Safety Data Sheet acc. to OSHA HCS 29CFR

Transcription

1 Page 1/9 * 1 Identification Relevant identified uses of the substance or mixture and uses advised against No further relevant information available. Details of the supplier of the safety data sheet Manufacturer/Supplier: Kester Inc. 800 West Thorndale Avenue Itasca, IL A Tel (630) Tel International ITW Specialty Materials (Suzhou) Co., Ltd. Heng Qiao Road Wujiang Economic Development Zone Suzhou, Jiangsu China Tel Kester GmbH Ganghofer Strasse 45 D Gernlinden Germany Tel +49 (0) Information department: Product Compliance: EHS_Kester@kester.com Emergency telephone number: CHEMTREC 24-Hour Emergency Response Telephone Number : (800) CHEMTREC 24-Hour Emergency Response (Outside & Canada) Telephone Number : (703) * 2 Hazard(s) identification Classification of the substance or mixture Eye Irrit. 2A H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS07 Signal word Warning Hazard-determining components of labeling: Modified Rosin Halogenated organic diol Hazard statements H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapors/spray (Contd. on page 2)

2 Page 2/9 (Contd. of page 1) P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 If on skin: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0-4) Health = 2 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH *2 FIRE 0 REACTIVITY 0 Health = *2 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vpvb assessment PBT: vpvb: * 3 Composition/information on ingredients Description: Mixture of the substances listed below with nonhazardous additions. CAS No. Description % Range CAS: TIN (Sn) % Modified Rosin 3-5% Skin Sens. 1, H317 CAS: Hexyl diglycol Eye Dam. 1, H318 Acute Tox. 4, H302; Acute Tox. 4, H312 1-<3% 1-3% Heterocyclic derivative % Acute Tox. 3, H301 Repr. 2, H361 Aquatic Chronic 2, H411 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335 Aquatic Acute 2, H401 Halogenated organic diol Acute Tox. 4, H302; Eye Irrit. 2A, H319; Skin Sens. 1B, H <1% SVHC This product does not contain any Substance of Very High Concern (SVHC) on the European Chemicals Agency (ECHA) candidate list. 4 First-aid measures Description of first aid measures General information: Follow general first aid procedures. After inhalation: Supply fresh air; consult doctor in case of complaints. (Contd. on page 3)

3 Page 3/9 (Contd. of page 2) After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: Seek immediate medical advice. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture In case of fire, the following can be released: Advice for firefighters Protective equipment: No special measures required. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Protective Action Criteria for Chemicals PAC-1: CAS: TIN (Sn) 6 mg/m³ CAS: Hexyl diglycol 3.7 mg/m³ 0.3 mg/m³ 3 mg/m³ Heterocyclic derivative 0.97 mg/m³ PAC-2: CAS: TIN (Sn) 67 mg/m³ CAS: Hexyl diglycol 41 mg/m³ 170 mg/m³ 33 mg/m³ Heterocyclic derivative 11 mg/m³ PAC-3: CAS: TIN (Sn) 400 mg/m³ CAS: Hexyl diglycol 480 mg/m³ 990 mg/m³ 200 mg/m³ Heterocyclic derivative 64 mg/m³ (Contd. on page 4)

4 Page 4/9 * 7 Handling and storage Handling: Precautions for safe handling Prevent formation of dust. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. Specific end use(s) No further relevant information available. (Contd. of page 3) * 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. CAS: TIN (Sn) PEL Long-term value: 2 mg/m³ metal REL Long-term value: 2 mg/m³ TLV Long-term value: 2 mg/m³ metal PEL Long-term value: 0.01 mg/m³ REL Long-term value: 0.01 mg/m³ TLV Long-term value: 0.1 mg/m³ metal: dust and fume Additional information: PEL = Permissible Exposure Limit (OSHA) TLV= Threshold Limit Value (ACGIH) OSHA= Occupational Safety and Health Administration ACGIH= American Conference of Governmental Industrial Hygienists Exposure controls Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Breathing equipment: Not necessary if room is well-ventilated. Use suitable respiratory protective device in case of insufficient ventilation. (Contd. on page 5)

