DEVRINOL 45 SC. 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Identification of the product

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1 SAFETY DATA SHEET Preparation Date 03-Feb-2012 Revision Number: 1 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Identification of the product Product Code Product Description: Pure substance/preparation HAR01 DEVRINOL 45 SC Preparation 1.2 Relevant identified uses of the substance or mixture and uses advised against Recommended Use herbicide. 1.3 Details of the supplier of the safety data sheet Supplier Address United Phosphorus Ltd The Centre Birchwood Park Warrington WA3 6YN Cheshire, UK info.uk@uniphos.com 1.4 Emergency telephone number Emergency Telephone Number (CARECHEM 24): Page 1 / 12

2 2. HAZARDS IDENTIFICATION 2.1 Classification of the mixture Symbol(s) R-code(s) Xi - Irritant N - Dangerous for the environment Xi;R36 - N;R51-53 For the full text of the R phrases mentioned in this Section, see Section Label Elements Symbol(s) Xi - Irritant N - Dangerous for the environment R -phrase(s) R36 - Irritating to eyes R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment S -phrase(s) S 2 - Keep out of the reach of children S13 - Keep away from food, drink and animal feedingstuffs S20/21 - When using, do not eat, drink or smoke S49 - Keep only in the original container S60 - This material and its container must be disposed of as hazardous waste S61 - Avoid release to the environment. Refer to special instructions/safety data sheets 2.3 Other hazards Page 2 / 12

3 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures Chemical Name EC No. Napropamide CAS-No Weight % Classification (Dir.67/548) Xi;R36 N;R51/53 EU - GHS Substance Classification Eye Irrit. 2 (H319) Aquatic Chronic 2 (H411) REACH No. No data available Ethoxylated fatty alcohol - - (ND) < 1 Xn; R22 Xi; R41 N;R50 Eye Dam. 1 (H318) Acute Tox. 4 (H302) Aquatic Acute 1 (H400) No data available Aqueous dipropylene glycol solution of approx. 20% 1,2-benzisothiazolin-3-o ne ( (17-23% (5-15%)) Ethylene glycol For the full text of the R phrases mentioned in this Section, see Section 16 For the full text of the H-Statements mentioned in this Section, see Section 16 < 1 C; R34 Xn; R22 Xi; R43 N; R Xn;R22 Acute Tox. 4 (H302) - - No data available 4.1 Description of first-aid measures 4. FIRST AID MEASURES Eye Contact Contact Ingestion Inhalation Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes If eye irritation persists, consult a specialist Wash skin with soap and water Remove and wash contaminated clothing before re-use Call a POISON CENTER or doctor/physician if exposed or you feel unwell Move to fresh air If symptoms persist, obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of immediate medical attention and special treatment needed Treat symptomatically. Page 3 / 12

4 5. FIRE-FIGHTING MEASURES 5.1 Extinguishing media Suitable Extinguishing Media Unsuitable Extinguishing Media As a water suspension, the fire is highly improbable Use extinguishing measures that are appropriate to local circumstances and the surrounding environment 5.2 Special hazards arising from the substance or mixture Special hazard 5.3 Advice for firefighters Wear self-contained breathing apparatus and protective suit. Prevent further leakage or spillage if safe to do so Do not allow material to contaminate ground water system Do not flush into surface water or sanitary sewer system 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Evacuate personnel to safe areas Avoid contact with eyes Wear protective gloves/clothing and eye/face protection. 6.2 Environmental precautions 6.3 Methods and materials for containment and cleaning up Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container Page 4 / 12

5 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Handling Ensure adequate ventilation Wear personal protective equipment Do not cut grind or weld on or near containers - explosion hazard Ensure that eyewash stations and safety showers are close to the workstation location Hygiene Measures Do not eat, drink or smoke when using this product Wash hands after handling 7.2 Conditions for safe storage, including any incompatibilities Keep only in the original container/package in a cool well-ventilated place 7.3 Specific end uses Page 5 / 12

6 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters Exposure limits Apply technical measures to comply with the occupational exposure limits Chemical Name Ethylene glycol S* TWA 20 ppm TWA 52 mg/m 3 STEL 40 ppm STEL 104 mg/m 3 EU United Kingdom France STEL: 40 ppm STEL: 104 mg/m 3 STEL: 30 mg/m 3 TWA: 20 ppm TWA: 52 mg/m 3 TWA: 10 mg/m 3 TWA: 20 ppm TWA: 52 mg/m 3 STEL: 40 ppm STEL: 104 mg/m 3 Spain S* STEL: 40 ppm STEL: 104 mg/m 3 TWA: 20 ppm TWA: 52 mg/m 3 Germany MAK: 10 ppm MAK: 26 mg/m 3 Ceiling / Peak: 20 ppm Ceiling / Peak: 52 mg/m 3 TWA: 10 ppm TWA: 26 mg/m 3 Chemical Name Ethylene glycol Italy TWA: 20 ppm TWA: 52 mg/m 3 STEL: 40 ppm STEL: 104 mg/m 3 Portugal Netherlands Finland Denmark Ceiling: 100 mg/m 3 STEL: 104 mg/m 3 TWA: 52 mg/m 3 TWA: 10 mg/m 3 TWA: 20 ppm TWA: 50 mg/m 3 STEL: 40 ppm STEL: 100 mg/m 3 TWA: 10 ppm TWA: 26 mg/m 3 TWA: 10 mg/m 3 Chemical Name Ethylene glycol Austria Switzerland STEL 20 ppm STEL STEL: 20 ppm 52 mg/m 3 STEL: 52 mg/m 3 TWA: 10 ppm TWA: TWA: 10 ppm TWA: 26 mg/m 3 26 mg/m 3 Poland Norway NDSCh: 50 mg/m 3 TWA: 10 mg/m 3 TWA: 15 mg/m 3 Ceiling: 25 ppm STEL: 20 ppm Ireland TWA: 10 mg/m 3 TWA: 20 ppm TWA: 52 mg/m 3 STEL: 40 ppm STEL: 104 mg/m 3 Derived No Effect Level (DNEL) Predicted No Effect Concentration (PNEC) 8.2 Exposure controls Engineering Controls Personal protective equipment Eye Protection Protection Hand Protection Respiratory Protection Environmental exposure controls Ensure adequate ventilation, especially in confined areas. Safety glasses with side-shields. Long sleeved clothing. Protective gloves. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Page 6 / 12

