Tools and Methods to Reduce Uncertainties Associated with the Use of In Situ Remediation Techniques for Organic Contaminants in Soil and Groundwater
|
|
- Sharyl Melton
- 5 years ago
- Views:
Transcription
1 Tools and Methods to Reduce Uncertainties Associated with the Use of In Situ Remediation Techniques for Organic Contaminants in Soil and Groundwater by Jean Paré, P. Eng. Toronto, ON July 15 th, 2017
2 The Chemistry works but the geology screws it up by Jean Paré, P. Eng. Toronto, ON July 15 th, 2017
3 Presentation Agenda In Situ Technology Review and Limitations Field application challenges and contact issue Tools, testing and tricks Before you get to the field When you re in the field Follow up After injection events Case Study Presentation Chemco-inc.com
4 In Situ Technology Key Drivers Time versus Money Contaminant Accessibility (infrastructures, utilities) Sustainability Contribution (remote disposal site, landfilling without treatment, Energy Output) Polishing steps to achieve Risk Based Criteria Improvement of contaminant removal rate versus natural attenuation Chemco-inc.com
5 Chemical Oxidation Technology Review Oxidants are introduced or mixed into the soil and groundwater to attack the organic contaminants Chemical oxidation treatments are commonly used in potable and wastewater applications Oxidants are non-specific and will react with the targeted contaminants AND with the soil organic content a value called Soil Oxidant Demand - SOD. Chemical oxidation reactions involve the transfer of electrons and the breaking of chemical bonds Water is the carrier for the oxidants used in chemical oxidation (except for ozone) If you have enough oxidant present and sufficient time you will push reaction to FULL mineralization (CO2, H2O, Cl-) of the contaminant of concern Chemical oxidation can slow down the biological activity but will NOT sterilize the soil completely (potential benefit because of lower toxicity after the Chemical Oxidation is completed)
6 Chemical Oxidation Technology Review Common Chemical Oxidants Potassium or sodium permanganate Hydrogen Peroxide alone Catalyzed Hydrogen Peroxide Hydrogen Peroxide with iron (regular Fenton reagent reaction) Need to establish acidic conditions (ideal ph between 4 and 6) Modified Fenton Reagent with chelated metals (neutral ph) Ozone Ozone is a gas and must be produced on site The gas must be injected into the soil Persulfate Requires activation to generate free sulphate radicals. Heat, chelated metal, high ph, surface, organic or hydrogen peroxide can be used to activate the persulphate. Activation method can be adapted to site conditions. Percarbonate Requires activation to generate free radicals SAFETY NOTE: ALL THESE PRODUCTS REQUIRE ADEQUATE HANDLING PRATICES AND SAFETY EQUIPMENT.
7 Chemical Oxidation Limitations (1) All chemical oxidation reactions occur in the WATER or moisture phase (except for ozone) Kinetics of the chemical oxidation reaction is thus influence by the contaminant of concern solubility and availability in the groundwater or moisture phase Sorbed phase contamination might be challenging to remediate (less available) In NAPL containing sites, contamination can persist because of the highly hydrophobic properties of the chemicals that make up the NAPLs Injection technique must induce proper contact between the contaminant and the oxidant for a proper duration for the required reaction to occurs (kinetics)
8 Chemical Oxidation Limitations (2) All oxidants can change the oxidation state of metals and thus increase their solubility and mobility Metals of particular concern are: chrome, lead, uranium, selenium, vanadium In most of these cases, the metals will come back in their reduced state once all of the oxidant has been consumed by the environment Impurities contained in the oxidant must be evaluated In the case of arsenic, oxidation will help immobilizing the metal by reducing its solubility
9 Conditions for Selecting Chemical Oxidation Chemical Oxidation Applicability Limitation / Disadvantage s Possible Alternative Options Mobile NAPL Probably not the best choice High oxidant requirement ($) Liquid Extraction Thermal degradation Residual NAPL (10,000 s mg/kg) Yes, but difficult High oxidant requirement ($) Extraction with air/steam injection Thermal degradation High conc. in soil/groundwater (10 s s mg/kg) Yes, good conditions Normal considerations Extraction with air/steam injection Bioremediation Dissolved plume (< 1 mg/kg) Yes, but could be costly Higher cost due to SOD Bioremediation, Reactive barriers Source : ITRC 2004 NAPL: Non-Aqueous Phase Liquid
10 Compatibility oxidant/contaminant Contaminant/Oxydant MnO4 S2O8 SO4 * Fenton s Ozone Petroleum Hydrocarbon L G/E E E E BTEX L G G/E E E Phenols G L/G G/E E E 1 Polycyclic Aromatic L G E E E Hydrocarbon (PAH) MTBE L L/G E G G Chlorinated Ethenes E G E E E (PCE, TCE, DCE, VC) Carbon Tetrachloride L G L/G L/G L/G Chlorinated Ethanes L G G/E G/E G (TCA, DCA) Polychlorinated L L L G/E G 1 Biphenyls (PCB) Energetics (RDX, HMX) E G E E E L=Low G=Good E=Excellent 1=Perozone Source: Carus Chemical Company
11 Enhanced Bioremediation Advantages Enhances natural in-situ processes already at play (typically uses natural groundwater gradient, naturally occurring biodegradation. Low energy and cost effective Relatively easy to manage and handle. Can be used in tandem with other remedial technologies that address small amounts of residual soil and groundwater contamination
12 Parameters to consider for a successful enhanced bioremediation Temperature, ph Nutrients Balance (C:N:P ratio) Site geology and hydrogeology consideration Proper micro-organisms presence Aerobic or anaerobic conditions to support bioremediation in soil and groundwater.
