Flo-Perm Marine and RV Antifreeze Ethanol Free C Burst Protection SAFETY DATA SHEET

Transcription

1 SECTION 1: Identification 1.1 Product identifier Product name Flo-Perm Marine and RV Antifreeze Ethanol Free C Burst Protection Part #: 92213, 92218, Recommended Use Restrictions on Use RV & Marine Antifreeze Not to be used as heat transfer fluid or as automotive coolant/antifreeze 1.4 Supplier's details Name Address Vulsay Industries Ltd. 35 Regan Road Brampton, Ontario L7A 1B2 Canada Telephone Fax Emergency phone number(s) 24 hours EMERGENCY Phone # SECTION 2: Hazard identification 2.1 GHS classification in accordance with: (CAN) WHMIS 2015 Not a hazardous substance or mixture 2.2 GHS label elements, including precautionary statements Not a hazardous substance or mixture SECTION 3: Composition/information on ingredients 3.2 Mixtures Substance name: Mixture Components Component 1,2-PROPANEDIOL (CAS no.: ) Concentration % (Volume) SECTION 4: First-aid measures 4.1 Description of necessary first-aid measures General advice Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). SDS No. 023E, Date of issue: , p. 1 of 6

2 If inhaled No adverse effects are expected, however, if irritation or other symptoms develop, remove to fresh air. Seek medical attention if symptoms persist. In case of skin contact Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if irritation develops or persists. In case of eye contact If swallowed Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Obtain medical attention if pain, blinking or redness develops or persists. Seek medical attention. Never give anything by mouth to or induce vomiting in an unconscious or drowsy person. 4.2 Most important symptoms/effects, acute and delayed May cause eye irritation. Ingestion of large amounts may cause acidosis and central nervous system effects. 4.3 Indication of immediate medical attention and special treatment needed, if necessary Seek immediate medical attention for large ingestions. NOTES TO PHYSICIAN: Following acute ingestion signs of toxicity unlikely. Ethanol treatment as in ethylene glycol poisoning is inappropriate. There is no specific antidote. Treatment should be directed at the control of symptoms and the clinical condition. Monitor for acidosis and central nervous system effects. SECTION 5: Fire-fighting measures 5.1 Suitable extinguishing media For large fires, use alcohol type or all purpose foam. For small fires, use water spray, carbon dioxide or dry chemical. 5.2 Specific hazards arising from the chemical A solid stream of water or foam directed into hot, burning liquid can cause frothing. Heat from fire may generate flammable vapor. Fine sprays or mists may be combustible at temperatures below the normal flash point. Burning may produce carbon monoxide and carbon dioxide. 5.3 Special protective actions for fire-fighters Firefighters should wear positive pressure self- contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Cool exposed container with water spray or fog. Burning liquid may float on water. SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Wear appropriate protective clothing and equipment (See Section 8). 6.2 Environmental precautions Prevent entry to sewers and public waters. Contact competent authorities after a spill 6.3 Methods and materials for containment and cleaning up Collect with absorbent material and place in appropriate, labeled container for disposal or, if permitted flush spill area with water. SECTION 7: Handling and storage SDS No. 023E, Date of issue: , p. 2 of 6

3 7.1 Precautions for safe handling Avoid eye and prolonged or repeated skin contact. Avoid breathing vapors or mists. Wash exposed skin thoroughly with soap and water after use. Keep container away from open flames and excessive heat. Do not reuse empty containers unless properly cleaned. 7.2 Conditions for safe storage, including any incompatibilities Technical Measures: Comply with applicable regulations. Storage Conditions: Store in a dry, cool, and well-ventilated place. Keep container closed when not in use. Keep/Store away from extremely high or low temperatures. SECTION 8: Exposure controls/personal protection 8.1 Control parameters 1. 1,2-PROPANEDIOL (CAS: ) TWA (Air): 10 mg/m3 (H)(b) occupational Exposure Limits for Ontario Workplaces - Vapour and aerosol. 8.2 Appropriate engineering controls Use general ventilation or local exhaust as required to minimize exposures. 8.3 Individual protection measures, such as personal protective equipment (PPE) Pictograms Eye/face protection Safety glasses or goggles Skin protection Wear suitable protective clothing. Body protection Wear chemically resistant protective gloves. Respiratory protection None normally needed. If exposure limits are exceeded or irritation is experienced, approved respiratory protection should be worn. Environmental exposure controls Prevent entry to sewers, on the ground, and public waters. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Appearance/form (physical state, color, etc.) Odor Pink, slightly viscous liquid SDS No. 023E, Date of issue: , p. 3 of 6

