SAFETY DATA SHEET CITRIC ACID

Transcription

1 Revision Date Revision 03 1 / SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No , 1006, 10094, , , , 10180, , , , , , , , , , , , , , , Synonyms, Trade Names MONOHYDRATE, 2, HYDROXY-1, 2, 3 PROPANE TRICARBOXYLIC ACID, Citric acid 1-hydrate E330 REACH Registration number CAS-No EC No Relevant identified uses of the substance or mixture and uses advised against Identified uses Food industry Cosmetics Industrial application Detergent. Pharmaceuticals 1.3. Details of the supplier of the safety data sheet Supplier Univar Aquarius House 6 Midpoint Business Park Thornbury Bradford BD3 AY sds@univareurope.com 1.4. Emergency telephone number Emergency Contact Number (Office Hours) Emergency Contact Number (Outside Office Hours) Finnish only TOL1: C10, KT1: 26 Sds No SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture

2 2 / Classification (EC 122/2008) Physical and Chemical Not classified. Hazards Human health Eye Irrit. 2 - H319 Environment Not classified. Classification (6/548/EEC) Xi;R36. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section Label elements EC No Label In Accordance With (EC) No. 122/2008 Signal Word Hazard Statements Precautionary Statements 2.3. Other hazards Warning H319 Not Classified as PBT/vPvB by current EU criteria. Causes serious eye irritation. P280 Wear protective gloves/protective clothing/eye protection/face protection. P264 Wash skin thoroughly after handling. P IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P If eye irritation persists: Get medical advice/attention. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Product name REACH Registration number CAS-No EC No Composition Comments The data shown are in accordance with the latest EC Directives. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Rinse nose and mouth with water. Get medical attention if any discomfort continues. Ingestion Immediately rinse mouth and provide fresh air. Get medical attention if any discomfort continues.

3 3 / Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention Most important symptoms and effects, both acute and delayed Eye contact May cause severe irritation to eyes Indication of any immediate medical attention and special treatment needed No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Specific hazards Oxides of: Carbon Advice for firefighters Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with skin and eyes. Avoid inhalation of dust. Provide adequate ventilation Environmental precautions Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body Methods and material for containment and cleaning up Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. Collect spillage in containers, seal securely and deliver for disposal according to local regulations Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. SECTION : HANDLING AND STORAGE.1. Precautions for safe handling Avoid spilling, skin and eye contact. Avoid handling which leads to dust formation. Avoid inhalation of high concentrations of dust. Provide good ventilation..2. Conditions for safe storage, including any incompatibilities

4 4 / Store in tightly closed original container in a dry, cool and well-ventilated place. Keep in original container. Store in closed original container at temperatures between 5 C and 30 C..3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments No exposure limits noted for ingredient(s). PNEC Freshwater 0.44 mg/l Marinewater mg/l STP >1000 mg/l 8.2. Exposure controls Protective equipment Engineering measures Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust. Respiratory equipment No specific recommendation made, but protection against nuisance dust must be used when the general level exceeds 10 mg/m3. Hand protection Use suitable protective gloves if risk of skin contact. Eye protection Wear dust resistant safety goggles where there is danger of eye contact. Other Protection Wear rubber apron. Wear rubber footwear. Hygiene measures DO NOT SMOKE IN WORK AREA! Wash hands at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Use appropriate skin cream to prevent drying of skin. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Powder, dust Crystals or crystalline Colour Colourless. or White. Odour Odourless. Solubility Soluble in water. Soluble in: Alcohol Melting point ( C) Relative density 20C ph-value, Diluted Solution 5% Solubility Value (G/100G 6.6 H2O@20 C) Auto Ignition Temperature 345 C ( C)

5 5 / Partition Coefficient (N-Octanol/Water) 9.2. Other information Not determined. (-0.2 )- (-1.8) SECTION 10: STABILITY AND REACTIVITY Reactivity There are no known reactivity hazards associated with this product Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Not determined Conditions to avoid Avoid excessive heat for prolonged periods of time. Avoid dust formation Incompatible materials Materials To Avoid Strong oxidising substances. Strong alkalis Hazardous decomposition products Fire creates: Carbon dioxide (CO2). Carbon monoxide (CO). SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Toxic Dose 1 - LD mg/kg (oral rat) Acute toxicity: Acute Toxicity (Dermal LD50) > 2000 mg/kg Rat Inhalation Dust in high concentrations may irritate the respiratory system. Ingestion May cause discomfort if swallowed. Skin contact Powder may irritate skin. Eye contact Irritating to eyes. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment Toxicity

6 6 / Acute Fish Toxicity Not considered toxic to fish. LC 50, 96 Hrs, Fish mg/l Persistence and degradability Degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating. Partition coefficient (-0.2 )- (-1.8) Mobility in soil Mobility: The product is soluble in water Results of PBT and vpvb assessment This product does not contain any PBT or vpvb substances Other adverse effects Not determined. Cod 665 mgo2/g SECTION 13: DISPOSAL CONSIDERATIONS General information Waste to be treated as controlled waste. Disposal to licensed waste disposal site in accordance with local Waste Disposal Authority Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION General UN number The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Environmentally Hazardous Substance/Marine Pollutant No Special precautions for user

7 / 14.. Transport in bulk according to Annex II of MARPOL3/8 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 16). Approved Code Of Practice Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes CHIP for everyone HSG(108). EU Legislation Regulation (EC) No 190/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 93/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 6/69/EEC and Commission Directives 91/155/EEC, 93/6/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 122/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 6/548/EEC and 1999/45/EC, and amending Regulation (EC) No 190/2006 with amendments. According to Regulation (EU) No 453/ Chemical Safety Assessment A chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision Date Revision 03 SDS No Safety Data Sheet Status Approved. Date Signature Jitendra Panchal Risk Phrases In Full R36 Irritating to eyes. Hazard Statements In Full H319 Causes serious eye irritation.