13 Chemical Reduction Principles In situ // Ex situ In Situ Chemical Reduction (ISCR) is defined as a process that combines biotic and abiotic reactions to treat contaminants by creating reducing conditions ISCR can be enhanced by anaerobic bioremediation ISCR also provides abiotic/chemical degradation component if a metal (zero valent iron or other) is present
14 Chemical Reduction Compatibility reductant/contaminant Chlorinated Compounds PCE, TCE, cdce, 11DCE, VC 1122TeCA, 111TCA, 12DCA CT, CF, DCM, CM Herbicides, Pesticides Toxaphene, Chlordane, Dieldrin, Pentachlorophenol Energetics TNT, DNT, RDX, HMX, Perchlorate Metals and metalloids As, Cr, Pb, Zn, Cd, Hg, Cu, Cr, Ni, Sb, Co Under aerobic conditions you can target HAP, phtalates, perchlorate, petroleum hydrocarbon In Red: need to have an organic substrate and/or a ZVI/carbon combination
15 Common Chemical Reducing Agents Sugars Molasses high fructose corn syrup whey Fatty acids Lactate Butyrate propionate Emulsified Vegetable Oils Soybean Oil Complex Fermentable Carbon complex lecithine polylactate Zero Valent Iron (ZVI) Soluble Iron Compounds
16 Selection Factors Chemical Reductant ORP of the aquifer Hydrogen vs. Acidity produced Biodegradation rate / longevity Ease of injection and distribution
17 Soil Washing Technology Review Organic Contaminants (Petroleum hydrocarbon, PCB, Dioxin, Furans, etc.) are entrapped as pure product (free phase) or at high concentration in various soil matrix. Highly contaminated soils are bringing challenges for an effective low cost remediation. Soil Washing using co-solvent and/or surfactant offers the benefit to treat effectively and economically these high contaminant concentration that allow for soil to be re-used or dispose at a lower cost.
18 Activated Carbon Technology Review Contaminants sorb to activated carbon Decreases groundwater mass immediately Disrupts groundwater/soil mass equilibrium to help drive desorption Concentrated mass accelerates degradation rates Various degradation mechanisms are used to treat Bioremediation (aerobic/anaerobic) Chemical reduction/oxidation Source: AST
19 Field application challenges and contact issue Good treatment require good contact Application challenges Geology (Silts and Clays, Sands, gravel and other) Heterogeneity Low GW Velocity < Fracture Pressures High Volumes to inject Reagent Kinetics Depth - Shallow environment - Deep environment
20 Tools, testing and tricks Before you get to the field Validating the qualification and quantification of the selected amendment with bench scale lab study Soil and Groundwater amendment validation and treatability study are ALWAYS recommended (If it doesn't work in the lab in ideal contact conditions it WON T work in the field) Make sure you have all the necessary data and your injection plan is set properly Chemco-inc.com
21 Tools, testing and tricks Before you get to the field
22 Tools, testing and tricks When you re in the field Making sure you are injecting in the adequate zone SITE CHARACTERIZATION IS KEY Validating the distribution and dilution of the amendment in the subsurface aquifer through the use of an INERT tracer PRIOR to moving in with your expensive oxidant or amendment. Evaluate the pro and cons of the various equipment and techniques to induce proper contact Confirm Injection Pressure and Flow Assumptions Confirm Formation Acceptance of Design Volume Confirm Vertical and Horizontal Distribution of Reagents Over Time
23 Tools, testing and tricks Search and Destroy Methodology Targeted Distribution Data Gap Analysis High Resolution Characterizatio n 3D Graphing & Conceptual Model Technology Selection High Resolution Remediation Design Distribution Testing Optimized Full Scale Application Troubleshooting Source Cascade Drilling 23
24
25 Search - Why MIP/HPT or LIF before injecting? Locate contaminant mass through high vertical resolution Define injection flows and pressures Don t get fooled by tight sands or clays with low conductivity
26 MIP 3D Imaging Injection Locations
