Safety Data Sheet. SECTION 1: Product and company identification. SECTION 2: Hazards identification. Revision date : - Version : 01.

Transcription

1 Safety Data Sheet Issuing date : 28-Nov-2014 SDS # : ICW 0300 N - 01 US EN Revision date : - Version : 01 SECTION 1: Product and company identification Product Identifier Product name Canon Ink Tank CLI-271 < BK > Product Code(s) Use 0390C Ink for Ink Jet Printer Details of the supplier of the safety data sheet Supplier Canon USA, Inc. One Canon Park, Melville, NY 11747, USA Phone number : OK-CANON Emergency phone number : 24 Hr. Emergency CHEMTREC # Canon Canada Inc Dixie Road, Mississauga, Ontario L5T 1P7, Canada Phone number : (1) Emergency phone number : 24 Hr. Emergency CHEMTREC # Manufacturer Canon Inc. 30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo , Japan Emergency Overview Ink tank containing black liquid ink with slight odor. Classification under FHSA Not classified US Label Elements under FHSA Symbol Signal word Hazard statements Precautionary statements Other hazards which do not result in classification SECTION 2: Hazards identification US EN Page 1 / 7

2 0390C Revision date : - Canon Ink Tank CLI-271 < BK > SECTION 3: Composition/information on ingredients Chemical name CAS-No Weight % Glycerin Substituted naphthol azo dye CBI 1-5 Glycol CBI Water Description of first aid measures SECTION 4: First aid measures Inhalation Ingestion Skin Contact Eye Contact Move to fresh air. Get medical attention immediately if symptoms occur. Rinse mouth. Drink 1 or 2 glasses of water. Get medical attention immediately if symptoms occur. Wash off immediately with soap and plenty of water. Get medical attention immediately if symptoms occur. Flush with plenty of water. Get medical attention immediately if symptoms occur. Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin Contact Eye Contact Chronic Effects under normal use. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. under normal use. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. under normal use. under normal use. May cause slight irritation. under normal use. Indication of any immediate medical attention and special treatment needed Extinguishing media Suitable extinguishing media Use CO2, dry chemical, or foam, Water. Unsuitable extinguishing media Special hazards arising from the substance or mixture Special Hazard Hazardous combustion products Carbon dioxide (CO 2), Carbon monoxide (CO) SECTION 5: Firefighting measures US EN Page 2 / 7

3 0390C Revision date : - Canon Ink Tank CLI-271 < BK > Advice for firefighters Special protective equipment for fire-fighters SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid contact with skin, eyes and clothing. Environmental Precautions Keep out of waterways. Methods and material for containment and cleaning up Wipe up with adsorbent material (e.g. cloth, fleece). Precautions for safe handling SECTION 7: Handling and storage Avoid contact with skin, eyes and clothing. Clean contaminated surface thoroughly. Use with adequate ventilation. Conditions for safe storage, including any incompatibilities Keep in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from direct sunlight. Keep away from heat and sources of ignition. Exposure guidelines SECTION 8: Exposure controls/personal protection Chemical name OSHA PEL ACGIH TLV Glycerin TWA: 15 mg/m 3 mist, total particulate TWA: 5 mg/m 3 mist, respirable fraction Appropriate engineering controls under normal use conditions. Individual protection measures, such as personal protective equipment Eye/face Protection under normal use. Skin Protection under normal use. Respiratory Protection under normal use. Information on basic physical and chemical properties SECTION 9: Physical and chemical properties Appearance Odor Odor threshold Black ; Liquid Slight odor US EN Page 3 / 7

