1. PRODUCT IDENTIFICATION. Product Number: , , , U.N. Number: 1950

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1 DENTSPLY International Professional Safety Data Sheet Date Issued: September 2011 Document Number: Date Revised: 09/09/2011 Revision Number: 2.0 Trade Name: Chemical Name/Classification: 1. PRODUCT IDENTIFICATION NUPRO Aerosol Fluoride Foams N/A Product Number: , , , U.N. Number: 1950 U.N. Dangerous Goods Classification: Recommended Use: Restriction on Use: IATA: Shipping Name Consumer Commondity, Hazard Class 9, ID# 8000 Air Packing instruction: 910 IMDG: Qualifies for Limited Quantity Exception, Shipping Name: Aerosols, Hazard Class 2, ID# UN1950, EmS# F-D, S-U Topical fluoride treatment for teeth Do not use this product on patients with known allergies to any of the components. Manufacturer/Supplier Name: DENTSPLY Professional Manufacturer/Supplier Address: Smile Way York, PA Manufacturer/Supplier Telephone Number: or (Product Information) Emergency Contact Telephone Number: (CHEMTREC) for CHEMICAL EMERGENCY SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT (US and Canada only) Address: ProfessionalMSDS@dentsply.com 2. HAZARD(s) IDENTIFICATION Hazard/Danger Classification: Health Environmental Physical R25 N/A R36/38 Associated Hazards: Hazard Statements Signal Word: N/A Precautionary Statements Page 1 of 5

May cause salivation, nausea, or vomiting. Large quantities may cause abdominal pain, weakness, tremor, spasm or convulsions. Death can result from respiratory paralysis.

EU Classification: Xi, R25, R36/38 EU Risk (R) and Safety (S) Phrases: Irritant, toxic if swallowed, irritating to eyes and skin Refer to Section 16 for the full text of the EU Classifications and R

COMPOSITION AND INFORMATION ON INGREDIENTS Hazardous Ingredients CAS # EC# Ethyl Alcohol 64-17-5/ 200-578-6 Heptafluoropropane P-227 431-89-0/ 207-079-2 Sodium Fluoride 7681-49-4/ 231-667-8 IUPAC

phrases and EU Classifications and R Phrases. 4. FIRST AID MEASURES Eye Contact: Immediately flush with copious quantities of water for 15 minutes.

2 May cause salivation, nausea, or vomiting. Large quantities may cause abdominal pain, weakness, tremor, spasm or convulsions. Death can result from respiratory paralysis. Eye exposure may cause irritation. Skin exposure may cause dermatitis. EU Classification: Xi, R25, R36/38 EU Risk (R) and Safety (S) Phrases: Irritant, toxic if swallowed, irritating to eyes and skin Refer to Section 16 for the full text of the EU Classifications and R Phrases. 3. COMPOSITION AND INFORMATION ON INGREDIENTS Hazardous Ingredients CAS # EC# Ethyl Alcohol / Heptafluoropropane P / Sodium Fluoride / IUPAC Name Substance WT % Classification Ethanol R11, S7, S Heptafluoropropane P-227 Xi 20 Sodium Fluoride R25, R32, R36/38, S22, S36, S45 Refer to Section 16 for the full text of the GHS and H phrases and EU Classifications and R Phrases. 4. FIRST AID MEASURES Eye Contact: Immediately flush with copious quantities of water for 15 minutes. Seek medical attention if irritation or discomfort persists after flushing. Skin Contact: Wash skin with soap and water. Ingestion: Immediately give copious quantities of milk or water if milk is not available. Inhalation: N/A 5. FIRE FIGHTING MEASURES Extinguishing Media: Use water fog, carbon dioxide, foam or dry chemical. Water may be used to cool containers to prevent build-up if exposed to extreme temperatures. Firefighting Procedures: Firefighters should wear full emergency equipment and NIOSH approved positive pressure self-contained breathing apparatus. Unusual Fire/Explosion Hazards: Containers may explode if exposed to temperatures of 50 C (122 F) and above. Known or Anticipated Hazardous Products of Combustion: N/A Recommended Protective Equipment for Fire Fighters: EYES/FACE SKIN RESPRIATORY THERMAL 3 Page 2 of 5

6. ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Wash and wipe area with water. Personal Precautions: N/A Environmental Precautions: None known.

Do not puncture or incinerate containers even when empty. Storage: Store in a cool, well ventilated area not exceeding 50 C (122 F). Store away from food and beverages.

EXPOSURE CONTROLS/PERSONAL PROTECTION Non-hazardous polymers None Established Engineering Controls: Use with adequate general or local exhaust ventilation if dust or vapors are generated in use.