27 Radius of Influence (ROI) Pore Volume ROI ROI Reagent Per Location 500 gals Injection Volume as a % of Effective Pore Volume 100% Pore Volume ROI 2 feet Advection / Dispersion ROI + = Additional ROI from Advection / Dispersion (Feet) Time Frame To Achieve Advection / Dispersion ROI (Days) 60 days 9 feet 7 feet 60 Days 4 10 ROI = P ROI + A/D ROI ROI = pore volume ROI (ft) + advection/dispersion ROI (ft) 9 feet = 2 feet days Kinetics > ROI T
28 ROI Realities Pore Volume ROI ROI Reagent Per Location 500 gals Injection Volume as a % of Effective Pore Volume 50% Pore Volume ROI 2 feet Advection / Dispersion ROI Additional ROI from Advection / Dispersion (Feet) Time Frame To Achieve Advection / Dispersion ROI (Days) 60 days 9 feet 7 feet 60 Days Tight Soils Low Injection Pore Volumes Tighter Spacing Higher Reagent Concentrations Permeable Soils / Flat Gradient Reagent Persistence Requires High Injection Pore Volume Exceed Fracture Pressure Stay Below Fracture Pressure Permeable Soils / Steep Gradient Lower Residence Time
29 Tools, testing and tricks Search and Destroy Methodology Targeted Distribution Data Gap Analysis High Resolution Characterizatio n 3D Graphing & Conceptual Model Technology Selection High Resolution Remediation Design Distribution Testing Optimized Full Scale Application Troubleshooting ROI Injection Volumes Pressure Delivery Tooling Source Cascade Drilling
30 Tools, testing and tricks Follow up After injection events Validate oxidant/amendment distribution (may integrate inert tracer to evaluate dilution factor) with : Core samples Hydro punch sampling Electrical Conductivity Groundwater sampling through monitoring wells
31 Case Study 1 - Outputs Visual Data Dry Cleaner Case Study Injection Strategic Injection Strategy Source: Cascade Drilling
32 Case Study 1 - Outputs Visual Data MIP Post Injection Injection Pre-Injection MIP Strategic Injection Strategy Post-Injection MIP Source: Cascade Drilling
33 About our Expertise, Products and Services Training and Education: technical transfer session, health and safety training; Technology Site Assessment: technology support and selection (chemical oxidation, co solvent-surfactant soil washing and enhanced bioremediation); Products supply, logistic and storage: nutrients, bacterial preparations strains, oxidants, catalysts, oxygen and hydrogen release compounds, co solvent-surfactant blends Laboratory Services and Analysis: Groundwater Parameter Analysis, Tracer Study, Soil and Groundwater Oxidant Demand Evaluation (SOD), Bench Scale Treatability testing.
34 Acknowledgements Carus Chemical AST EOS Peroxychem Progressive Engineering & Construction Vertex Environmental Inc. Cascade Drilling Thank you for your attention! Have a good day!!! jean.pare@chemco-inc.com Tel: // Chemco-inc.com
Prepared by Jean Paré, P. Eng. Chemco Inc.
Tools and Methods to Reduce and Control Uncertainties Associated with the Use of In Situ Remediation Techniques (Chemical Oxidation) for Organic Contaminants in Soil and Groundwater Remtech 2010 Banff,
More informationPrepared by Ken Summerour, P.G.
EXO TECH, INC. Remediation Solutions Provider Specialize in innovative chemical delivery-based solutions (completed over 125 injections/blending applications at 75 + sites since 2006). We provide ISCO/ISCR/Enhanced
More informationMixed Plume Remediation using EHC In-Situ Chemical Reduction and Oxidation Technologies
Mixed Plume Remediation using EHC In-Situ Chemical Reduction and Oxidation Technologies Innovative Solutions for Federal Contaminated Sites in Pacific and Northern Regions October 15, 2008 John Vogan,
More informationField-proven remediation technologies for the most challenging sites.
Field-proven remediation technologies for the most challenging sites. Field-Proven Remediation Technologies The PeroxyChem Environmental Solutions team provides a portfolio of field-proven products and
More informationORIN. Remediation Technologies. ORIN Remediation Technologies. Chemical Treatments. By: Larry Kinsman
Chemical Treatments By: Larry Kinsman Overview! The Chemistries! Implementation! Case Study! Variables on Pricing Chemical Approaches! Chemical Oxidation! Reductive Dechlorination! Metal Stabilization!
