: Maleic Acid Solution

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1 Date of issue: 06/11/2013 Revision date: 06/11/2013 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name. Product code : Mixtures : Maleic Acid Solution : LPD110L 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet : Laboratory chemical SIRCHIE Finger Print Laboratories 100 Hunter Place Youngsville, NC - USA T ; F ; Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) No data available : None under normal conditions. SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable Full text of H-phrases: see section Mixtures Name Product identifier % Classification (GHS-US) AQUA (CAS No) Not classified Maleic Acid (CAS No) Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Non-hazardous as defined in 29 CFR Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use Indication of any immediate medical attention and special treatment needed 06/11/2013 EN (English US) Page 1

2 SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : No reactivity hazard other than the effects described in sub-sections below Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight Exposure controls Personal protective equipment : Gloves. Safety glasses. Hand protection Eye protection Respiratory protection : Wear protective gloves. : Chemical goggles or safety glasses. : Wear appropriate mask. : Do not eat, drink or smoke during use. 06/11/2013 EN (English US) 2/6

3 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Color Odor Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity : Liquid : Clear, colorless liquid. : colorless. on odour. : Soluble in water. No reactivity hazard other than the effects described in sub-sections below Chemical stability Stable under recommended handling and storage conditions (see section 7) Possibility of hazardous reactions Conditions to avoid None under recommended storage and handling conditions (see section 7) Incompatible materials Strong acids. Strong bases Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity 708 mg/kg (Rat) 1560 mg/kg (Rabbit) Based on available data, the classification criteria are not met 06/11/2013 EN (English US) 3/6

4 Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met Based on available data, the classification criteria are not met : Based on available data, the classification criteria are not met. SECTION 12: Ecological information Toxicity LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 TLM fish 1 TLM fish mg/l (48 h; Gambusia affinis) 316 mg/l (48 h; Daphnia magna) 5 mg/l (96 h; Pimephales promelas) 240 ppm (48 h; Gambusia affinis; Fresh water) 5 ppm (96 h; Pimephales promelas; Fresh water) Persistence and degradability Maleic Acid Solution Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oyxgen demand (COD) ThOD BOD (% of ThOD) 0.38 g O²/g substance 0.83 g O²/g substance 0.83 g O²/g substance 38 % ThOD Bioaccumulative potential Maleic Acid Solution Bioaccumulative potential BCF fish 1 < 10 (72 h; Leuciscus idus) BCF other aquatic organisms 1 11 (24 h; Chlorella sp.) Log Pow Bioaccumulative potential Low potential for bioaccumulation (BCF < 500) Mobility in soil Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number Not applicable UN proper shipping name Not applicable Additional information : No supplementary information available. Overland transport 06/11/2013 EN (English US) 4/6

5 Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations US State regulations SECTION 16: Data sources Training advice : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labeling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : Normal use of this product shall imply use in accordance with the instructions on the packaging. : None. Full text of H-phrases: see section 16: Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category H302 Harmful if swallowed H312 Harmful in contact with skin NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical Personal Protection : 1 Slight Hazard - Irritation or minor reversible injury possible : 0 Minimal Hazard : 0 Minimal Hazard : B SDS US (GHS HazCom 2012) 06/11/2013 EN (English US) 5/6

6 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, expressed or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigation to determine the suitability of the information for their particular purposes. 06/11/2013 EN (English US) 6/6

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