4 0390C Revision date : - Canon Ink Tank CLI-271 < BK > ph 6-8 Melting/Freezing point ( C) Boiling Point/Range ( C) Flash Point ( C) ; estimated Evaporation Rate Flammability (solid, gas) Not flammable; Not combustible Flammability Limits in Air Upper Flammability Limit ; estimated Lower Flammability Limit ; estimated Vapor pressure Vapor Density Relative density Solubility(ies) Water; miscible Partition coefficient: n-octanol/water Autoignition Temperature ( C) ; estimated Decomposition Temperature ( C) Viscosity (mpa s) 1-5 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of Hazardous Reactions Conditions to Avoid Incompatible materials Acids, Bases, Oxidizing agents, Reducing agents. Hazardous Decomposition Products Carbon dioxide (CO 2), Carbon monoxide (CO), and/or Ammonia. Information on toxicological effects SECTION 11: Toxicological information Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Sensitization Non-irritant (OECD Guideline) Minimal irritant (OECD Guideline) Non-sensitizer (OECD Guideline) US EN Page 4 / 7

5 0390C Revision date : - Canon Ink Tank CLI-271 < BK > Germ cell mutagenicity Carcinogenicity Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard Ames test: Negative SECTION 12: Ecological information Toxicity Ecotoxicity effects Fish, 96h LC50 > 100 mg/l (OECD Guideline) Crustaceans, 48h EC50 > 100 mg/l (OECD Guideline) Algae, ErC50 (0-72h) > 100 mg/l, NOECr (0-72h) = 3 mg/l (OECD Guideline) NOECr: No Observed Effect Concentration Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects Waste treatment methods Dispose of in accordance with local regulations. SECTION 13: Disposal considerations SECTION 14: Transport information UN number UN Proper Shipping Name Transport Hazard Class Packing Group Environmental Hazards No special environmental precautions required. US EN Page 5 / 7

6 0390C Revision date : - Canon Ink Tank CLI-271 < BK > Special Precautions for users Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not Applicable SECTION 15: Regulatory information Safety, health and environmental regulations specific for the product in question TSCA Sec. 4,5,6,7,8,12b SARA Title III Sec. 313 California Proposition 65 CEPA Sec. 81 HPA (WHMIS) (Manufactured Item) (Manufactured Article) SECTION 16: Other information Key literature references and sources for data - U.S. Department of Labor, 29CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Consumer Product Safety Commission, 16CFR Part ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices - U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens - World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of Chemicals to Humans - California EPA, Code of Regulations Title 27. Division 4. Chapter 1. Safe Drinking Water and Toxic Enforcement Act of Environment Canada, Canadian Environmental Protection Act, Health Canada, Hazardous Products Act, and Controlled Products Regulations - Canada Workplace Hazardous Materials Information System Key or legend to abbreviations and acronyms used in the safety data sheet - OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA) - FHSA: Federal Hazardous Substances Act - IARC: International Agency for Research on Cancer - OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA) - ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists - TWA: Time Weighted Average - STEL: Short Term Exposure Limit - TSCA: Toxic Substances Control Act - SARA Title III: SARA Title III of the Superfund Amendments and Reauthorization Act of Proposition 65: Safe Drinking Water and Toxic Enforcement Act of CEPA: Canadian Environmental Protection Act, HPA: Hazardous Products Act - WHMIS: Workplace Hazardous Materials Information System - CBI: Confidential Business Information Issuing date : 28-Nov-2014 Revision date : - Revision Note US EN Page 6 / 7

7 0390C Revision date : - Canon Ink Tank CLI-271 < BK > Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. US EN Page 7 / 7

8 Safety Data Sheet Issuing date : 28-Nov-2014 SDS # : ICW 0301 N - 01 US EN Revision date : - Version : 01 SECTION 1: Product and company identification Product Identifier Product name Canon Ink Tank CLI-271 < C > Product Code(s) Use 0391C Ink for Ink Jet Printer Details of the supplier of the safety data sheet Supplier Canon USA, Inc. One Canon Park, Melville, NY 11747, USA Phone number : OK-CANON Emergency phone number : 24 Hr. Emergency CHEMTREC # Canon Canada Inc Dixie Road, Mississauga, Ontario L5T 1P7, Canada Phone number : (1) Emergency phone number : 24 Hr. Emergency CHEMTREC # Manufacturer Canon Inc. 30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo , Japan Emergency Overview Ink tank containing cyan liquid ink with slight odor. Classification under FHSA Not classified US Label Elements under FHSA Symbol Signal word Hazard statements Precautionary statements Other hazards which do not result in classification SECTION 2: Hazards identification US EN Page 1 / 7

