SAFETY DATA SHEET KEYSTONE REAL A-PEEL CLEANER DEGREASER AEROSOL

Transcription

1 KEYSTONE REAL A-PEEL CLEANER DEGREASER AEROSOL SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : Not applicable Recommended use : Degreaser Restrictions on use : Reserved for industrial and professional use. Product dilution information : Product is sold ready to use. Company : Ecolab Inc. 370 N. Wabasha Street St. Paul, Minnesota USA Emergency health information : (US/Canada), (outside US) Issuing date : 05/19/2016 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable aerosols : Category 2 Eye irritation : Category 2B Skin sensitization : Category 1 GHS label elements Hazard pictograms : Signal Word Hazard Statements Precautionary Statements : Warning : Flammable aerosol. May cause an allergic skin reaction. Causes eye irritation. : Prevention: Keep away from heat/sparks/open flames/hot surfaces. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wash skin thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Intentional misuse by deliberate inhalation may be harmful or fatal. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Wash contaminated clothing before reuse. Storage: / 9

2 Protect from sunlight. Do not expose to temperatures exceeding 50 C/ 122 F. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical name CAS-No. Concentration (%) distillates (petroleum), hydrotreated light Aliphatic hydrocarbons propane d-limonene Alcohols, C9-11, ethoxylated SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician Most important symptoms and effects, both acute and delayed : Rinse with plenty of water. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : See Section 11 for more detailed information on health effects and symptoms. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire fighting Hazardous combustion products : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : High volume water jet : Fire Hazard Keep away from heat and sources of ignition. Flash back possible over considerable distance. Pressurised container: May burst if heated. Flammable aerosols : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus / 9

3 Special protective equipment for fire-fighters Specific extinguishing methods : Use personal protective equipment. : Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Remove all sources of ignition. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Eliminate all ignition sources if safe to do so. Stop leak if safe to do so. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Do not get in eyes, on skin, or on clothing. Keep away from fire, sparks and heated surfaces. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors). Contents under pressure. Do not puncture. Wash hands thoroughly after handling. : Keep away from heat and sources of ignition. Keep in a cool, wellventilated place. Keep away from oxidizing agents. Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : 5 C to 45 C SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION with workplace control parameters CAS-No. Form of exposure Permissible concentration Basis distillates (petroleum), hydrotreated light TWA 500 ppm 2,000 mg/m3 OSHA Z1 TWA 200 mg/m3 (as total ACGIH hydrocarbon vapor) TWA (Mist) 5 mg/m3 OSHA Z1 TWA (Mist) 5 mg/m3 NIOSH REL STEL (Mist) 10 mg/m3 NIOSH REL Aliphatic hydrocarbons TWA 800 ppm NIOSH REL 1,900 mg/m3 STEL 1,000 ppm ACGIH propane TWA 1,000 ppm NIOSH REL 1,800 mg/m3 TWA 1,000 ppm 1,800 mg/m3 OSHA Z / 9

4 Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures : No special protective equipment required. : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Handle in accordance with good industrial hygiene and safety practice. Wash face, hands and any exposed skin thoroughly after handling. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Color Odor : aerosol : clear, light yellow : citrus ph : 10.3, 100 % Flash point Odor Threshold Melting point/freezing point Initial boiling point and boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density Relative density Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic : Not applicable, Sustains combustion : > 35 C : soluble : mm2/s (40 C) Explosive properties Oxidizing properties : The substance or mixture is not classified as oxidizing / 9

5 Molecular weight VOC Heat of combustion : 5.69 kj/g SECTION 10. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : Heat, flames and sparks. : None known. : Decomposition products may include the following materials: Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Oxides of phosphorus SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure : Causes eye irritation. : May cause allergic skin reaction. : Health injuries are not known or expected under normal use. : Health injuries are not known or expected under normal use. Intentional misuse by deliberate inhalation may be harmful or fatal. : Health injuries are not known or expected under normal use. Experience with human exposure Eye contact Skin contact Ingestion Inhalation : Redness, Irritation : Redness, Irritation, Allergic reactions : No symptoms known or expected. : No symptoms known or expected. Toxicity Product Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity : Acute toxicity estimate : > 5,000 mg/kg / 9

6 Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Acute inhalation toxicity Acute dermal toxicity : Mild eye irritation : Aliphatic hydrocarbons 4 h LC50 Rat: ppm : d-limonene LD50 Rabbit: > 5,000 mg/kg Alcohols, C9-11, ethoxylated LD50 Rat: > 5,000 mg/kg SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Toxicity to fish : Harmful to aquatic life with long lasting effects. : distillates (petroleum), hydrotreated light 96 h LC50: > 1,000 mg/l Aliphatic hydrocarbons 96 h LC50 Fish: mg/l Alcohols, C9-11, ethoxylated 96 h LC50 Fish: 8.5 mg/l Toxicity to daphnia and other aquatic invertebrates : distillates (petroleum), hydrotreated light 48 h EC50: > 1,000 mg/l / 9 Alcohols, C9-11, ethoxylated 48 h EC50 Daphnia magna (Water flea): 5.3 mg/l

7 Toxicity to algae : distillates (petroleum), hydrotreated light 72 h EC50: > 1,000 mg/l Persistence and degradability No data available Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations : The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. Dispose of in accordance with local, state, and federal regulations. SECTION 14. TRANSPORT INFORMATION The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) UN number : 1950 Description of the goods : Aerosols Class : 2.1 Environmentally hazardous : no Sea transport (IMDG/IMO) UN number : 1950 Description of the goods : AEROSOLS Class : 2.1 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity / 9

8 This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards SARA 302 SARA 313 : Fire Hazard Acute Health Hazard : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL Australia Inventory of Chemical Substances (AICS) : New Zealand. Inventory of Chemical Substances : Japan. ENCS - Existing and New Chemical Substances Inventory : not determined Japan. ISHL - Inventory of Chemical Substances (METI) : not determined Korea. Korean Existing Chemicals Inventory (KECI) : Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China. Inventory of Existing Chemical Substances in China (IECSC) : SECTION 16. OTHER INFORMATION / 9

9 Health Instability SAFETY DATA SHEET NFPA: Flammability HMIS III: 3 HEALTH 2* 2 0 FLAMMABILITY 3 PHYSICAL HAZARD 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 05/19/2016 Version : 1.1 Prepared by : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 9