5 Page 5/9 Protection of hands: (Contd. of page 4) Protective gloves Material of gloves: Nitrile rubber, NBR Natural rubber, NR Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Safety glasses 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solid Color: Silver grey Odor: Mild ph-value: Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 244 C (471.2 F) Flash point: Flammability (solid, gaseous): Not determined. Auto igniting: Danger of explosion: Vapor pressure: Density: Vapor density Solubility in / Miscibility with Water: Product is not selfigniting. Product does not present an explosion hazard. Not determined. Insoluble. Solvent content: Organic solvents: 0.8 % Solids content: % 10 Stability and reactivity Reactivity No further relevant information available. (Contd. on page 6)

6 Page 6/9 (Contd. of page 5) Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known. * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: Modified Rosin Oral LD50 >4,000 mg/kg (Rat) Dermal LD50 >2,500 mg/kg (rabbit) Primary irritant effect: on the skin: No irritant effect. on the eye: Irritating effect. Sensitization: Sensitization possible through inhalation. Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Harmful Irritant Carcinogenic categories IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) OSHA-Ca (Occupational Safety & Health Administration) 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Additional ecological information: General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: vpvb: (Contd. on page 7)

7 Page 7/9 13 Disposal considerations Waste treatment methods Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. (Contd. of page 6) * 14 Transport information UN-Number DOT, ADR, ADN, IMDG, IATA UN proper shipping name DOT, ADR, ADN, IMDG, IATA Transport hazard class(es) DOT, ADR, ADN, IMDG, IATA Class Packing group DOT, IMDG, IATA Special precautions for user Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code UN "Model Regulation": * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture All ingredients are listed on the following Government Inventories: China: Inventory of Existing Chemical Substances in China (IECSC) Korea: Korea Existing Chemicals List (ECL) Europe: European Inventory of Existing Commercial Chemical Substances (EINECS) Japan: Inventory of Existing and New Chemical Substances (ENCS) Philippines: Philippine Inventory of Chemicals and Chemical Substances (PICCS) A: TSCA (Toxic Substances Control Act) TSCA Inventory of Chemical Substances A The following information relates to product regulation specific to the A. SARA (Superfund Amendments and Reauthorization Act) Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): CAS: Hexyl diglycol TSCA new (21st Century Act) (Substances not listed) All ingredients are listed or exempt from listing. (Contd. on page 8)

8 Page 8/9 California Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity: Carcinogenic categories EPA (Environmental Protection Agency) NIOSH-Ca (National Institute for Occupational Safety and Health) (Contd. of page 7) D D CANADA: Workplace Hazardous Materials Identification (WHMIS): This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulation (CPR) and the (SDS) contains all of the information required by the CPR. GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS07 Signal word Warning Hazard-determining components of labeling: Modified Rosin Halogenated organic diol Hazard statements H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. Precautionary statements P261 Avoid breathing dust/fume/gas/mist/vapors/spray P264 Wash thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 If on skin: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information The information contained herein is based on data considered accurate and is offered solely for information, consideration and investigation. Kester extends no warranties, makes no representations and assumes no responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this Material relates only to this product and does not relate to use with any other material or in any process. All chemical products should be used only by, or under the direction of, technically qualified personnel who are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication regulations require that employees must be trained on how to use a Material as a source for hazard information. Department issuing (SDS): Product Compliance / EHS Department (Contd. on page 9)

9 Page 9/9 (Contd. of page 8) Contact: Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods DOT: Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (A) HMIS: Hazardous Materials Identification System (A) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic SVHC: Substances of Very High Concern vpvb: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Acute Tox. 3: Acute toxicity Category 3 Acute Tox. 4: Acute toxicity Category 4 Skin Irrit. 2: Skin corrosion/irritation Category 2 Eye Dam. 1: Serious eye damage/eye irritation Category 1 Eye Irrit. 2A: Serious eye damage/eye irritation Category 2A Skin Sens. 1: Skin sensitisation Category 1 Skin Sens. 1B: Skin sensitisation Category 1B Repr. 2: Reproductive toxicity Category 2 STOT SE 3: Specific target organ toxicity (single exposure) Category 3 Aquatic Acute 2: Hazardous to the aquatic environment - acute aquatic hazard Category 2 Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard Category 2 * Data compared to the previous version altered.