9 0391C Revision date : - Canon Ink Tank CLI-271 < C > SECTION 3: Composition/information on ingredients Chemical name CAS-No Weight % Glycerin Ethylene urea Substituted phthalocyanine CBI 1-5 Substituted phthalocyanine CBI 1-5 Glycol CBI Water Description of first aid measures SECTION 4: First aid measures Inhalation Ingestion Skin Contact Eye Contact Move to fresh air. Get medical attention immediately if symptoms occur. Rinse mouth. Drink 1 or 2 glasses of water. Get medical attention immediately if symptoms occur. Wash off immediately with soap and plenty of water. Get medical attention immediately if symptoms occur. Flush with plenty of water. Get medical attention immediately if symptoms occur. Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin Contact Eye Contact Chronic Effects under normal use. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. under normal use. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. under normal use. under normal use. May cause slight irritation. under normal use. Indication of any immediate medical attention and special treatment needed Extinguishing media Suitable extinguishing media Use CO2, dry chemical, or foam, Water. Unsuitable extinguishing media Special hazards arising from the substance or mixture Special Hazard SECTION 5: Firefighting measures US EN Page 2 / 7

10 0391C Revision date : - Canon Ink Tank CLI-271 < C > Hazardous combustion products Carbon dioxide (CO 2), Carbon monoxide (CO) Advice for firefighters Special protective equipment for fire-fighters SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid contact with skin, eyes and clothing. Environmental Precautions Keep out of waterways. Methods and material for containment and cleaning up Wipe up with adsorbent material (e.g. cloth, fleece). Precautions for safe handling SECTION 7: Handling and storage Avoid contact with skin, eyes and clothing. Clean contaminated surface thoroughly. Use with adequate ventilation. Conditions for safe storage, including any incompatibilities Keep in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from direct sunlight. Keep away from heat and sources of ignition. Exposure guidelines SECTION 8: Exposure controls/personal protection Chemical name OSHA PEL ACGIH TLV Glycerin TWA: 15 mg/m 3 mist, total particulate TWA: 5 mg/m 3 mist, respirable fraction Appropriate engineering controls under normal use conditions. Individual protection measures, such as personal protective equipment Eye/face Protection under normal use. Skin Protection under normal use. Respiratory Protection under normal use. Information on basic physical and chemical properties SECTION 9: Physical and chemical properties Appearance Cyan ; Liquid US EN Page 3 / 7

11 0391C Revision date : - Canon Ink Tank CLI-271 < C > Odor Slight odor Odor threshold ph 7-9 Melting/Freezing point ( C) Boiling Point/Range ( C) Flash Point ( C) ; estimated Evaporation Rate Flammability (solid, gas) Not flammable; Not combustible Flammability Limits in Air Upper Flammability Limit ; estimated Lower Flammability Limit ; estimated Vapor pressure Vapor Density Relative density Solubility(ies) Water; miscible Partition coefficient: n-octanol/water Autoignition Temperature ( C) ; estimated Decomposition Temperature ( C) Viscosity (mpa s) 1-5 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of Hazardous Reactions Conditions to Avoid Incompatible materials Acids, Bases, Oxidizing agents, Reducing agents. Hazardous Decomposition Products Carbon dioxide (CO 2), Carbon monoxide (CO), and/or Ammonia. Information on toxicological effects SECTION 11: Toxicological information Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Non-irritant (OECD Guideline) Mild irritant (OECD Guideline) US EN Page 4 / 7

12 0391C Revision date : - Canon Ink Tank CLI-271 < C > Sensitization Germ cell mutagenicity Carcinogenicity Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard Non-sensitizer (OECD Guideline) Ames test: Negative SECTION 12: Ecological information Toxicity Ecotoxicity effects Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Dispose of in accordance with local regulations. SECTION 14: Transport information UN number UN Proper Shipping Name Transport Hazard Class Packing Group Environmental Hazards No special environmental precautions required. US EN Page 5 / 7

