SAFETY DATA SHEET. DICHLOROMETHANE For pesticide residue trace analysis 0095B

Transcription

1 Page : 1 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name Product code Identification of the product : : : Dichloromethane CAS No : Relevant identified uses of the substance or mixture and uses advised against Use : Industrial. For professional use only Details of the supplier of the safety data sheet Company identification : 107 Wode House Road, Jehangir Villa, Colaba Mumbai INDIA 1.4. Emergency telephone number Phone nr : (9:00am - 6:00 pm) [ Office hours ] 2. Hazards identification -DSD 2.1. Classification of the substance or mixture Classification EC 67/548 or EC 1999/45 Classification : R40 R36/37/38, R67 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Specific target organ toxicity - repeated exposure, Oral (Category 2), Liver, Blood, H373 Specific target organ toxicity - repeated exposure, Inhalation (Category 2), Central nervous system, H373 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Respiratory system, Central nervous system, H335, H Label elements

2 Page : 2 2. Hazards identification -DSD (continued) Labelling EC 67/548 or EC 1999/45 Symbol(s) Symbol(s) R Phrase(s) S Phrase(s) : Xn : Harmful : Xn Harmful R36/37/38 : Irritating to eyes, respiratory system and skin. R40 : Limited evidence of a carcinogenic effect. R67 : Vapours may cause drowsiness and dizziness : S2 : Keep out of the reach of children. S23 : Do not breathe the gas, fumes, vapours, spray. S24/25 : Avoid contact with skin and eyes. S36/37 : Wear suitable protective clothing and gloves. Labelling Regulation EC 1272/2008 (CLP) Hazard pictograms Signal words Hazard statements Precautionary statements Prevention Response Contains 2.3. Other hazards Other hazards : Danger : H315 : Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs (Liver, Blood) through prolonged or repeated exposure if swallowed. : P261 : Avoid breathing vapours. P281 : Use personal protective equipment as required. P102: Keep out of reach of children. P103: Read label before use. P101: If medical advice is needed, have product container or label at hand. P201: Obtain special instructions before use. : P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. : DICHLOROMETHANE : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH.

3 Page : 3 3. Composition/information on ingredients Substance / Preparation : Dichloromethane CAS No : EC No : Annex No : Substance. Substance name Contents CAS No EC No Annex No REACH Ref. Classification Dichloromethane : 100 % R40-67 Xn; R36/37/38 ; Carc. Cat. 3; R Eye irrit 2 _ H319 Skin Irrit. 2 _ H315 STOT SE 3 _ H335 Contains no other components or impurities which will influence the classification of the product. 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Obtain emergency medical attention. Do NOT induce vomiting. Call a POISON CENTER or doctor if you feel unwell. Rinse mouth Most important symptoms and effects, both acute and delayed Symptoms relating to use : Swallowing a small quantity of this material will result in serious health hazard Indication of any immediate medical attention and special treatment needed General information : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Surrounding fires : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Use water spray or fog for cooling exposed containers Special hazards arising from the substance or mixture Hazardous combustion products : Under fire conditions, hazardous fumes will be present Advice for fire-fighters

4 Page : 4 5. Fire-fighting measures (continued) Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders For non-emergency personnel : Equip cleanup crew with proper protection. Ventilate area. : Evacuate unnecessary personnel Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Clean up methods : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling Handling Technical protective measures : Do not eat, drink or smoke when using this product. Wash thoroughly after handling. : Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage Storage - away from : Keep only in the original container in a cool, well ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. Sources of ignition. Direct sunlight Specific end use(s) Specific end use(s) : None.

