SAFETY DATA SHEET. 1. Product and Company Identification

Transcription

1 SAFETY DATA SHEET 1. Product and Company Identification Product identifier Other means of identification Recommended use Recommended restrictions Manufacturer Rid O' Rust Rust Stain Remover Not available Rust Stain Remover None known. Pro Products LLC 721 Engle Road Fort Wayne, IN US Phone Emergency Phone: (CHEMTREC) Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements 2. Hazards Identification Corrosive to metals Skin corrosion/irritation Serious eye damage/eye irritation Category 1 Category 1 Category 1 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Danger May be corrosive to metals. Causes severe skin burns and eye damage. Keep only in original container. Do not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Absorb spillage to prevent material damage. If swallowed: Rinse mouth. Do NOT induce vomiting. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Specific treatment (see this label). Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Store locked up. Store in corrosive resistant container with a resistant inner liner. Dispose of contents/container in accordance with local/regional/national/international regulations. None known. 99% of the mixture consists of component(s) of unknown acute inhalation toxicity. Mixture Chemical name 3. Composition/Information on Ingredients Common name and synonyms CAS number % Ethanedioic acid, dihydrate Composition comments US GHS: The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of Inhalation Skin contact 4. First Aid Measures If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Specific treatment (see product label). Immediately call a poison center/doctor/. #195 Page: 1 of 7

2 Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center/doctor/. Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Provide general supportive measures and treat symptomatically. Symptoms may be delayed. Treat patient symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. If you feel unwell, seek medical advice (show the label where possible). Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Wear rubber gloves and chemical splash goggles. Keep out of reach of children. 5. Fire Fighting Measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. Firefighters should wear a self-contained breathing apparatus. Firefighters should wear full protective clothing including self contained breathing apparatus. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. May include and are not limited to: Oxides of carbon. Formic acid 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep out of low areas. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Stop the flow of material, if this is without risk. Should not be released into the environment. Large Spills: Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb spillage to prevent material damage. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Do not discharge into lakes, streams, ponds or public waters. 7. Handling and Storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Avoid prolonged exposure. Observe good industrial hygiene practices. Wash thoroughly after handling. Avoid breathing vapors or mists of this product. Store locked up. Protect from sunlight. Store in corrosive resistant container with a resistant inner liner. Keep only in the original container. Store away from incompatible materials (see Section 1 of the SDS). Keep out of the reach of children. Store in a cool, dry, well-ventilated place away from incompatible materials. #195 Page: 2 of 7

3 8. Exposure Controls/Personal Protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 191.1) Type Ethanedioic acid, dihydrate (CAS ) US. ACGIH Threshold Limit Values Ethanedioic acid, dihydrate (CAS ) PEL Type STEL TWA Value 1 mg/m3 Value 2 mg/m3 1 mg/m3 US. NIOSH: Pocket Guide to Chemical Hazards Type Ethanedioic acid, dihydrate (CAS ) Biological limit values Exposure guidelines Appropriate engineering controls STEL TWA Value No biological exposure limits noted for the ingredient(s). 2 mg/m3 1 mg/m3 There are no established ACGIH or OSHA PEL exposure limits for the hazardous chemicals listed in section 3 of the SDS. Good general ventilation (typically 1 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Appearance Physical state Form Color Odor Odor threshold Wear chemical goggles. Impervious gloves. Confirm with reputable supplier first. As required by employer code. Use of an impervious apron is recommended. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Not applicable. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Clear Liquid. Liquid ph < 1 Melting point/freezing point Initial boiling point and boiling range Pour point Specific gravity 1.2 Partition coefficient (n-octanol/water) Flash point Evaporation rate Flammability (solid, gas) Colorless Odorless 9. Physical and Chemical Properties Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) #195 Page: 3 of 7

4 Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Auto-ignition temperature Decomposition temperature Viscosity 1. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Oxalic acid is a mild reducing agent and is easily oxidized. Reacts vigorously with alkaline material. This product may react with reducing agents. Hazardous polymerization does not occur. Stable under recommended storage conditions. High temperatures. Reacts violently with strong alkaline substances. This product may react with reducing agents. Do not mix with other chemicals. Strong oxidizing agents. Acids. This product may react with reducing agents. Incompatible with bases. Alkaline materials. Oxidizers. Chlorites Combustible materials. Reducing agents. May include and are not limited to: Oxides of carbon. Formic acid 11. Toxicological Information Routes of exposure Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Eye, Skin contact, Skin absorption, Inhalation, Ingestion. Causes digestive tract burns. Prolonged inhalation may be harmful. Causes severe skin burns. Causes serious eye damage. Burning pain and severe corrosive skin damage. Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. Species Acute Dermal LD5 Oral LD5 Skin corrosion/irritation Exposure minutes Erythema value Oedema value Serious eye damage/eye irritation Corneal opacity value Iris lesion value Conjunctival reddening value Rabbit Rat Causes severe skin burns and eye damage. Causes serious eye damage. Conjunctival oedema value Test Results 2 mg/kg 18 mg/kg 375 mg/kg #195 Page: 4 of 7

5 Recover days Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Mutagenicity Carcinogenicity Reproductive toxicity Teratogenicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information Name of Toxicologically Synergistic Products This product is not expected to cause skin sensitization. Not classified or listed by IARC, NTP, OSHA and ACGIH. Prolonged inhalation may be harmful. 12. Ecological Information Ecotoxicity Crustacea Aquatic Crustacea Persistence and degradability Bioaccumulative potential Mobility in soil Mobility in general Other adverse effects Because of the low ph of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. EC5 EC5 Species Daphnia Water flea (Daphnia magna) No data is available on the degradability of this product. No data available. No data available. Test Results mg/l, 48 Hours mg/l, 48 hours No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal Considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport Information General Canada: TDG Proof of Classification: In accordance with Part (SOR/ ) of the Transportation of Dangerous Goods Regulations, we certify that the classification of this product is correct as of the SDS date of issue. If applicable, the technical name and the classification of the product will appear below. U.S. Department of Transportation (DOT) Basic shipping requirements: UN number UN176 Proper shipping name Corrosive liquids, n.o.s. (Ethanedioic acid, dihydrate) Hazard class 8 #195 Page: 5 of 7

6 Packing group III Special provisions IB3, T7, TP1, TP28 Packaging exceptions 154 Transportation of Dangerous Goods (TDG - Canada) Basic shipping requirements: UN number UN176 Proper shipping name CORROSIVE LIQUID, N.O.S. (Ethanedioic acid, dihydrate) Hazard class 8 Packing group III Special provisions 16 DOT TDG 15. Regulatory Information Canadian federal regulations WHMIS status WHMIS classification WHMIS labeling This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. Controlled Class E - Corrosive Material US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export Notification (4 CFR 77, Subpt. D) CERCLA Hazardous Substance List (4 CFR 32.4) 1. % One-Time Export Notification only. Not listed. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 32 Extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No #195 Page: 6 of 7

7 SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) No Other federal regulations Safe Drinking Water Act (SDWA) Food and Drug Administration (FDA) US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Hazardous Substances (Director's): Listed substance Listed. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US - Minnesota Haz Subs: Listed substance Listed. US - New Jersey RTK - Substances: Listed substance Listed. US - Texas Effects Screening Levels: Listed substance US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Inventory status Listed. Listed. Listed. Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada Non-Domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information No Yes Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 3 X 3 Disclaimer Issue date Effective date Expiry date Further information The data contained in this material safety data sheet was obtained from sources that were technically accurate, reliable, and state of the art when this document was prepared. If data was unavailable to complete certain sections, the absence of that data is identified in this document. Because the supplier cannot know the exact circumstances during actual use of this product, other hazards, exposure scenarios, disposal considerations, and regulations may apply and it is the responsibility of the user to read and understand the product label and this document before use. Do not use the product for purposes other than those stated in Section May May May-218 For an updated SDS, please contact the supplier/manufacturer listed on the first page of the document. Prepared by Dell Tech Laboratories, Ltd. Phone: (519) Other information This Safety Data Sheet was prepared to comply with the current OSHA Hazard Communication Standard (HCS) adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). This SDS conforms to the ANSI Z4.1/Z Standard. Redbook revision # 6, 8/13/14 #195 Page: 7 of 7