13 0391C Revision date : - Canon Ink Tank CLI-271 < C > Special Precautions for users Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not Applicable SECTION 15: Regulatory information Safety, health and environmental regulations specific for the product in question TSCA Sec. 4,5,6,7,8,12b SARA Title III Sec. 313 "Copper Compounds" : 5-10 Weight % (as Cu : <0.35 Weight %) California Proposition 65 CEPA Sec. 81 (Manufactured Item) HPA (WHMIS) (Manufactured Article) SECTION 16: Other information Key literature references and sources for data - U.S. Department of Labor, 29CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Consumer Product Safety Commission, 16CFR Part ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices - U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens - World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of Chemicals to Humans - California EPA, Code of Regulations Title 27. Division 4. Chapter 1. Safe Drinking Water and Toxic Enforcement Act of Environment Canada, Canadian Environmental Protection Act, Health Canada, Hazardous Products Act, and Controlled Products Regulations - Canada Workplace Hazardous Materials Information System Key or legend to abbreviations and acronyms used in the safety data sheet - OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA) - FHSA: Federal Hazardous Substances Act - IARC: International Agency for Research on Cancer - OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA) - ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists - TWA: Time Weighted Average - STEL: Short Term Exposure Limit - TSCA: Toxic Substances Control Act - SARA Title III: SARA Title III of the Superfund Amendments and Reauthorization Act of Proposition 65: Safe Drinking Water and Toxic Enforcement Act of CEPA: Canadian Environmental Protection Act, HPA: Hazardous Products Act - WHMIS: Workplace Hazardous Materials Information System - CBI: Confidential Business Information Issuing date : 28-Nov-2014 Revision date : - Revision Note US EN Page 6 / 7

14 0391C Revision date : - Canon Ink Tank CLI-271 < C > Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. US EN Page 7 / 7

15 Safety Data Sheet Issuing date : 30-Jul-2015 SDS # : IJS US EN Revision date : - Version : 01 SECTION 1: Product and company identification Product Identifier Product name Canon Ink Tank CLI-271 < M > Product Code(s) Use 0392C Ink for Ink Jet Printer Details of the supplier of the safety data sheet Supplier Canon USA, Inc. One Canon Park, Melville, NY 11747, USA Phone number : OK-CANON Emergency phone number : 24 Hr. Emergency CHEMTREC # Canon Canada Inc Dixie Road, Mississauga, Ontario L5T 1P7, Canada Phone number : (1) Emergency phone number : 24 Hr. Emergency CHEMTREC # Manufacturer Canon Inc. 30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo , Japan Emergency Overview Ink tank containing magenta liquid ink with slight odor. Classification under FHSA Not classified US Label Elements under FHSA Symbol Signal word Hazard statements Precautionary statements SECTION 2: Hazards identification US EN Page 1 / 7

16 Issuing date : 30-Jul C Revision date : - Canon Ink Tank CLI-271 < M > Other hazards which do not result in classification SECTION 3: Composition/information on ingredients Chemical name CAS-No Weight % Ethylene urea Glycerin Glycol CBI 5-10 Water Description of first aid measures SECTION 4: First aid measures Inhalation Ingestion Skin Contact Eye Contact Move to fresh air. Get medical attention immediately if symptoms occur. Rinse mouth. Drink 1 or 2 glasses of water. Get medical attention immediately if symptoms occur. Wash off immediately with soap and plenty of water. Get medical attention immediately if symptoms occur. Flush with plenty of water. Get medical attention immediately if symptoms occur. Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin Contact Eye Contact Chronic Effects under normal use. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. under normal use. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. under normal use. under normal use. May cause slight irritation. under normal use. Indication of any immediate medical attention and special treatment needed Extinguishing media Suitable extinguishing media Use CO2, dry chemical, or foam, Water. Unsuitable extinguishing media SECTION 5: Firefighting measures US EN Page 2 / 7

