Safety Data Sheet. Prepared for: Anchor Drilling Fluids USA, Inc East 61 st Street, Suite 710 Tulsa, Oklahoma

Transcription

1 Safety Data Sheet Prepared for: Anchor Drilling Fluids USA, Inc East 61 st Street, Suite 710 Tulsa, Oklahoma August 11, 2014 Section 1: Identification Identification of the chemical as well as the recommended uses and the essential contact information of the supplier. Product Identifier: Drill-Sure OBM Additive Common Name(s): Drill-Sure OBM Chemical Family: UVCB Synonyms: Drilling Mud Additive, HTHP Fluid Loss Additive Manufacturer, Importer, and/or Responsible Party Information Name: Chevron Phillips Chemical Company, L.P.- Product Safety and Toxicology Group Address: Six Pines Drive, The Woodlands, Texas Phone Number: Emergency Phone Number: (North America) (International) Recommended Use of Chemical Chemical Services: Drilling mud additive Use Restrictions: Section 2: Hazard(s) Identification Identification of the hazards of the chemical presented and the appropriate warning information associated with those hazards. Hazard Classification: Signal Word: Warning Not a hazardous substance or mixture according to Regulation EC No Hazard Statement(s): 1272/2008 and EC-directives 67/548/EEC. Pictogram(s): Precautionary Handle in accordance with all precautions stated within this SDS. Statement(s): Description of any hazards not otherwise classified: Mixture Identification (if toxicity is unknown) Percentage of the mixture consisting of ingredient(s) with unknown toxicity: Note: this is a total percentage of the mixture and not tied to the individual ingredient(s).

2 Section 3: Composition/Information on Ingredients Identification of the ingredient(s) contained in the product, including impurities and stabilizing additives. This section includes information on substances, mixtures and all chemicals where a trade secret is claimed. Substances Product is a mixture. Mixtures Product is proprietary. Recommended Use of Chemical Chemical Services: Use Restrictions: Drilling mud additive Trade Secret Is the specific chemical identity and/or exact concentration of composition withheld as a trade secret? Yes Section 4: First-Aid Measures Description of the initial care that should be given by untrained responders to an individual who has been exposed to the chemical. Necessary first-aid instructions If unconscious place in recovery position and seek medical advice. If symptoms Inhalation: persist, call a physician. Acute Symptoms of Inhalation: Possible irritation Delayed Symptoms of Inhalation: known Skin Contact: Not an irritant Acute Symptoms of Skin Contact: known Delayed Symptoms of Skin Contact: known Eye Contact: Remove contact lenses. If eye irritation persists, consult a physician. Acute Symptoms of Eye Contact: Possible irritation Delayed Symptoms of Eye Contact: known Keep respiratory tract clear. Never give anything by mouth to an unconscious Ingestion: person. If symptoms persist, call a physician. Acute Symptoms of Ingestion: Possible irritation Delayed Symptoms of Ingestion: known Immediate Medical Care / Special Treatment Is immediate medical care or special treatment required? No If so, what is needed: Section 5: Fire-Fighting Measures Recommendations for fighting a fire caused by or including the chemical. Suitable Extinguishing Use extinguishing measures that are appropriate to Equipment: local circumstances and the surrounding environment. Extinguishing equipment not appropriate:

3 Specific hazards created from chemical burning: Special protective equipment needed: Provide appropriate exhaust ventilation at places where dust is formed Wear self contained breathing apparatus Section 6: Accidental Release Measures Recommendations on the appropriate response to spills, leaks, or releases; including containment and cleanup practices to prevent or minimize exposure to people, properties, or the environment. Personal Precautions: Avoid dust formation Emergency Alert authorities if product contaminates rivers, lakes or drains Procedure(s): Method(s) and material(s) used for containment: Cleanup procedure(s): Product is a solid, utilize brooms, vacuums, shovels, etc. Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. Section 7: Handling and Storage Guidance on the safe handling practices and conditions for safe storage of the chemical. Handling precautions: Handle without creating dust Hygiene practices: Smoking, eating and drinking should be prohibited near product. Normal hygiene practices are sufficient. Safe storage recommendation: Electrical installations / working materials must comply with the technological safety standards. Incompatible storage options: No materials to be especially mentioned. Section 8: Exposure Controls/Personal Protection Identification of the exposure limits, engineering controls, and personal protective measures that can be used to minimize worker exposure. OSHA Permissible LD50: > 50,000 mg/kg (acute oral toxicity) Exposure Limits (PELs): American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs): Exposure limit (recommended by LD50: > 50,000 mg/kg (acute oral toxicity) manufacturer, importer or employer): Appropriate Engineering Controls: Recommendations for personal protective measures: Respiratory: Hand: Normal controls are sufficient. Wear NIOSH approved respirator unless ventilation or other engineering controls are adequate to maintain minimal oxygen content of 19.5% by volume under normal atmospheric pressure. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