7 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance Physical State Odor Cream. Liquid Capsule suspension Characteristic. Property Values ph 8-9 Melting point/freezing point Boiling Point/Range > 100 C Flash Point > 100 C Evaporation rate Flammability (solid, gas) Water Solubility Miscible with water Solubility in other solvents Partition coefficient: n-octanol/water Autoignition Temperature Decomposition temperature Viscosity 50 Oxidizing Properties Explosive Properties Remarks/ Method ISO mm 9.2 Other information VOC Content 10. STABILITY AND REACTIVITY 10.1 Reactivity 10.2 Chemical Stability Stable under normal conditions Possibility of Hazardous Reactions 10.4 Conditions to Avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products 11. TOXICOLOGICAL INFORMATION Page 7 / 12

8 11.1 Information on toxicological effects Acute Toxicity Local effects Inhalation Eye Contact Contact Ingestion LD50 Oral LD50 Dermal LC50 Inhalation: There is no data available for this product. There is no data available for this product. There is no data available for this product. There is no data available for this product. > 5000 mg/kg (rat) > 2000 mg/kg (rat) 2 mg/l (rat) Corrosivity Sensitization Repeated Dose Toxicity Carcinogenic effects Mutagenic Effects Reproductive Effects STOT - single exposure STOT - repeated exposure Page 8 / 12

9 12. ECOLOGICAL INFORMATION 12.1 Toxicity EC50/72h/algae = 11 mg/l LC50/48h/daphnia = 14 mg/l LC50/fish/96 h = 13 mg/l 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil Chemical Name log Pow Ethylene glycol Results of PBT and vpvb assessment This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). This mixture contains no substance considered to be very persistent nor very bioaccumulating (vpvb) Other adverse effects 13.1 Waste treatment methods 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated Packaging EWC waste disposal No Other Information Dispose of in accordance with local regulations. Empty containers should be taken for local recycling, recovery or waste disposal agrochemical waste containing dangerous substances. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Page 9 / 12

10 14. TRANSPORT INFORMATION ADR/RID UN-No Proper Shipping Name 14.3 Hazard Class 14.4 Packing Group 14.5 Environmental hazard 14.6 Special Provisions Tunnel restriction code UN3082 Environmentally hazardous substance, liquid, n.o.s. ( Napropamide ) 9 III Dangerous for the environment 274, 335, 601 (E) IMDG/IMO UN-No UN Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. ( Napropamide ) 14.3 Hazard Class Packing Group III 14.5 Environmental hazard Marine pollutant 14.6 Special Provisions 274, 335 IATA/ICAO UN-No UN Proper Shipping Name Environmentally hazardous substance, liquid, n.o.s. ( Napropamide ) 14.3 Hazard Class Packing Group III 14.5 Environmental hazard Dangerous for the environment 14.6 Special Provisions A97, A158 Page 10 / 12

11 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture - To avoid risks to man and the environment, comply with the instructions for use International Inventories TSCA EINECS/ ELINCS DSL/NDSL PICCS ENCS CHINA - AICS KECL Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances AICS - Australian Inventory of Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances 15.2 Chemical Safety Assessment A chemical safety assessment has not been carried out. Page 11 / 12

12 16. OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 R22 - Harmful if swallowed R34 - Causes burns R36 - Irritating to eyes R41 - Risk of serious damage to eyes R43 - May cause sensitization by skin contact R50 - Very toxic to aquatic organisms R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Full text of H-Statements referred to under sections 2 and 3 H302 - Harmful if swallowed H319 - Causes serious eye irritation H411 - Toxic to aquatic life with long lasting effects Revision Date Revision Note 03-Feb-2012 not applicable This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information contained is based on our knowledge of the product at the date of publishing. It applies to the PRODUCT AS SUCH. In case of formulation or mixture, make sure that a new danger will not appear. Users are advised of possible additional hazards when the product is used in applications for which it was not intended. This sheet shall only be used and duplicated for prevention and Safety purposes. For rates and use recommendations, refer to the information displayed on the packaging. It is the responsability of the handlers of the product to pass on this safety data sheet to any subsequent persons who will come into contact with the product. End of Safety Data Sheet Page 12 / 12