2 Hazards identification

Transcription

1 Page 1/7 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: , CAS Number: EC number: Index number: Registration number xxxx Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Application of the substance / the preparation Oxidant Manufacturer/Supplier: Grünbeck Wasseraufbereitung GmbH Josef-Grünbeck-Str. 1 D Höchstädt a.d. Donau GERMANY gefahrstoff@gruenbeck.de Further information obtainable from: Product safety department Tel Fax Emergency telephone number: During normal opening times: Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS03 flame over circle Ox. Sol. 2 H272 May intensify fire; oxidiser. GHS09 environment Aquatic Acute 1 H400 Very toxic to aquatic life. Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. GHS07 Acute Tox. 4 H302 Harmful if swallowed. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R22: Harmful if swallowed. O; Oxidising R8: Contact with combustible material may cause fire. N; Dangerous for the environment R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Information concerning particular hazards for human and environment: Not applicable. (Contd. on page 2)

2 Page 2/7 Label elements Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. Hazard pictograms (Contd. of page 1) GHS03 GHS07 GHS09 Signal word Danger Hazard-determining components of labelling: potassium permanganate Hazard statements H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H410 Very toxic to aquatic life with long lasting effects. Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P221 Take any precaution to avoid mixing with combustibles. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P220 Keep/Store away from clothing/combustible materials. P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment. P264 Wash thoroughly after handling. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Substances CAS No. Description Identification number(s) EC number: Index number: * 4 First aid measures Description of first aid measures General information: Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. Protect unharmed eye. After swallowing: Call for a doctor immediately. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. (Contd. on page 3)

3 Page 3/7 Indication of any immediate medical attention and special treatment needed No further relevant information available. (Contd. of page 2) 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Product itself does not burn CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * 7 Handling and storage Handling: Precautions for safe handling No special precautions are necessary if used correctly. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Store only in the original receptacle. Information about storage in one common storage facility: Store away from flammable substances. Further information about storage conditions: Protect from heat and direct sunlight. Storage class: 5.1 B - Substances causing ignition (oxidation) 5.1 B Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: AGW (Germany) 0,5E mg/m³ DFG,Y,10 Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. (Contd. on page 4)

4 Page 4/7 Respiratory protection: Not required. Protection of hands: (Contd. of page 3) Protective gloves Material of gloves Nitrile rubber, NBR Penetration time of glove material Value for the permeation: Level 480 min Eye protection: Tightly sealed goggles 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Crystalline Colour: Violet Odour: Odourless ph-value: Not determined. Change in condition Melting point/melting range: >240, Zers. C Boiling point/boiling range: Undetermined. Flash point: Not applicable. Flammability (solid, gaseous): Contact with combustible material may cause fire. Danger of explosion: Explosive when mixed with combustible material. Vapour pressure at 20 C: 0 hpa Density at 20 C: 2,703 g/cm³ Solubility in / Miscibility with water at 20 C: 64,3 g/l Solvent content: Organic solvents: 0,0 % VOC (EC) 0,00 % Solids content: 100,0 % Other information No further relevant information available. 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat. Possibility of hazardous reactions Toxic fumes may be released if heated above the decomposition point. Reacts with flammable substances. Conditions to avoid Extreme temperatures and direct sunlight Incompatible materials: No further relevant information available. Hazardous decomposition products: Oxygen (Contd. on page 5)

5 Page 5/7 (Contd. of page 4) 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: Oral LD mg/kg (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. 12 Ecological information Toxicity Aquatic toxicity: LC50/96 h 7,52 mg/l (fish) Oral EC50/48h 0,08 mg/l (crustaceans) EC50/72h 0,45 mg/l (algae) Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. Ecotoxical effects: Remark: Very toxic for fish Additional ecological information: General notes: Water hazard class 3 (German Regulation) (Assessment by list): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. Very toxic for aquatic organisms Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. Recommended cleansing agents: Water, if necessary together with cleansing agents. * 14 Transport information UN-Number ADR, IMDG, IATA UN1490 UN proper shipping name ADR 1490 POTASSIUM PERMANGANATE, ENVIRONMENTALLY HAZARDOUS IMDG, IATA POTASSIUM PERMANGANATE (Contd. on page 6)

6 Page 6/7 Transport hazard class(es) ADR (Contd. of page 5) Class 5.1 Oxidising substances. Label 5.1 IMDG, IATA Class 5.1 Oxidising substances. Label 5.1 Packing group ADR, IMDG, IATA II Environmental hazards: Product contains environmentally hazardous substances: potassium permanganate Marine pollutant: No Special marking (ADR): Symbol (fish and tree) Special precautions for user Warning: Oxidising substances. Danger code (Kemler): 50 EMS Number: F-H,S-Q Segregation groups Permanganates Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport/Additional information: ADR Limited quantities (LQ) 1 kg Transport category 2 Tunnel restriction code E Not applicable. UN "Model Regulation": U N , P O T A S S I U M P E R M A N G A N A T E, 5. 1, I I, ENVIRONMENTALLY HAZARDOUS 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. Hazard pictograms GHS03 GHS07 GHS09 Signal word Danger Hazard-determining components of labelling: potassium permanganate Hazard statements H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H410 Very toxic to aquatic life with long lasting effects. (Contd. on page 7)

7 Page 7/7 (Contd. of page 6) Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P221 Take any precaution to avoid mixing with combustibles. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P220 Keep/Store away from clothing/combustible materials. P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment. P264 Wash thoroughly after handling. P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Department issuing MSDS: Laboratory Contact: Mrs. Gerstmeier Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organization ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent * Data compared to the previous version altered.