4 Eye: Skin & Body: Special requirements of PPE, protective clothing or respirators: Wear safety glasses. Work station should be equipped with eye was station or eye was bottle with pure water. Lightweight protective clothing See chart above Section 9: Physical and Chemical Properties Identification of physical and chemical properties associated with the substance or mixture. Appearance (Physical State): Fine Powder Color: Dark Brown, Black Odor: Odor Threshold: Not regulated Vapor Pressure: Vapor Density: ph: Relative Density: 1,4 1,6 Melting Point: Freezing Point: Solubility(ies): Partly soluble in water Initial Boiling Point: Boiling Range: Flash Point: Evaporation Rate: Flammability: Upper/lower flammability or explosive limits: Partition Coefficient: Auto-Ignition Temperature: Decomposition Temperature: Viscosity: Section 10: Stability and Reactivity Description of the reactivity hazards of the chemical and the chemical stability information. Reactivity Description of specific test data: Is the chemical stable or unstable: Stabilizers needed to maintain chemical stability: Safety issues that may arise should the chemical change in physical appearance: Chemical Stability This material is considered stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. known Other

5 Conditions in which hazardous reactions may known occur: Possibility of hazardous Low reactions: Will chemical react or No polymerize: Will chemical release pressure, heat, or any other hazardous known conditions: Conditions to known avoid: Class(es) of incompatible known material(s): Known or anticipated hazardous decomposition products produced because of storage, use, or heating: Section 11: Toxicological Information No decomposition if stored and applied as directed Identification of toxicological and/or health effects. Likely routes of Skin/eye contact and/or inhalation exposure: Delayed, immediate or chronic effects of short-term May cause irritation exposure: Delayed, immediate or chronic effects of long-term known exposure: Numerical measurement of LD50: > 50,000 mg/kg (acute oral toxicity) toxicity: Description of symptoms (lowest to Possible irritation most severe): Repeated dose toxicity: Reproductive toxicity: Species: rat Sex: male Application Route: oral Dose: 0, 250, 500, 1000 mg/kg Exposure Time: 43 D Number of Exposures: daily NOEL: 1,000 mg/kg Method: OECD Guideline 422 Species: rat Sex: male and female Application Route: oral gavage Dose: 2, 250, 500, 1000 mg/kg Exposure Time: D Number of Exposures: daily Method: OECD Guideline 422 NOAEL Parent: 1,000 mg/kg NOAEL F1: 1,000 mg/kg

6 Developmental toxicity: Toxicology Assessment: fertility. Is chemical listed in the National Toxicology Program (NTP) Report on Carcinogens: Has chemical been found to be a potential carcinogen in the International Agency for Research on Cancer (IARC) Monographs: Species: rat Application Route: oral gavage Dose: 1, 250, 500, 1000 mg/kg Number of Exposures: daily Test Period: 54 D NOAEL Teratogenicity: 1,000 mg/kg NOAEL Maternal: 1,000 mg/kg Carcinogenicity: not available Mutagenicity: Tests on bacterial or mammalian cell structures did not show mutagenic effects. Teratogenicity: Animal testing did not show any effects on fetal development. Reproductive toxicity: animal testing did not show any effects on Has chemical been found to be a potential carcinogen by OSHA: No ingredient of this product present at levels 0.1% is identified as a known or anticipated carcinogen by NTP. No ingredient of this product present at levels 0.1% is identified as probable, possible or confirmed carcinogen by IARC. No Section 12: Ecological Information (non-mandatory) Information to evaluate the environmental impact of the chemical if it were released to the environment. LC50: > 240 mg/l Exposure Time: 96 h Toxicity to fish: Species: Scophthalmus maximus (Flatfish, Flounder) semi-static test Method: OECD Test Guideline 203 LC50: 380 mg/l Toxicity to daphnia and Exposure Time: 48 h other aquatic invertebrates: Species: Acartia tonsa (Marie Copepod) Static test Toxicity to algae: Toxicity test results performed on aquatic and/or terrestrial organisms: EC50: 240 mg/l Exposure Time: 72 h Species: Skeletonema costatum (Marine Algae) Static test Does the chemical have the potential to degrade the environment (biodegradation, oxidation, hydrolysis, etc.): Bioaccumulation test results: Potential of chemical moving from soil to the groundwater: This material is not expected to be harmful to aquatic organisms. No Low possibility. Product is a solid and therefore cannot penetrate soil, also is not very soluble in water