17 Issuing date : 30-Jul C Revision date : - Canon Ink Tank CLI-271 < M > Special hazards arising from the substance or mixture Special Hazard Hazardous combustion products Carbon dioxide (CO 2), Carbon monoxide (CO) Advice for firefighters Special protective equipment for fire-fighters SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid contact with skin, eyes and clothing. Environmental Precautions Keep out of waterways. Methods and material for containment and cleaning up Wipe up with adsorbent material (e.g. cloth, fleece). Precautions for safe handling SECTION 7: Handling and storage Avoid contact with skin, eyes and clothing. Clean contaminated surface thoroughly. Use with adequate ventilation. Conditions for safe storage, including any incompatibilities Keep in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from direct sunlight. Keep away from heat and sources of ignition. Exposure guidelines SECTION 8: Exposure controls/personal protection Chemical name OSHA PEL ACGIH TLV Glycerin TWA: 15 mg/m 3 mist, total particulate TWA: 5 mg/m 3 mist, respirable fraction Appropriate engineering controls under normal use conditions. Individual protection measures, such as personal protective equipment Eye/face Protection under normal use. Skin Protection under normal use. US EN Page 3 / 7

18 Issuing date : 30-Jul C Revision date : - Canon Ink Tank CLI-271 < M > Respiratory Protection under normal use. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Appearance Magenta ; Liquid Odor Slight odor Odor threshold ph 7-9 Melting/Freezing point ( C) Boiling Point/Range ( C) Flash Point ( C) ; estimated Evaporation Rate Flammability (solid, gas) Not Applicable Flammability Limits in Air Upper Flammability Limit ; estimated Lower Flammability Limit ; estimated Vapor pressure Vapor Density Relative density Solubility(ies) Water; miscible Partition coefficient: n-octanol/water Autoignition Temperature ( C) ; estimated Decomposition Temperature ( C) Viscosity (mpa s) 1-5 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of Hazardous Reactions Conditions to Avoid Incompatible materials Acids, Bases, Oxidizing agents, Reducing agents. Hazardous Decomposition Products Carbon dioxide (CO 2), Carbon monoxide (CO), and/or Ammonia. US EN Page 4 / 7

19 Issuing date : 30-Jul C Revision date : - Canon Ink Tank CLI-271 < M > Information on toxicological effects SECTION 11: Toxicological information Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Sensitization Germ cell mutagenicity Carcinogenicity Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard Non-irritant (OECD Guideline) Mild irritant (OECD Guideline) Non-sensitizer (OECD Guideline) Ames test: Negative SECTION 12: Ecological information Toxicity Ecotoxicity effects Fish, 96h LC50 > 100 mg/l (OECD Guideline) Crustaceans, 48h EC50 > 100 mg/l (OECD Guideline) Algae, ErC50 (0-72h) > 100 mg/l (OECD Guideline) Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects US EN Page 5 / 7

20 Issuing date : 30-Jul C Revision date : - Canon Ink Tank CLI-271 < M > Waste treatment methods Dispose of in accordance with local regulations. SECTION 13: Disposal considerations SECTION 14: Transport information UN number UN Proper Shipping Name Transport Hazard Class Packing Group Environmental Hazards Special Precautions for users Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No special environmental precautions required. Not Applicable SECTION 15: Regulatory information Safety, health and environmental regulations specific for the product in question TSCA Sec. 4,5,6,7,8,12b SARA Title III Sec. 313 California Proposition 65 CEPA Sec. 81 HPA (WHMIS) (Manufactured Item) (Manufactured Article) SECTION 16: Other information Key literature references and sources for data - U.S. Department of Labor, 29CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Consumer Product Safety Commission, 16CFR Part ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices - U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens - World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of Chemicals to Humans - California EPA, Code of Regulations Title 27. Division 4. Chapter 1. Safe Drinking Water and Toxic Enforcement Act of Environment Canada, Canadian Environmental Protection Act, Health Canada, Hazardous Products Act, and Controlled Products Regulations - Canada Workplace Hazardous Materials Information System US EN Page 6 / 7