4 Odor threshold ph 9-10 Melting point/freezing point -10 deg C Initial boiling point and boiling range >100 deg C Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability limits LEL: 2.6% (propylene glycol) UEL: 12.5% (propylene glycol) Vapor pressure Vapor density Relative density Solubility(ies) Completely soluble in water Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidizing properties SECTION 10: Stability and reactivity 10.1 Reactivity Normally not reactive 10.2 Chemical stability Stable 10.3 Possibility of hazardous reactions Reactions with strong acids, strong oxidizing agents, and materials reactive with hydroxyl compounds will generate heat 10.4 Conditions to avoid Strong alkalis, strong oxidizing agents Incompatible materials Strong acids, strong oxidizing agents, and materials reactive with hydroxyl compounds Hazardous decomposition products Carbon monoxide and other toxic vapors SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Propylene Glycol: LD50 Oral Rat: 20,000 mg/kg LD50 Skin Rabbit: 20,800 mg/kg Skin corrosion/irritation SDS No. 023E, Date of issue: , p. 4 of 6

5 No significant irritation is expected. Not expected to be absorbed through the skin Serious eye damage/irritation May cause minor eye irritation Respiratory or skin sensitization No significant adverse health effects are expected from inhalation exposure Germ cell mutagenicity Carcinogenicity None of the components of this product are listed as a carcinogen or suspected carcinogen by IARC, NTP, ACGIH, or OSHA. Reproductive toxicity STOT-single exposure INGESTION: Considered relatively non-toxic following acute ingestion, however, lactic acidosis, stupor and seizures have been reported following chronic ingestion and in individuals with underlying kidney disease. Propylene Glycol: LD50 Oral Rat: 20,000 mg/kg LD50 Skin Rabbit: 20,800 mg/kg STOT-repeated exposure None currently known. Aspiration hazard Not classified SECTION 12: Ecological information Toxicity Propylene Glycol: LC50: Daphnia magna, 43,500 mg/l/ 48 hr; LC50: Pimephales promelas, 46,500 mg/l/ 96 hr Persistence and degradability Propylene glycol achieved 64% of its theoretical BOD using a sewage inoculum and a 5 day incubation period Bioaccumulative potential Propylene Glycol has an estimated BCF of 3 suggests the potential for bioconcentration in aquatic organisms is low. Mobility in soil Propylene Glycol is expected to have very high mobility in soil. SECTION 13: Disposal considerations Disposal of the product Dispose of product in accordance with all local, state/provincial and federal regulations. SECTION 14: Transport information SDS No. 023E, Date of issue: , p. 5 of 6

6 Canadian TDG: Not regulated In accordance with DOT Not a dangerous good in sense of transport regulations SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations specific for the product in question Canadian Domestic Substances List (DSL) All ingredients are listed on the DSL/NDSL SECTION 16: Other information SDS Prepared By: Quality Assurance Department Phone #: Preparation date: Aug 23, 2017 Revision #: First Issue Disclaimer The recommendations and data presented herein are based on sources considered to be reliable. However, no. warranty is expressed or implied regarding the accuracy of the data or the results obtained from the use of this information or the use of product. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. SDS No. 023E, Date of issue: , p. 6 of 6