FFB 716. Version 21 Revision Date 2012/10/29 Print Date 2013/03/02

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material-Number : 7540 MSDS Number : Product Use Description : Raw material / additive / pigment / auxiliary material for chemical processes and technical applications Raw material for industry Binder Company : Chemische Fabrik Budenheim KG Rheinstraße 27 Budenheim Telephone : Telefax : Emergency telephone number : +49(0) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form: powder, Colour: white, Odour: odourless OSHA Hazards : COMBUSTIBLE DUST SEVERE EYE IRRITANT Carcinogenicity: IARC OSHA NTP ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components SECTION 4. FIRST AID MEASURES First aid procedures 1 / 8

2 General advice If inhaled In case of skin contact In case of eye contact If swallowed : Move out of dangerous area. : If breathed in, move person into fresh air. If symptoms persist, call a physician. : Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. If symptoms persist, call a physician. : Immediately flush eye(s) with plenty of water. If eye irritation persists, consult a specialist. : Obtain medical attention. Rinse mouth with water. SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point Fire fighting Suitable extinguishing media Further information : Remarks: not applicable : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Protective equipment and precautions for firefighters Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for containment / Methods for cleaning up : Use personal protective equipment. Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. : Do not flush into surface water or sanitary sewer system. : Use mechanical handling equipment. Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE 2 / 8

3 Handling Handling Advice on protection against fire and explosion Storage Requirements for storage areas and containers : Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. : Normal measures for preventive fire protection. : Keep container tightly closed in a dry and well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components CAS-No. Value Control Update Basis parameters aluminium TWA 2 mg/m OSHA P0 tris(dihydrog en 50-2 TWA 2 mg/m NIOSH REL Further information : Aluminium Engineering measures Personal protective equipment Eye protection : Tightly fitting safety goggles Hand protection : Polyvinyl alcohol or nitrile- butyl-rubber gloves The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. The suitability for a specific workplace should be discussed with the producers of the protective gloves. Skin and body protection Respiratory protection Hygiene measures : Dust impervious protective suit : In the case of dust or aerosol formation use respirator with an approved filter. : Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. 3 / 8

4 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour Safety data Flash point ph Melting point/range Boiling point/boiling range Bulk density : powder : white : odourless : Note: not applicable : at g/l 20 C : 3,092 F (1,700 C) : Note: no data available : 500 kg/m3 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Hazardous decomposition products Hazardous reactions : Remarks: no data available : Note: No decomposition if stored and applied as directed. : No dangerous reaction known under conditions of normal use. SECTION 11. TOXICOLOGICAL INFORMATION Acute oral toxicity : LD50: > 2,000 mg/kg Species: rat Method: Fixed Dose Method Acute inhalation toxicity : LC50: > 5.1 mg/l Exposure time: 4 h Species: rat Method: OECD Test Guideline 403 Acute dermal toxicity : LD50: > 4,640 mg/kg Species: rabbit Method: OECD Test Guideline 402 Skin irritation : Remarks: May cause skin irritation in susceptible persons. 4 / 8

5 Eye irritation : Remarks: Product dust may be irritating to eyes, skin and respiratory system. Sensitisation : Remarks: no data available 12. ECOLOGICAL INFORMATION Toxicity to fish : LC50: > 100 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) Method: OECD Test Guideline 203 NOEC: 100 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50: > 100 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Method: OECD Test Guideline 202 Biodegradability : Remarks: not applicable Further information on ecology Additional ecological information SECTION 13. DISPOSAL CONSIDERATIONS : There is no data available for this product. Further information Contaminated packaging : Offer surplus and non-recyclable solutions to a licensed disposal company. : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION DOT 5 / 8

6 TDG IATA IMDG RID SECTION 15. REGULATORY INFORMATION OSHA Hazards : Combustible dust, Severe eye irritant Canadian PBT Chemicals : CERCLA Reportable : Quantity This material does not contain any components with a CERCLA RQ. SARA 302 Reportable : Quantity SARA 311/312 Hazards : Acute Health Hazard SARA 302 Reportable Quantity This material does not contain any components with a SARA 302 RQ. SARA 304 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any components with a section 304 EHS RQ. SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act Ozone-Depletion Potential : This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR , Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR ). Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. 6 / 8

7 This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table Remarks Pennsylvania Right To Know Components : No components are subject to the Massachusetts Right to Know Act. : New Jersey Right To Know Components : California Prop. 65 Components : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: REACH CH INV US.TSCA : On TSCA Inventory DSL : All components of this product are on the Canadian DSL list. AICS NZIoC : Not in compliance with the inventory ENCS ISHL KECI PICCS IECSC SECTION 16. OTHER INFORMATION Further information HMIS Classification : Health hazard: 3 Flammability: 3 Physical hazards: 0 NFPA Classification : Health hazard: 2 Fire Hazard: 3 Reactivity Hazard: / 8

8 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by: : Department EHS 8 / 8