5 Page : 5 8. Exposure controls/personal protection 8.1. Exposure controls Personal protection Respiratory protection Hand protection Eye protection Others : Avoid all unnecessary exposure. : Wear approved mask. : Wear protective gloves. : Chemical goggles or safety glasses. : When using, do not eat, drink or smoke Control parameters Occupational Exposure Limits : No data available. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C Colour Odour Odour threshold ph value Melting point [ C] Decomposition point [ C] Critical temperature [ C] Auto-ignition temperature [ C] Flammability (solid, gas) Flash point [ C] Boiling point [ C] Initial boiling point [ C] Final boiling point [ C] Evaporation rate Vapour pressure [20 C] Vapour pressure mm/hg Vapour density Density [g/cm3] Relative density, gas (air=1) Relative density, liquid (water=1) Solubility in water [% weight] Solubility in water Log Pow octanol / water at 20 C : Liquid. : Clear Colorless : Chloroform-like odor : No data available. : Not applicable. : -97 C : 556 C : C : 39.8 C : 40 C : 0.71 : hpa at 20 C : : Slightly soluble : No data available.

6 Page : 6 9. Physical and chemical properties (continued) Solubility Viscosity at 40 C [mm2/s] 9.2. Other information Explosive properties Explosion limits - upper [%] Explosion limits - lower [%] Oxidising properties : No data available. 10. Stability and reactivity Reactivity Reactivity : Not established Chemical stability Chemical stability : Stable under recommended storage conditions Possibility of hazardous reactions Hazardous reactions : Not established Conditions to avoid Conditions to avoid : Direct sunlight. Extremely high or low temperatures Incompatible materials Materials to avoid : Strong acids. Strong bases Hazardous decomposition products Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide. 11. Toxicological information Information on toxicological effects Acute toxicity Inhalation Dermal Ingestion : Harmful if swallowed.

7 Page : Toxicological information (continued) Corrosion Irritation Sensitization Mutagenicity Carcinogenicity Toxic for reproduction STOT-single exposure STOT-repeated exposure Aspiration hazard : Suspected of causing cancer. 12. Ecological information Toxicity Toxicity information : Not established Persistence - degradability Persistence - degradability : Biodegradable Bioaccumulative potential Bioaccumulative potential : Not established Mobility in soil Mobility in soil : Not established Results of PBT and vpvb assessment Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH Other adverse effects Environmental precautions : Avoid release to the environment. 13. Disposal considerations Waste treatment methods General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

8 Page : Transport information Land transport (ADR-RID) Proper shipping name UN N H.I. nr ADR - Class Labelling - Transport : DICHLOROMETHANE : 1593 :60 : 6.1 : 6.1 : Toxic substances. ADR - Classification code ADR - Group ADR - Packing instructions ADR - Limited Quantity ADR - Tunnel code ÉL :T1 : III : P001 R001 LP001 : 5L : E : Passage forbidden through tunnels of category E.» Sea transport (IMDG) [English only] Proper shipping name UN N IMO-IMDG - Class or division IMO-IMDG - Packing group IMO- IMDG - Packing instructions IMO-IMDG - Limited quantities IMO-IMDG - Marine pollution EMS-Nr : DICHLOROMETHANE : 1593 : 6.1 : Toxic substances. : III : P001 LP01 : 5L : NO : F-A S-A Air transport (ICAO-IATA) [English only] Proper shipping name : DICHLOROMETHANE UN N : 1593 IATA - Class or division : 6.1 : Toxic substances. IATA - Packing group : III IATA - Passenger and Cargo Aircraft : ALLOWED - Passenger and Cargo - Packing : 655 instruction

9 Page : Transport information (continued) - Passenger and Cargo - Maximum : 60L Quantity/Packing IATA - Cargo only : ALLOWED - Cargo only - Packing instruction : Cargo only - Maximum Quantity/ : 220 L Packing IATA - Limited Quantites : 2L ERG-Nr :6L 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions. REACH Authorisation - Annex XIV : The components of this product are not subject to authorization Chemical Safety Assessment Chemical Safety Assessment : It has not been carried out. 16. Other information Revision : Revision - See : * Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vpvb: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 List of relevant R phrases (heading 3) : R36/37/38 : Irritating to eyes, respiratory system and skin. R40 : Limited evidence of a carcinogenic effect. R67 : Vapours may cause drowsiness and dizziness. List of full text of H-statements in section 3 Further information : H335 May cause respiratory irritation. H351 Suspected of causing cancer. : None. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the

10 Page : 10 product is used as a component in another product, this MSDS information may not be applicable. End of document