MATERIAL SAFETY DATA SHEET

Transcription

1 SECTION 1 : IDENTIFICATION Product name: Chemical name : Product Use: Chemical family : Supplier s name: Address : Mixture Hertel Pro Cleaner Degreaser LAVO Inc Boul. Saint-Jean Baptiste Montréal, Québec Canada H1C 2J3 Telephone : or Emergency phone : CANUTEC (transport) SECTION 2 : HAZARD IDENTIFICATION Emergency Overview DANGER. CORROSIVE. POTENTIAL HEALTH EFFECTS short-term (acute) exposure: Eyes : Skin : Inhalation : Target organs: Signs and symptoms: Signs and symptoms : May cause chemical burns. May cause blindness. May cause chemical burns. Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Harmful if inhaled. May cause respiratory tract irritation. Eyes. Respiratory system. Skin. Prolonged or repeated exposure can cause drying, de fatting and dermatitis The product may cause burns to eyes, skin and mucous membranes. SECTION 3 : COMPOSITION/INFORMATION ON INGREDIENTS Ingredients CAS Percentage Sodium Xylene sulfonate % Dipropylene glycol Methyl Ether % Ethoxylated Alcohols C7-C % Sodium metasilicate % Sodium Hydoxide % Tetrasodium Ethylene Diamine Acetate % Alkyl ethoxylated Alcohol C9-C < 1.5 % SECTION 4 : FIRST AID MEASURES Eye contact : Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention. Skin contact: Inhalation : Notes for physician : General advice : Flush with cool water. Obtain medical. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Symptoms may be delay. Treat symptomatically. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children Page 1 / 5

2 SECTION 5 : FIRE FIGHTING MEASURES Fire hazards/conditions of flammability: Extinguishing media: Protection of firefighters Specific hazards arising from the chemical: Protective equipment for firefighters: Hazardous combustion products : Not flammable by WHMIS criteria. Dry chemical. Alcohol foam. Carbon dioxide. Fog. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. SECTION 6 : ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Methods for containment: Methods for cleaning up : Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak.. Do not discharge into lakes, streams, ponds or public waters. Stop leak if you can do so without risk. Prevent entry into waterways, Sewers, basements or confined areas. Before attempting clean up, refer to hazard data given above. Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Never return spills in original containers for re-use. SECTION 7 : HANDLING AND STORAGE Safe Handling procedures: Storage requirements : Storage temperature: Use good industrial hygiene practices in handling this material. Avoid contact with eyes and skin. Keep out of reach of children C. Do not freeze. Avoid high temperature. SECTION 8 : EXPOSITION CONTROL/PERSONAL PROTECTION Exposition limit values ACGIH TLV OSHA PEL Ingredients CAS TWA PEL STEL Sodium Xylene sulfonate Not available N/D Dipropylene glycol Methyl Ether ppm dermal Ethoxylated Alcohols C7-C Not available Sodium metasilicate Not available Sodium Hydoxide mg/m 3 ceiling Tetrasodium Ethylene Diamine Acetate Not available Alkyl ethoxylated Alcohol C9-C Not available Engineering controls: Eye/Face protection: Skin and body protection: Respiratory protection: General hygiene considerations: General ventilation normally adequate. Safety glasses or a facial screen if eye contact is possible. Rubber gloves. Confirm with a reputable supplier first. Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Wash hands before breaks and immediately after handling the product Page 2 / 5

3 SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES MATERIAL SAFETY DATA SHEET Physical state Liquid Appearance Uncolored liquid Odor Characteristic Odor threshold Not available ph Water Solubility Miscible Boiling point Not available Evaporation Rate Not available Freezing point Not available Viscosity (@20 C) Not available Vapor Pressure 20 C/68 F) Not available Auto-ignition temperature Not available Flash point / Poor point Not available Flammability limits in air, lower %vol Not available Density Flammability limits in air, upper %vol Not available Repartition Coefficient water/oil Not available Vapor density Not available SECTION 10 : STABILITY AND REACTIVITY Reactivity: Possibility of hazardous reactions: Chemical stability: Conditions to avoid: Incompatible materials: Hazardous decomposition products: This product may react with strong acids. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Acids. Oxidizing agents. May include and are not limited to: Oxides of carbon. SECTION 11 : TOXICOLOGICAL INFORMATION Ingredients CAS LC50(4hr)inh, rat LD50 (Oral, rat) LD50 (Rabbit, dermal) Sodium Xylene sulfonate Not available 7200mg/kg >2000mg/kg Dipropylene glycol Methyl Ether > 661 ppm mg/kg 9500 mg/kg Ethoxylated Alcohols C7-C Not available Not available Not available Sodium metasilicate Not available 1153 mg/kg ; 770 mg/kg mice >4640mg/kg Sodium Hydoxide Not available Not available Not available Tetrasodium Ethylene Diamine Acetate Not available > 2000 mg/kg Not available Alkyl Ethoxylated Alcohol C9-C Not available Not available Not available Effects of acute exposure: eyes : Skin : Inhalation: Sensitization to material : Chronic effects: Carcinogenicity : Reproductive effects: Teratogenicity : Mutagenicity: Synergistic Products : May cause chemical burns. May cause blindness. May cause chemical burns. Harmful if inhaled. May cause respiratory tract irritation. Harmful if swallowed. May cause chemical burns to mouth, throat and stomach Page 3 / 5

4 SECTION 12 : ECOLOGICAL INFORMATION Eco toxicity: Because of the high ph of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. Persistence and degradability: Bioaccumulation Potential: Mobility in environmental media : Environmental effects: Aquatic toxicity: Partition coefficient Chemical fate information : Other adverse effects ; SECTION 13 : DISPOSAL CONSIDERATIONS Disposal instructions: Waste from residues / Unused products: Contaminated packaging Dispose in accordance with all applicable federal, state, provincial and local regulations. SECTION 14 : TRANSPORT INFORMATION Transportation of Dangerous Goods (TDG - Canada) : Proper chipping name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (sodium metasilicate) Hazard class: 8 Packing group II UN number: UN3266 Special provisions: 16 Packaging exceptions: Limited Quantity <1L SECTION 15 : REGULATORY INFORMATION Canadian federal regulations : This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Canada WHMIS Ingredient Disclosure List: Sodium metasilicate % Sodium Hydoxide % Tetrasodium Ethylene Diamine Acetate % WHMIS classification : Class D 2A Class E Corrosive material WHMIS status: Controlled WHMIS labeling: space space Inventory Status : All components of this product are either on the Domestic substances List (LIS), the Non Domestic Substances List (NDSL) or exempt Page 4 / 5

5 SECTION 16 : OTHER INFORMATION HMIS Rating; Chronic hazard: 0- Minimal 1-Slight 2-Moderate 3-Serious Health : 3 Flammability : 0 Reactivity : 0 Disclaimer of liability: The information in the Material Safety Data Sheet is offered for your consideration and guidance when exposed to this product. Lavo Inc. expressly disclaims all expressed or implied warranties for the accuracy or completeness of the data contained herein and assumes no responsibilities for any involved damages by above data. Product s users have to do their own tests to establish the applicability of the information for a specific use of the product. MSDS data does not apply to use with any other product or in any other process. Other information: For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. References: MSDS of suppliers SIMDUT regulation Prepared by : Lavo Inc Boul. Saint-Jean Baptiste Montreal, QC, Canada H1C 2J3 Téléphone : Issuing date : 31-March-2013 Due date : March Page 5 / 5