7 Other adverse effects: known Section 13: Disposal Considerations (non-mandatory) Guidance on proper disposal practices, recycling or reclamation of the chemical or its container. Safe handling practices to minimize exposure. (Refer to section 8 for more information) Appropriate disposal Original container or similar container (clean) containers: Appropriate disposal methods: Material may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility. Physical and chemical properties Not soluble in water that may affect disposal activities: Special precautions for landfills or incineration activities: Is it advisable to utilize sewage disposal for this No chemical: Section 14: Transport Information (non-mandatory) Guidance on classification information for shipping and transporting the chemical by road, air, rail, or sea. This product is not a DOT/IMO Hazardous Material.

8 Section 15: Regulatory Information (non-mandatory) Identification of safety, health and environmental regulations specific for the chemical that is not indicated anywhere else on this SDS. Chemical Weapons Convention (CWC): This product does not contain any chemicals listed under the CWC schedules of chemicals. Clean Air Act - Hazardous Air Pollutants (HAP): This product does not contain any chemicals listed within the Hazardous Air Pollutants. Clean Air Act - Ozone Depleting Substances (ODS): This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpart A, App. A+B). Clean Air Act - Accidental Release Prevention: This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR , Subpart F). Clean Air Act - Intermediate or Final VOC s: This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC s (40 CFR ). Clean Water Act - Priority Pollutants (PP): This product does not contain any PP listed under the U.S. Clean Water Act Section 307 (2)(1) PP List (40 CFR ). Occupational Safety and Health Act (OSHA): The OSHA Hazard Communication Standard (29 CFR ) defines this chemical as C.4.3 Acute Toxicity - Inhalation: Hazard Category 3. For more information, see Section 2 of this SDS. Resource Conservation and Recovery Act (RCRA): This product is not considered to be a P or U listed hazardous waste under RCRA (40 CFR 261). Superfund Amendments and Reauthorization Act (SARA) Title III: Section Extremely Hazardous Substances (EHS): This product does not contain any chemicals regulated under Section 302 (40 CFR 355) as extremely hazardous substances. Superfund Amendments and Reauthorization Act (SARA) Title III: Section CERCLA: This product does not contain any chemicals regulated under Section 304 (40 CFR 302) as hazardous substance(s) for emergency release notification. Superfund Amendments and Reauthorization Act (SARA) Title III: Section 311/312 - Hazard Communication Standard (HCS): This product is not regulated under Section (40 CFR 370). Superfund Amendments and Reauthorization Act (SARA) Title III: Section 313 Toxic Chemical List (TCL): This product does not contain any chemicals for routine annual toxic chemical release reporting under Section 313 (40 CFR 372). TSCA Section 5(e) - Consent Order / SNUR: This product is not subject to a Section 5(3) Consent Order for Significant New use Rule (SNUR). TSCA Section 8(b) - Inventory Status: All chemical(s) comprising this product are either exempt or not listed on the TSCA inventory. TSCA Section 12(b) - Export Notification: This product does not contain any chemical(s) that are subject to a Section 12(b) export notification. Items in red require immediate attention.

9 Section 16: Other Information Date of SDS Preparation: August 11, 2014 Revision Date: Changes from previous version: US State Regulations: Other useful information: Pennsylvania Right to Know and New Jersey Right to Know Asphalt, Sulfonated, Sodium Salt California Prop. 65 Ingredients This product does not contain any chemicals know to the State of California to cause cancer, birth or any other reproductive defects. We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind, expressed or implied, and we assume no responsibility for any damage or expense.