21 Issuing date : 30-Jul C Revision date : - Canon Ink Tank CLI-271 < M > Key or legend to abbreviations and acronyms used in the safety data sheet - OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA) - FHSA: Federal Hazardous Substances Act - IARC: International Agency for Research on Cancer - OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA) - ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists - TWA: Time Weighted Average - STEL: Short Term Exposure Limit - TSCA: Toxic Substances Control Act - SARA Title III: SARA Title III of the Superfund Amendments and Reauthorization Act of Proposition 65: Safe Drinking Water and Toxic Enforcement Act of CEPA: Canadian Environmental Protection Act, HPA: Hazardous Products Act - WHMIS: Workplace Hazardous Materials Information System - CBI: Confidential Business Information Issuing date : 30-Jul-2015 Revision date : - Revision Note Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. US EN Page 7 / 7

22 Safety Data Sheet Issuing date : 28-Nov-2014 SDS # : ICW 0303 N - 01 US EN Revision date : - Version : 01 SECTION 1: Product and company identification Product Identifier Product name Canon Ink Tank CLI-271 < Y > Product Code(s) Use 0393C Ink for Ink Jet Printer Details of the supplier of the safety data sheet Supplier Canon USA, Inc. One Canon Park, Melville, NY 11747, USA Phone number : OK-CANON Emergency phone number : 24 Hr. Emergency CHEMTREC # Canon Canada Inc Dixie Road, Mississauga, Ontario L5T 1P7, Canada Phone number : (1) Emergency phone number : 24 Hr. Emergency CHEMTREC # Manufacturer Canon Inc. 30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo , Japan Emergency Overview Ink tank containing yellow liquid ink with slight odor. Classification under FHSA Not classified US Label Elements under FHSA Symbol Signal word Hazard statements Precautionary statements Other hazards which do not result in classification SECTION 2: Hazards identification US EN Page 1 / 7

23 0393C Revision date : - Canon Ink Tank CLI-271 < Y > SECTION 3: Composition/information on ingredients Chemical name CAS-No Weight % Glycerin Ethylene urea Thiadiazole Azo dye CBI 1-5 Glycol CBI Water Description of first aid measures SECTION 4: First aid measures Inhalation Ingestion Skin Contact Eye Contact Move to fresh air. Get medical attention immediately if symptoms occur. Rinse mouth. Drink 1 or 2 glasses of water. Get medical attention immediately if symptoms occur. Wash off immediately with soap and plenty of water. Get medical attention immediately if symptoms occur. Flush with plenty of water. Get medical attention immediately if symptoms occur. Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin Contact Eye Contact Chronic Effects under normal use. Symptoms of overexposure are dizziness, headache, tiredness, nausea, unconsciousness, cessation of breathing. under normal use. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. under normal use. under normal use. May cause slight irritation. under normal use. Indication of any immediate medical attention and special treatment needed Extinguishing media Suitable extinguishing media Use CO2, dry chemical, or foam, Water. Unsuitable extinguishing media Special hazards arising from the substance or mixture Special Hazard SECTION 5: Firefighting measures US EN Page 2 / 7

24 0393C Revision date : - Canon Ink Tank CLI-271 < Y > Hazardous combustion products Carbon dioxide (CO 2), Carbon monoxide (CO) Advice for firefighters Special protective equipment for fire-fighters SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid contact with skin, eyes and clothing. Environmental Precautions Keep out of waterways. Methods and material for containment and cleaning up Wipe up with adsorbent material (e.g. cloth, fleece). Precautions for safe handling SECTION 7: Handling and storage Avoid contact with skin, eyes and clothing. Clean contaminated surface thoroughly. Use with adequate ventilation. Conditions for safe storage, including any incompatibilities Keep in a dry, cool and well-ventilated place. Keep out of the reach of children. Keep away from direct sunlight. Keep away from heat and sources of ignition. Exposure guidelines SECTION 8: Exposure controls/personal protection Chemical name OSHA PEL ACGIH TLV Glycerin TWA: 15 mg/m 3 mist, total particulate TWA: 5 mg/m 3 mist, respirable fraction Appropriate engineering controls under normal use conditions. Individual protection measures, such as personal protective equipment Eye/face Protection under normal use. Skin Protection under normal use. Respiratory Protection under normal use. Information on basic physical and chemical properties SECTION 9: Physical and chemical properties Appearance Odor Yellow ; Liquid Slight odor US EN Page 3 / 7

