YARA Environmental Technologies GmbH

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1 YARA Environmental Technologies GmbH

2 SAFETY IS ALWAYS OUR TOP PRIORITY Ambition of zero injuries to people and no major process related incidents Product stewardship program Production according to high technical standards Reliable transport and shipping concepts Best practice sharing on storage and handling with partners and customers 2

3 KEY NUMBERS Revenues and other income (2014) USD 15.1 billion Number of employees Located in more than 50 countries Sales to more than 150 countries

4 YARA PRODUCTS AND SOLUTIONS SHARE A COMMON PLATFORM Ammonia Urea Nitric acid CORE PRODUCTS Urea Nitrates CN NPK Nitric acid Gases PRODUCT BRANDS AND APPLICATIONS Global fertilizer brands Environmental solutions Industrial applications 4

5 WE SERVE A WIDE RANGE OF CUSTOMERS through an extensive offering End users Yara value proposition Yara competitive edge Automotive Trucks Off-road vehicles Cars Reagent AdBlue: High-quality urea solution Technology Services Dispensing bulk equipment Telemetry Training Global reach Strong market infrastructure Stationary Power plants Cement factories Waste Incinerators NOxCare: high-quality urea solution and ammonia solution SCR Technology SNCR Technology Hybridsystems Optimization of operations, emissions reduction, safety and performance improvement Reliable supply Proximity to customers High-quality products Marine Cruise and ferries Coast-near vessels Deep sea vessels NOxCare40: High purity urea solution SCR Technology SOx scrubbers Design and engineering Commissioning Operational training Safety training Maintenance Spare-parts Proven technology Strong Yara brand 5

6 FULL SERVICE PROVIDER Go for the most cost efficient system to abate NOx and control and optimize your CAPEX and OPEX costs over lifetime by choosing Yara. 6

7 30 YEARS OF WORLDWIDE EXPERIENCE We work on a global scale with references in all major continents 7 North America Europe India Taiwan/ China South America 7

8 ACQUISITION 8

9 FIRST ORDERS In the Cement Industry the first orders for SNCR DeNOx systems have been placed (kiln installations). YARA won 3 projects. Birla Corporation Chanderia Birla Corporation Satna Aliacem Lukavac 9 9

10 FIRST QUALIFIED BHEL (TRICHY) VENDOR 10 10

11 NTPC SNCR / SCR / HYBRID PILOT TESTING Rihand Power Plant 11 11

12 DeNOx Technology

13 REFERENCE PROJECTS Power Plants & Boilers EL-SEGUNDO NEM / Siemens Project location: USA, California Natural Gas SCR in HRSG after Gas Turbine ŁAZISKA TAURON Wytwarzanie S.A. Project location: Poland Pulverized Coal High Dust SCR Integrated in ECO 79% Simmering Wienstrom 38% Project location: Austria 20% 17% Heavy Fuel Oil & Natural Gas High Dust SCR Integrated in ECO Voitsberg ODK Project location: Austria Lignite High Dust SCR 13

14 14 REFERENCE PROJECTS Industrial Boilers Yan San SINOPEC Project location: China Coal Slurry High Dust SCR 79% LP1 & 2 FPG 38% Project location: Taiwan 20% Pulverized Coal High Dust SCR 17% Synthos Chemoservies Project location: Poland Pulverized Coal SNCR for PC firing Shell GTL Plant Aalborg Project location: Qatar Various gaseous fuels SCR integrated in ECO

15 REFERENCE PROJECTS Chemical Storage & Handling Systems Edwards Scope: Anhydrous Ammonia System for DeNOx application Lurgi Lentjes North America Project location: USA 79% Daxing Guanyinsi Scope: Urea to Ammonia system for 38% DeNOx application 20% 17% Tongfang Environmental Co. Project location: China Rabigh Scope: Anhydrous Ammonia System for SO 3 removal application ALSTOM K.K. Project location: KSA Bialystok Scope: Ammoniawater (25 %wt.) for DeNOx application ENEA Wytwarzanie S.A Project location: Poland 15

16 REFERENCE PROJECTS Catalyst Rejuvenation 79% 38% Project: Simmering Wienstrom Country: Austria 20% Heavy Fuel Oil Catalyst Type: Honeycomb 17% 79% 38% Project: Taichung Taiwan Power Company Country: Taiwan 20% 17% Coal Catalyst Type: Plate Project: Mucha Taipei City Government Country: Taiwan Municipal Waste Catalyst Type: Honeycomb Project: Bowen Southern Company Country: USA Coal Catalyst Type: Honeycomb 16

17 ANHYDROUS AMMONIA SYSTEM 17

18 AMMONIAWATER EVAPORATION BY USING GAS/GAS HEATER TECHNOLOGY OF YARA 18

19 NOxCare SNCR system 19 Process control Reagent mixing & distribution Combustion chamber / Boiler Storage Tank CMM PU reagent injection PMR PMW Unloading pump PMR = Pump module for reagent PMW = Pump module for water

