Safety Data Sheet (SDS)
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1 NSK-SDS-006(E) Rev Identification Product Description Order code Company Information Company Name Address Dept. TEL FAX Emergency contact No. Recommended use and usage restrictions Safety Data Sheet (SDS) FLASH Pearl T798500, Y900693, Y Quality Assurance Dept. +81(0) (HQ) +81(0) (HQ) Issued on Revised on NAKANISHI INC. 700 Shimohinata Kamuna-shi Tochigi , Japan (HQ) +81(0) (QA) +81(0) (QA) Dental material. For use only by dental professionals. 2. Hazard identification Significant hazards and effects Specific hazards GHS classification Physical and Chemical hazards Explosives Flammable/Ignitable gas Flammable/Ignitable aerosol Burnable/oxidized gas High-pressure gas Ignitable liquid Flammable solid Autoreactive chemical Pyrophoric liquid Pyrophoric solid Self-heating chemical Water-reactive flammable chemical Oxidizing liquid Oxidizing solid Organic peroxide Metal-corrosive chemical Hazards to health Acute toxicity (oral) Acute toxicity (percutaneous) Acute toxicity (inhalation : gas) Acute toxicity (inhalation : vapor) Acute toxicity (inhalation : dust, mist) Skin corrosivity/irritation Serious damage to eyes/eye irritation Respiratory sensitization Skin sensitization Germline mutagenicity Carcinogenicity P1/6
2 Reproductivity Effects on breast-feeding Target organ/systemic toxicity (single exposure) Target organ/systemic toxicity (repeated exposure) Hazards to suction aspiration Hazards to environment Hazards to water environment (acute) Hazards to water environment (chronic) Hazards to the Ozone layer Labeling elements Pictogram Signal word Hazard statements Precautionary statement Prevention Response Storage Disposal No precautionary phrases 3. Composition/information on ingredients Substance / Mixture General product description Mixture Dental material Ingredients and composition Chemical name CAS No. Concentration (another name) (mass %) Calcium carbonate calculated ca. 94% Calcium fluoride <0.5% Calcium nitrate <0.5% Ammonium nitrate <2.0% Tribasic calcium phosphate <0.5% Strontium carbonate <1.5% Danger class./cmnt. 4. First-aid measures General Inhalation Skin contact Eye contact Ingestion Most important symptoms and effects, both acute and delayed Protection of first-aiders Notes to physician 5. Fire-fighting measures Suitable extinguishing medi Similar to other dust nuisance; may cause irritation effects. Move the sufferer to fresh air, keep him/her warm and at rest. Similar to other dust nuisance; may cause irritation to the respiratory Move the sufferer to fresh air, keep him/her warm and at rest. Wash skin thoroughly with soap and water. Flush with large amounts of water (open eyelids) for at least 15 tract. minutes. Get medical advice if irritation persists. Give him/her plenty of water or milk to drink. Use extinguishing media appropriate for surrounding fire. P2/6
3 Unsuitable extinguishing media Specific hazards during firefighting Specific extinguishing methods Special protective equipment for firefighters The product is not combustible. 6. Accidental release measures Personal precautions, Wear protective laboratory glasses. protective equipment and emergency procedures Methods and materials for Use mechanical handling equipment. Collect it in a dry container. containment and cleaning Finally, flush the area with water. up Additional advice 7. Handling and storage Handling General Precautions Advice on safe handling Avoidance of contact Product Transfer Storage Conditions Packaging material Container Advice Store it in a dry place. 8. Exposure controls/personal protection TWA 0.1mg/m3 or less Exposure Control Wash with water. Respiratory Protection Wear a dust-protective mask. Hand protection Eye protection Wear protective laboratory glasses. Skin and body protection 9. Physical and chemical properties Appearance Powder Colour Grayish Odour Odorless Odour Threshold ph ca. 8.5 (10%) pour point Initial boiling point and boiling Flash point Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure P3/6
4 Relative vapour density Relative density Density Solubility(ies) Water solubility Solubility in other solvents Partition coefficient: noctanol/ Auto-ignition temperature Viscosity Viscosity, dynamic Viscosity, kinematic Conductivity Decomposition temperature 10. Stability and reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products ca. 2.5g/cm 3 Slightly Soluble in acids Stable. May ignite upon contact with fluorine gas. Calcium oxide and carbon dioxide are formed upon heating / reaction with acids. 11. Toxicological information Basis for assessment Similar to other dust nuisance; may cause irritation effects. Symptoms of Acute toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT - single exposure STOT - repeated Aspiration toxicity Further information P4/6
5 12. Ecological information Basis for assessment Ecotoxicity Toxicity to fish (Acute toxicity) Toxicity to crustacean (Acute toxicity) Toxicity to algae/aquatic plants (Acute toxicity) Toxicity to fish (Chronic toxicity) Toxicity to crustacean (Chronic toxicity) Toxicity to microorganisms (Acute Persistence and degradability Biodegradability Bioaccumulative potential Bioaccumulation Partition coefficient: noctanol/water Mobility in soil Mobility Other adverse effects no data available Additional ecological information Breakdown 13. Disposal considerations Disposal methods Waste from residues Contaminated Local legislation Remarks: Slowly soluble in water. There are no specific environmental data for the product. Release to water systems will cause a slight increase in alkalinity. Mineralizes. Remarks: Does not bioaccumulate. Not classified as hazardous waste. 14. Transport information National Regulations Hazchem Code International Regulation ADR IATA-DGR IMDG-Code RID Transport in bulk according to the IBC Code Pollution category Not applicable Ship type Not applicable P5/6
6 Product name Special precautions Special precautions for Not applicable Not applicable Not applicable 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Fire Defense Law: Hazardous Material PRTR: Non-Hazardous Material Environmental Quality Standards Regarding Air Pollution (Environment Agency Notification No.25) 16. Other information Reference Recommendation of Occupational Exposure Limits ( ), Japan Society of Occupational Health, J Occup Health, 2007 ; 50 : This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. P6/6
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