Material Safety Data Sheet Oxalic acid, 0.1 N standard solution

Transcription

1 Page 1 of 5 ACC# Material Safety Data Sheet Oxalic acid, 0.1 N standard solution Section 1 - Chemical Product and Company Identification MSDS Name: Oxalic acid, 0.1 N standard solution Catalog Numbers: AC , AC Synonyms: Ethanedioic acid Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: Section 2 - Composition, Information on Ingredients CAS# Chemical Name Percent EINECS/ELINCS Oxalic acid < Water Balance Hazard Symbols: XN Risk Phrases: 21/22 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear, colorless. Caution! May cause kidney damage. May cause central nervous system effects. May cause eye and skin irritation. May cause respiratory and digestive tract irritation. May cause cyanosis with bluish skin. Target Organs: Kidneys. Potential Health Effects Eye: May cause eye irritation. May result in corneal injury. Skin: Causes skin irritation. May cause irritation with pain and stinging, especially if the skin is abraded. Ingestion: May cause irritation of the digestive tract. Inhalation: May cause kidney damage. Exposure may lead to shock, convulsions, and collapse. Chronic: No information found. Section 4 - First Aid Measures Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water. Ingestion: Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls

2 Page 2 of 5 of milk or water. Inhalation: Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - Firefighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcoholresistant foam. Section 6 - Accidental Release Measures General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Section 7 - Handling and Storage Handling: Not available. Storage: Not available. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits. Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs Oxalic acid 1 mg/m3; 2 mg/m3 STEL 1 mg/m3 TWA 500 mg/m3 IDLH 1 mg/m3 TWA Water none listed none listed none listed OSHA Vacated PELs: Oxalic acid: 1 mg/m3 TWA Water: No OSHA Vacated PELs are listed for this chemical. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Respirators: Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions. Section 9 - Physical and Chemical Properties Physical State: Not available.

3 Page 3 of 5 Appearance: clear, colorless Odor: None reported. ph: Not available. Vapor Pressure: Not available. Vapor Density: Not available. Evaporation Rate:Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point:Not available. Decomposition Temperature:Not available. Autoignition Temperature: Not available. Flash Point: Not available. NFPA Rating: Not published. Explosion Limits, Lower:Not available. Upper: Not available. Solubility: soluble in water Specific Gravity/Density:.9900g/cm3 Molecular Formula:C2H2O4 Molecular Weight:90.04 Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Not available. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information RTECS#: CAS# : RO CAS# : ZC LD50/LC50: CAS# : Oral, rat: LD50 = 7500 mg/kg; CAS# : Oral, rat: LD50 = >90 ml/kg; Carcinogenicity: CAS# : Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. CAS# : Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. Epidemiology: No data available. Teratogenicity: No data available. Reproductive Effects: No data available. Neurotoxicity: No data available. Mutagenicity: No data available. Other Studies: No data available. Section 12 - Ecological Information Ecotoxicity: Not available.

4 Page 4 of 5 Section 13 - Disposal Considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. Section 14 - Transport Information Shipping Name: Hazard Class: UN Number: Packing Group: US DOT IATA RID/ADR IMO No information available. Canada TDG No information available. Section 15 - Regulatory Information US FEDERAL TSCA CAS# is listed on the TSCA inventory. CAS# is listed on the TSCA inventory. Health & Safety Reporting List None of the chemicals are on the Health & Safety Reporting List. Chemical Test Rules None of the chemicals in this product are under a Chemical Test Rule. Section 12b None of the chemicals are listed under TSCA Section 12b. TSCA Significant New Use Rule None of the chemicals in this material have a SNUR under TSCA. SARA Section 302 (RQ) None of the chemicals in this material have an RQ. Section 302 (TPQ) None of the chemicals in this product have a TPQ. SARA Codes CAS # : acute, chronic, flammable. Section 313 No chemicals are reportable under Section 313. Clean Air Act: This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors. Clean Water Act: None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA. OSHA: None of the chemicals in this product are considered highly hazardous by OSHA.

5 Page 5 of 5 STATE CAS# can be found on the following state right to know lists: California, New Jersey, Florida, Pennsylvania, Minnesota, Massachusetts. CAS# is not present on state lists from CA, PA, MN, MA, FL, or NJ. California No Significant Risk Level: None of the chemicals in this product are listed. European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 21/22 Harmful in contact with skin and if swallowed. Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection) CAS# : 1 CAS# : No information available. Canada CAS# is listed on Canada's DSL/NDSL List. CAS# is listed on Canada's DSL/NDSL List. WHMIS: Not available. CAS# is not listed on Canada's Ingredient Disclosure List. CAS# is not listed on Canada's Ingredient Disclosure List. Exposure Limits CAS# : OEL-ARAB Republic of Egypt:TWA 1 mg/m3 OEL-AUSTRALIA :TWA 1 mg/m3;stel 2 mg/m3 OEL-BELGIUM:TWA 1 mg/m3;stel 2 mg/m3 OEL-D ENMARK:TWA 1 mg/m3 OEL-FINLAND:TWA 1 mg/m3;stel 3 mg/m3 OEL-FRANCE:T WA 1 mg/m3 OEL-THE NETHERLANDS:TWA 1 mg/m3 OEL-THE PHILIPPINES:TWA 1 mg/m3 OEL-SWITZERLAND:TWA 1 mg/m3 OEL-UNITED KINGDOM:TWA 1 mg/m3;st EL 2 mg/m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV Section 16 - Additional Information MSDS Creation Date: 12/12/1997 Revision #1 Date: 8/02/2000 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.