25 0393C Revision date : - Canon Ink Tank CLI-271 < Y > Odor threshold ph 7-8 Melting/Freezing point ( C) Boiling Point/Range ( C) Flash Point ( C) ; estimated Evaporation Rate Flammability (solid, gas) Not flammable; Not combustible Flammability Limits in Air Upper Flammability Limit ; estimated Lower Flammability Limit ; estimated Vapor pressure Vapor Density Relative density Solubility(ies) Water; miscible Partition coefficient: n-octanol/water Autoignition Temperature ( C) ; estimated Decomposition Temperature ( C) Viscosity (mpa s) 1-5 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable Possibility of Hazardous Reactions Conditions to Avoid Incompatible materials Acids, Bases, Oxidizing agents, Reducing agents. Hazardous Decomposition Products Carbon dioxide (CO 2), Carbon monoxide (CO), and/or Ammonia. Information on toxicological effects SECTION 11: Toxicological information Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Non-irritant (Estimate) (OECD Guideline) Minimal irritant (Estimate) (OECD Guideline) US EN Page 4 / 7

26 0393C Revision date : - Canon Ink Tank CLI-271 < Y > Sensitization Germ cell mutagenicity Carcinogenicity Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration hazard Non-sensitizer (Estimate) (OECD Guideline) Ames test: Negative SECTION 12: Ecological information Toxicity Ecotoxicity effects Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Dispose of in accordance with local regulations. SECTION 14: Transport information UN number UN Proper Shipping Name Transport Hazard Class Packing Group Environmental Hazards Special Precautions for users No special environmental precautions required. US EN Page 5 / 7

27 0393C Revision date : - Canon Ink Tank CLI-271 < Y > Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not Applicable SECTION 15: Regulatory information Safety, health and environmental regulations specific for the product in question TSCA Sec. 4,5,6,7,8,12b SARA Title III Sec. 313 California Proposition 65 CEPA Sec. 81 HPA (WHMIS) (Manufactured Item) (Manufactured Article) SECTION 16: Other information Key literature references and sources for data - U.S. Department of Labor, 29CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Environmental Protection Agency, 40CFR Part U.S. Consumer Product Safety Commission, 16CFR Part ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices - U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens - World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of Chemicals to Humans - California EPA, Code of Regulations Title 27. Division 4. Chapter 1. Safe Drinking Water and Toxic Enforcement Act of Environment Canada, Canadian Environmental Protection Act, Health Canada, Hazardous Products Act, and Controlled Products Regulations - Canada Workplace Hazardous Materials Information System Key or legend to abbreviations and acronyms used in the safety data sheet - OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA) - FHSA: Federal Hazardous Substances Act - IARC: International Agency for Research on Cancer - OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA) - ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists - TWA: Time Weighted Average - STEL: Short Term Exposure Limit - TSCA: Toxic Substances Control Act - SARA Title III: SARA Title III of the Superfund Amendments and Reauthorization Act of Proposition 65: Safe Drinking Water and Toxic Enforcement Act of CEPA: Canadian Environmental Protection Act, HPA: Hazardous Products Act - WHMIS: Workplace Hazardous Materials Information System - CBI: Confidential Business Information Issuing date : 28-Nov-2014 Revision date : - Revision Note Disclaimer The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. US EN Page 6 / 7

28 0393C Revision date : - Canon Ink Tank CLI-271 < Y > US EN Page 7 / 7