed batch process (synthesis or formulation) PROC 3 Use in batch and other process (synthesis) where opportunity for exposure arises PROC 4 Mixing or blending in batch processes for formulation of preparations* and articles (multistage and/or significant contact) PROC 5 Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilities PROC 8b Transfer of substance or preparation into small containers (dedicated filling line, including weighing) PROC 9 Treatment of articles by dipping and pouring PROC 13 37/50