Safety Data Sheet MasterRoc MP 303CE Hardener also MEYCO MP 303 CE Hardener Revision date : 2013/06/18 Page: 1/6
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1 Revision date : 2013/06/18 Page: 1/6 1. Product and Company Identification Company BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA 24 Hour Emergency Response Information CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) 2. Hazards Identification Emergency overview OXIDIZER. SENSITIZER. IRRITANT. Irritating to eyes, respiratory system and skin. May cause sensitization by inhalation and skin contact. State of matter: solid Colour: white Odour: odourless Potential health effects Acute toxicity: Of moderate toxicity after single ingestion. Virtually nontoxic by inhalation. Virtually nontoxic after a single skin contact. Irritation / corrosion: Irritating to eyes, respiratory system and skin. Assessment other acute effects: Causes temporary irritation of the respiratory tract. Sensitization: May cause sensitization by inhalation and skin contact. Chronic toxicity: Carcinogenicity: No data available concerning carcinogenic effects. Repeated dose toxicity: After repeated exposure the prominent effect is local irritation.
2 Revision date : 2013/06/18 Page: 2/6 Reproductive toxicity: No data available. Teratogenicity: No data available. Genotoxicity: No mutagenic effect was found in various tests with bacteria and mammalian cell culture. The substance was not mutagenic in studies with mammals. Signs and symptoms of overexposure: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Potential environmental effects Aquatic toxicity: Acutely harmful for aquatic organisms. Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. 3. Composition / Information on Ingredients CAS Number Content (W/W) Hazardous ingredients > <= % Peroxydisulfuric acid ([(HO)S(O)2]2O2), disodium salt 4. First-Aid Measures If on skin: Wash thoroughly with soap and water. Under no circumstances should organic solvent be used. If irritation develops, seek medical attention. 5. Fire-Fighting Measures Flash point: Lower explosion limit: Upper explosion limit: Flammability: Self-ignition temperature: not flammable not applicable For solids not relevant for classification and labelling. For solids not relevant for classification and labelling. not self-igniting Suitable extinguishing media: foam, water spray, dry powder, carbon dioxide Unsuitable extinguishing media for safety reasons: water jet Protective equipment for fire-fighting: Wear a self-contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. Containers may rocket or explode in heat of fire. Remove product from areas of fire, or otherwise cool containers with water in order to avoid pressure build up due to heat. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
3 Revision date : 2013/06/18 Page: 3/6 6. Accidental release measures Personal precautions: Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Avoid dust formation. Do not breathe dust. Handle in accordance with good building materials hygiene and safety practice. Environmental precautions: Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. 7. Handling and Storage Handling Protection against fire and explosion: Dust can form an explosive mixture with air. Substance/product in the dry state promotes fires. The relevant fire protection measures should be noted. Storage General advice: Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat or flame. Protect from direct sunlight. 8. Exposure Controls and Personal Protection Components with occupational exposure limits Peroxydisulfuric acid ([(HO)S(O)2]2O2), disodium salt ACGIH TLV TWA value 0.1 mg/m3 (persulfate); Personal protective equipment General safety and hygiene measures: When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). 9. Physical and Chemical Properties Form: crystalline Odour: odourless Odour threshold: No data available. Colour: white ph value: approx. 4.3 ( 10 g/l, 20 C) Melting point: > 180 C Boiling point: not applicable Vapour pressure: ( 20 C) not applicable Density: 1.2 g/cm3 ( 20 C) Bulk density: not determined Vapour density: The product is a non-volatile solid. Partitioning coefficient n ( 25 C) (calculated) octanol/water (log Pow): Viscosity, dynamic: not applicable Solubility in water: 556 g/l ( 20 C)
4 Revision date : 2013/06/18 Page: 4/6 Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Substances to avoid: reducing agents, base metals Hazardous reactions: Contact with combustible material may cause fire. Decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Corrosion to metals: No corrosive effect on metal. Oxidizing properties: Oxidizing. 11. Toxicological information Acute toxicity Oral: Type of value: LD50 Species: rat (male) Value: 895 mg/kg Inhalation: Type of value: LC50 Species: rat (male/female) Value: > 5.1 mg/l (OECD Guideline 403) Exposure time: 4 h Dermal: Type of value: LD50 Species: rabbit (male) Value: > 10,000 mg/kg (other) Genetic toxicity Experimental/calculated data: Ames-test with and without metabolic activation negative Unscheduled DNA synthesis without metabolic activation negative 12. Ecological Information Fish Acute: static Oncorhynchus mykiss/lc50 (48 h): 388 mg/l Nominal concentration.
5 Revision date : 2013/06/18 Page: 5/6 Aquatic plants Toxicity to aquatic plants: static green algae/ec10 (96 h): 33 mg/l Degradability / Persistence Biological / Abiological Degradation Evaluation: Inorganic product which cannot be eliminated from water by biological purification processes. Bioaccumulation Because of the n-octanol/water distribution coefficient (log Pow) accumulation in organisms is not to be expected. Other adverse effects: Do not allow to enter soil, waterways or waste water channels. 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with local authority regulations. Do not discharge into drains/surface waters/groundwater. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Land transport TDG Hazard class: 5.1 Packing group: III ID number: UN 1505 Hazard label: 5.1 Proper shipping name: SODIUM PERSULPHATE Sea transport IMDG Hazard class: 5.1 Packing group: III ID number: UN 1505 Hazard label: 5.1 Marine pollutant: NO Proper shipping name: SODIUM PERSULPHATE Air transport IATA/ICAO
6 Revision date : 2013/06/18 Page: 6/6 Hazard class: 5.1 Packing group: III ID number: UN 1505 Hazard label: 5.1 Proper shipping name: SODIUM PERSULPHATE 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed See user defined text. WHMIS classification: C: Oxidizing Material D2B: Materials Causing Other Toxic Effects - Toxic material THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CPR AND THE MSDS CONTAINS ALL THE INFORMATION REQUIRED BY THE CPR. 16. Other Information We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. SDS Prepared by: BASF NA Product Regulations msds@basf.com BASF HOTLINE (800) 454 COPE (2673) SDS Prepared on: 2013/06/18 END OF DATA SHEET
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