20 NOxCare Hybrid System 20 Process control Reagent mixing & distribution Combustion chamber / Boiler Gas analyzers NO x NH 3 CMM Storage Tank PU reagent injection GAS Cat. MIXER module module PMR PMW Unloading pump PMR = Pump module for reagent PMW = Pump module for water primary reagent injection secondary reagent injection Soot blowing module

21 21 SCR Technology Main Chemical Reaction for NOx Removal: NOx + NH3 N2 + H2O Honeycomb Type Plate Type

22 22 CFD Design and Optimization CFD Design and Optimization is performed for: Ammonia injection system Ammonia distribution Flue gas flow distribution Optimization of flow pattern and pressure drop Optimization of temperature distribution Optimization of fly ash distribution (prevent plugging)

23 23 Ammonia Injection Grid (AIG) ADVANCED AIG DESIGN NOZZLE / MIXER TYPE YARA PATENT

24 DeSOx Technology

25 REFERENCE PROJECTS Marine & Engine Applications LNG Tanker Diesel, HFO, MDO, Gas Technology: Wet Scrubber 79% 38% Seismic Vessel HFO 20% 17% Technology: Wet Scrubber Cruise Liner Natural Gas, MDO, HFO Technology: Wet Scrubber Island Power Plant BWSC Project location: Malta Land Engine Technology: SCR 25

26 REFERENCE PROJECTS Industrial Boilers Zhejiang Sinosteel Project location: China Coal, Municipal Waste & Sludge Semi-Dry Scrubber + Bag Filter Durnrohr EVN Project location: Austria Municipal Waste Wet Scrubber + Bag Filter 79% Luoyang Longyu Power Scale: 2x260t/h 38% Project location: China 20% 17% coal FGD Chengde Dongsheng Power Scale: 1x180t/h Project location: China coal FGD 26

27 REFERENCE PROJECTS Power Plants & Boilers Datang Linfen Power Scale: 2x300MW Project location: China coal FGD Guo hua Jinjie Power Scale: 2x600MW 79% Project location: 38% China coal FGD 20% 17% Xinjiang Qiya Power Scale: 4x360MW Project location: China coal FGD DaTang Wangtan Power Scale: 2x600MW 79% Project location: 38% China coal FGD 20% 17%

28 DESULPHURIZATION WITH HIGHLY EFFICIENT LOW ENERGY CONSUMPTION Technical advantages Gas-liquid Coupler The location of gas-liquid coupler Simple system,no rotating equipment, free maintenance, stable running Uniform Air-flow distribution to avoid bias flow and short circuit, gas-liquid collision frequency is enhenced Double cyclone to prevent slurry spraying uniform from gas-flow damage Flow gas is fast cooled, which provid appropriate temperature for reaction Gas- liquid ratio and energy consumption reduced, at least one circulating pump reduced 28 28

29 DESULPHURIZATION WITH HIGHLY EFFICIENT LOW ENERGY CONSUMPTION With the increasing of flow rate, spray desulfurization efficiency gradually reduce and gas-liquid coupler desulfurization efficiency increase, as a result the efficient is complemented. Desulfurizer equipped with the spray layer and gasliquid coupler can realize the stability of desulfurization efficiency. The change of desulfurization efficiency with the load 29 29

30 TECHNICAL PRINCIPLES OF CYCLONE DEDUSTING DEMISTER Cyclone Dedusting Demister is composed of four cyclone units. Its working principle is that when the clean gas enters demister, it carries a lot droplet which is generated in Wet Desulfurization and is composed of slurry, condensate and dust. It is rotated by cyclone unit to form revolve and perturbation, because of the collision among particles, big droplets which are made of ultra-fines are born. In the same time, big droplets flow along the wall of the round pipe under pressure of centrifugation and are caught by liquid film, and high efficiency dedusting and demisting is realized

31 HIGH EFFICIENT CYCLONE DEDUSTING Technical advantages Cyclone Dedusting Demister System resistance increased only 200Pa Droplet less-than 15mg/Nm³, dust less-than 5mg/Nm³ Low energy consumption, no electricity, low operation fare Easy transformation, short period, low investment Simple system, easy operation and good reliability Polymer with higher corrosion and wear resistance, 30 years life 31 31

32 TECHNICAL PRINCIPLES OF CYCLONE DEDUSTING DEMISTER Advantages of Cyclon Dedusting in engineering Reusing the demister position without structural change Reusing the washing system without auxiliary equipment Mechanical construction design, non-clog, free maintenance Short construction period, less than 15 days for a unit Polymer with corrosion, wear resistance, antiaging and fire retardant Low expansion, without leaks System resistance less than 400Pa Secondary blowing dust avoided 70% washing water of general demister Upper water flushing, easy overhaul 32 32

33 Customers

34 Reference Projects Yara Marine Technologies has delivered more than 100 scrubber systems Yara Marine Technologies has more than running hours on their systems

35 杭锅集团

36 36

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