3 6. ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Wash and wipe area with water. Personal Precautions: N/A Environmental Precautions: None known. Recommended Personal Protective Equipment for Containment and Clean-up: EYES/FACE SKIN SKIN 7. HANDLING AND STORAGE Handling: For dental professional use only. Keep away from children. Do not puncture or incinerate containers even when empty. Storage: Store in a cool, well ventilated area not exceeding 50 C (122 F). Store away from food and beverages. Occupational Exposure Limits: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Non-hazardous polymers None Established Engineering Controls: Use with adequate general or local exhaust ventilation if dust or vapors are generated in use. Personal Protective Equipment: Eye Protection: Wear chemical splash goggles. Skin Protection: Impervious protective gloves Respiratory Protection: None should be needed for normal use. If the exposure levels are excessive, an approved dust/mist respirator appropriate for the form and concentration of the contaminants should be used. Selection and use of respiratory equipment must be in accordance with applicable regulations and good industrial hygiene practice. Other Protective Clothing or Equipment: Observe normal care when working with chemicals. Recommended Personal Protective Equipment EYES/FACE SKIN RESPRIATORY Page 3 of 5

4 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: Liquid under pressure and a white foam at normal pressure. Propellant and odor of flavoring. Boiling Point: Not determined Melting Point: Not applicable Freezing Point: Not determined Specific Gravity: 0.95 g/cm 3 Solubility in Water: 90% ph: for APF, for Neutral Vapor Pressure (mmhg): Vapor Density: Not applicable Evaporation Rate: Not applicable Viscosity: Not determined % Volatile by Volume: Not applicable Flashpoint: Not determined Flammable Limits in Air: Not applicable Autoignition Temperature: Not determined 10. STABILITY AND REACTIVITY Stability: Stable Conditions to Avoid: Extreme temperatures Incompatibility with Other Materials: Oxidizing agents and strong acids Hazardous Decomposition Products: Carbon monoxide, carbon dioxide and smoke. Acetic acid. Hazardous Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Non-hazardous polymers: No data available 12. ECOLOGICAL INFORMATION Non-hazardous polymers: No data available 13. DISPOSAL CONSIDERATIONS Dispose in accordance with federal, state, and local regulations. DOT Shipping Name: Consumer Commodity DOT Hazard Class: ORM-D UN Number: 1950 DOT Labels Required (49CFR ): ORM-D IATA Shipping Name: Consumer Commodity IATA Hazard Class: 9 ID Number: 8000 IATA Hazard Labels Required: 9 IMDG Shipping Name: Aerosols IMDG Class: 2 UN Number: 1950 IMDG Label: EmS# F-D, S-U 14. TRANSPORT INFORMATION Page 4 of 5

5 U.S. FEDERAL REGULATIONS: 15. REGULATORY INFORMATION Comprehensive Environmental Response and Liability Act of 1980 (CERCLA): This product is not subject to CERCLA reporting requirements. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the TSCA inventory. Superfund Amendments and Reauthorization Act (SARA) Title III Information: Hazard Category for Section 311/312: Not applicable Section 313 Toxic Chemicals: This product contains the following chemicals subject to Annual Release Reporting Requirements under SARA Title III, Section 313 (40 CFR 372): None Section 302 Extremely Hazardous Substances (TPQ): None SARA Section 311/312 (40 CFR 370) Hazard Categories: Immediate Hazard: None Pressure Hazard: None Delayed Hazard: None Reactivity Hazard: None Fire Hazard: None U.S. STATE REGULATIONS California Proposition 65: This product contains the following chemicals(s) known to the State of California to cause cancer, birth defects or reproductive harm (if blank, the product does not contain Proposition 65 regulated chemicals): Components C.A.S. # WT % None N/A N/A 16. OTHER INFORMATION Full text of Classification abbreviations used in Section 2 and 3: Xi Irritant R11 Highly Flammable R25 Toxic if swallowed R32 Contact with acids liberates very toxic gas R36/38 Irritating to eyes and skin S7 Keep container tightly closed S16 Keep away from source of ignition no smoking S22 Do not breathe dust S36 Wear suitable protective clothing S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) HMIS Hazard Rating: Health 1 Fire Hazard 0 Reactivity 0 Date of SDS Preparation/Revision: 09/09/2011 Page 5 of 5

DENTSPLY International Safety Data Sheet [SDS] Form 0280-FM Rev 6

DENTSPLY International Safety Data Sheet [SDS] Form 0280-FM-07-09 Rev 6 Document Number: 0280-MSDS-0035 Date Issued: 9/15/14 Date Revised: 9/15/14 Revision Number: 1 Product Identifier [Part/Item Number(s)]: