Issuing Date 07-Feb-2011 Revision Date 04-Apr-2016 Revision Number 2 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Transcription

1 SAFETY DATA SHEET Issuing Date 07-Feb-2011 Revision Number 2 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING GHS product identifier Product Name AquaMate Carpet Cleaner Other means of identification Synonyms ne Recommended use of the chemical and restrictions on use Recommended Use Uses advised against Carpet cleaner information available Supplier's details Manufacturer Address Rexair LLC 230 Seventh Street Cadillac, MI USA TEL: Distributor Rexair LLC 50 W. Big Beaver Suite 350 Troy, MI USA TEL: Emergency telephone number Emergency Telephone Number Classification HAZARDS IDENTIFICATION This product is considered hazardous by the OSHA Hazard Communication Standard 2012 (29 CFR ). Serious Eye Damage/Eye Irritation Category 2 GHS Label elements, including precautionary statements Emergency Overview Signal Word Hazard Statements Causesseriouseyeiritation Warning Appearance Clear. Physical State Liquid. Odor Precautionary Statements Page 1 / 7

2 Prevention Washface,handsandanyexposedskinthoroughlyafterhandling. Weareye/faceprotection. General Advice ne Eyes IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continue rinsing. Ifeyeiritationpersists:Getmedicaladvice/atention. Storage ne Disposal ne Hazard t Otherwise Classified (HNOC) t applicable. Other information Harmful to aquatic life. Harmful to aquatic life with long lasting effects % of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS- Weight % Trade secret Sodium 1-octanesulfonate * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of necessary first-aid measures Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. Skin Contact Inhalation Ingestion Wash skin with soap and water. Get medical attention if irritation develops and persists. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Most important symptoms/effects, acute and delayed Most Important Symptoms/Effects Red eyes, Irritation. Indication of immediate medical attention and special treatment needed, if necessary tes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media ne Page 2 / 7

3 Specific Hazards Arising from the Chemical n-combustible Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge ne. ne. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Wear protective gloves/clothing and eye/face protection. Environmental Precautions Environmental Precautions Avoid release to the environment. Dispose of contents/container to an approved waste disposal plant. Collect spillage. See Section 12 for additional Ecological Information. Methods and materials for containment and cleaning up Methods for Containment Methods for Cleaning Up Dike far ahead of liquid spill for later disposal. Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Use personal protective equipment. Sweep up and shovel into suitable containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Handling Avoid contact with eyes. Wear protective gloves/ eye protection/ face protection Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Incompatible Products Keep container tightly closed. Alkalis. Alkaline earth metals. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH STEL: 150 ppm TWA: 100 ppm S* Dipropylene glycol monomethyl ether TWA: 100 ppm TWA: 600 mg/m 3 (vacated) TWA: 100 ppm (vacated) TWA: 600 mg/m 3 (vacated) STEL: 150 ppm (vacated) STEL: 900 mg/m 3 (vacated) S* IDLH: 600 ppm TWA: 100 ppm TWA: 600 mg/m 3 STEL: 150 ppm STEL: 900 mg/m 3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures ne under normal use conditions. Page 3 / 7

4 Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures ne required for consumer use. ne required for consumer use. ne required under normal usage. Provide regular cleaning of equipment, work area and clothing. Information on basic physical and chemical properties 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid. Appearance Clear. Odor Odor Threshold Property Values Remarks/ - Method ph data available ne known Melting Point/Range data available ne known Boiling Point/Boiling Range 100 C / 212 F ne known Flash Point data available ne known Evaporation rate data available ne known Flammability (solid, gas) data available ne known Flammability Limits in Air upper flammability limit data available lower flammability limit data available Vapor Pressure data available ne known Vapor Density data available ne known Specific Gravity data available ne known Water Solubility data available ne known Solubility in other solvents data available ne known Partition coefficient: n-octanol/water data available ne known Autoignition Temperature data available ne known Decomposition Temperature data available ne known Viscosity data available ne known Flammable Properties Explosive Properties Oxidizing Properties t flammable data available data available Other information VOC Content (%) data available 10. STABILITY AND REACTIVITY Reactivity data available. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions ne under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Page 4 / 7

5 ne known based on information supplied. Incompatible materials Alkalis. Alkaline earth metals. Hazardous decomposition products ne known based on information supplied. Information on likely routes of exposure 11. TOXICOLOGICAL INFORMATION Product Information Inhalation Eye Contact Skin Contact Ingestion Product does not present an acute toxicity hazard based on known or supplied information. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Dipropylene glycol monomethyl = 5230 mg/kg ( Rat ) = 9500 mg/kg ( Rabbit ) - ether Symptoms related to the physical, chemical and toxicological characteristics Symptoms Irritation Delayed and immediate effects and also chronic effects from short and long term exposure Sensitization Mutagenic Effects Carcinogenicity Contains no ingredients above reportable quantities listed as a carcinogen. Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration Hazard Numerical measures of toxicity - Product Acute Toxicity % of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document: LD50 Oral mg/kg; Acute toxicity estimate LD50 Dermal mg/kg; Acute toxicity estimate 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Dipropylene glycol LC50 96 h: > mg/l monomethyl ether static (Pimephales promelas) Daphnia Magna (Water Flea) LC50 48 h: = 1919 mg/l (Daphnia magna) Persistence and Degradability Bioaccumulation Page 5 / 7

6 Other Adverse Effects 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods Contaminated Packaging Dispose of in accordance with federal, state, and local regulations Do not re-use empty containers. 14. TRANSPORT INFORMATION DOT TDG MEX ICAO IATA IMDG/IMO RID ADR ADN International Inventories TSCA DSL 15. REGULATORY INFORMATION Complies Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/n-Domestic Substances List U.S. Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS- Weight % SARA Threshold Values % Dipropylene glycol monomethyl ether SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. Page 6 / 7

7 U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Illinois Rhode Island Dipropylene glycol X X X X X monomethyl ether U.S. EPA Label Information EPA Pesticide Registration Number t applicable 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection X Prepared By Product Stewardship 23 British American Blvd. Latham, NY Issuing Date 07-Feb-2011 Revision Date 04-Apr-2016 Revision te (M)SDS sections updated. 14. General Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 7 / 7