80-95 Heavy ends of Polyethylbenzene residue

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1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Recommended use Recommended restrictions Ergon Break Additive ne known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer: Ergon Asphalt & Emulsions, Inc. Address: P. O. Box 1639 Jackson, MS Website: Telephone: (Customer Service) 24 hour Emergency rth America ; International (CHEMTREC): 2. Hazard(s) identification Physical hazards Health hazards Environmental hazards OSHA defined hazards t classified. t classified. t classified. t classified. Label elements Hazard symbol Signal word Hazard statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information ne. ne known. ne. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % Maleated Tall Oil Amide Proprietary Heavy ends of Polyethylbenzene residue 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed < 30 Immediately remove from further exposure. Get immediate medical assistance. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. Give supplemental oxygen, if available. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Flush thoroughly with water. If irritation occurs, get medical assistance. Immediately rinse mouth and provide fresh air. If swallowed, do NOT induce vomiting. Give a glass of water. Call a physician or poison control center immediately. Only induce vomiting at the instruction of medical personnel. Never give anything by mouth to an unconscious person. 1 / 6

2 Indication of immediate medical attention and special treatment needed Treat symptomatically. 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Extinguish with foam, carbon dioxide, dry powder or water fog. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up t applicable. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. In case of fire, toxic and irritating gases may be formed. Keep people away from and upwind of spill/leak. Keep out of low areas. Ventilate closed spaces before entering them. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Extinguish all flames in the vicinity. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Collect spillage. Following product recovery, flush area with water. Prevent product from entering drains. Do not allow material to contaminate ground water system. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills in original containers for re-use. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Wear appropriate personal protective equipment. Avoid eating, drinking and smoking when using the product. Wash hands after handling. Observe good industrial hygiene practices. Do not store this material in open or unlabeled containers. Store in a cool, dry place out of direct sunlight. Keep container in a well-ventilated place. 8. Exposure controls/personal protection Occupational exposure limits Biological limit values Exposure guidelines Appropriate engineering controls exposure limits noted for ingredient(s). biological exposure limits noted for the ingredient(s). exposure standards allocated. Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/face protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear goggles/face shield. Chemical resistant gloves are recommended. If contact with forearms is likely wear gauntlet style gloves. Use protective gloves, goggles and suitable protective clothing. If ventilation is not sufficient to effectively prevent buildup of aerosols or vapors, appropriate NIOSH/MSHA respiratory protection must be provided. When using do not smoke. Do not get in eyes. Do not get this material in contact with skin. When using, do not eat, drink or smoke. Avoid contact with eyes. Avoid contact with skin. Wash hands before breaks and immediately after handling the product. Wash hands after handling and before eating. Keep away from food and drink. Contaminated work clothing should not be allowed out of the workplace. Handle in accordance with good industrial hygiene and safety practice. 2 / 6

3 9. Physical and chemical properties Appearance Odor Physical state Form Color Odor threshold Opaque Liquid. Liquid. Brown ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) > F (> 93.3 C) Pensky-Martens Closed Cup Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Other information Dynamic viscosity Flammability class Pour point 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products 68 deg F soluble cp Combustible IIIB estimated 0 F ( C) Stable. 11. Toxicological information Will not occur. Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Avoid contact with acids. dangerous reaction known under conditions of normal use. 3 / 6

4 Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity US. OSHA Specifically Regulated Substances (29 CFR ) t listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard 12. Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Other adverse effects 13. Disposal considerations Disposal instructions Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT IATA IMDG t regulated as dangerous goods. t regulated as dangerous goods. t regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations ecotoxicity data noted for the ingredient(s). Disposal recommendations are based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal. Do not allow this material to drain into sewers/water supplies. t regulated. Empty containers should be taken to an approved waste handling site for recycling or disposal. TSCA Section 12(b) Export tification (40 CFR 707, Subpt. D) t regulated. CERCLA Hazardous Substance List (40 CFR 302.4) t listed. US. OSHA Specifically Regulated Substances (29 CFR ) t listed. 4 / 6

5 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - SARA 302 Extremely hazardous substance t listed. SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) t regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List t regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) t regulated. Safe Drinking Water Act (SDWA) US state regulations t regulated. US. Massachusetts RTK - Substance List t regulated. US. New Jersey Worker and Community Right-to-Know Act t regulated. US. Pennsylvania RTK - Hazardous Substances t regulated. US. Rhode Island RTK t regulated. US. California Proposition 65 t Listed. International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Canada Canada China Europe Europe Japan Korea New Zealand Philippines United States & Puerto Rico Australian Inventory of Chemical Substances (AICS) Domestic Substances List (DSL) n-domestic Substances List (NDSL) Inventory of Existing Chemical Substances in China (IECSC) European Inventory of Existing Commercial Chemical Substances (EINECS) European List of tified Chemical Substances (ELINCS) Inventory of Existing and New Chemical Substances (ENCS) Existing Chemicals List (ECL) New Zealand Inventory Philippine Inventory of Chemicals and Chemical Substances (PICCS) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date Version # 01 Yes Yes Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 5 / 6

6 Revision Information Product and Company Identification: Product and Company Identification Composition / Information on Ingredients: Ingredients Physical & Chemical Properties: Multiple Properties Transport Information: Material Transportation Information Regulatory Information: United States HazReg Data: International Inventories 6 / 6