More informationCommon Causes of Remediation Failure and Solution Practices
Do it Right, Do it once Common Causes of Remediation Failure and Solution Practices Presented by Derek Ingram, P.E., R.G., P.G. Midwest Operations Manager July 17, 2018 Look Familiar???? You Needed This:
More informationTechnology Overview KLOZUR PERSULFATE
KLOZUR PERSULFATE Klozur persulfate is a high purity environmental grade product used as an in situ chemical oxidation (ISCO) technology to treat a wide variety of contaminants of concern in soil and groundwater
More informationEden Remediation Services Kenneth Summerour, P.G.
Prepared by: Eden Remediation Services Kenneth Summerour, P.G. ken@edenremediation.com 601 S. Madison Avenue, Suite 60 Monroe, GA 30655 Office: 678-635-7360/Cell: 770-241-6176 www.edenremediation.com Overview
More informationNanoFe. Supported Zero-Valent Nanoiron. An Innovative Remediation Technology for Soils and Groundwater. PARS Environmental Inc.
NanoFe Supported Zero-Valent Nanoiron An Innovative Remediation Technology for Soils and Groundwater PARS Environmental Inc. H.S. Gill Ph.D. Tel: 609-890-7277 Introduction NanoFe will remediate recalcitrant
More informationIn Situ Treatment of Contaminated Soil and Groundwater: Lessons Learned from the Field
In Situ Treatment of Contaminated Soil and Groundwater: Lessons Learned from the Field Presented by Alan Weston, Ph.D. Conestoga-Rovers & Associates Niagara Falls, NY, USA Agenda 1. Introduction to In
More informationEx-Situ Soil Washing Achieving Effective Mass Reduction for Organic Contaminant in Soil via the use of a Co solvent/surfactant Process
Ex-Situ Soil Washing Achieving Effective Mass Reduction for Organic Contaminant in Soil via the use of a Co solvent/surfactant Process Presentation summary About our Expertise, Products and Services Project
More informationExtended Release Potassium Persulfate: Laboratory and Field Results
Extended Release Potassium Persulfate: Laboratory and Field Results Brant Smith, Stacey Telesz, and Brianna Desjardins/Peroxychem Jean Pare/Chemco Gord Guest/Geotactical Remediation Technologies Symposium
More informationPermeable Reactive Barriers for Petroleum Hydrocarbons
Vertex Environmental Inc. Permeable Reactive Barriers for Petroleum Hydrocarbons October 14, 2016 Bruce Tunnicliffe Outline What is a PRB? Trap and Treat PRB Case Studies Slow Release Oxidant PRB Questions
More informationTechnologies. Sciences. Clichés 11/21/2017
November 2017 Paul M. Dombrowski, P.E. ISOTEC Remediation Technologies, Inc. Boston Operations Sciences Geology Organic chemistry RedOx Chemistry Microbiology NAPL Transport Advection/Dispersion Matrix
More informationWhat is the CAPISCO process. Technologies used
TOPICS What is the CAPISCO process Technologies used Reference project What is the CAPISCO process Turn key project for VOC pollution Fixed price Payments coupled with achieved results Condition : Condition
More informationChemical Reduction processes for In Situ Soluble Metals Remediation and Immobilization in Groundwater
Chemical Reduction processes for In Situ Soluble Metals Remediation and Immobilization in Groundwater 2014 RPIC Federal Contaminated Sites National Workshop Ottawa 2014 Prepared by Jean Paré, P. Eng. Chemco
More informationCRT CRT. Carus Remediation Technologies. Simplified Science. Carus Remediation Technologies. Carus Remediation Technologies
Simplified Science St Louis Tank Conference 2012 Remediation is complex In Situ remediation is even more complex In life do we try to complicate or simplify? Carus Remediation Technologies Simplified Science
More informationAIPG 4 th Conference: Innovative Environmental Assessment and Remediation Technology
AIPG 4 th Conference: Innovative Environmental Assessment and Remediation Technology Kennesaw State University September 12-13, 2012 Prepared by: Ken Summerour, P.G. Envirorisk Consultants, Inc. www.eriskinc.com
More informationSubsurface Distribution of ZVI/EHC Slurry Validating Radius of Influence. Josephine Molin, PeroxyChem October
Subsurface Distribution of ZVI/EHC Slurry Validating Radius of Influence Josephine Molin, PeroxyChem October 2 2014 Presentation Objective / Outline To empirically summarize our experience from a range
More informationCAP 18 Anaerobic Bioremediation Product CASE STUDY
CAP 18 Anaerobic INTRODUCTION TO ENHANCED ANAEROBIC BIOREMEDIATION (EAB) Enhanced anaerobic reductive dechlorination with non-emulsified and emulsified vegetable oils has been implemented at thousands
More informationComparison of EHC, EOS, and Solid Potassium Permanganate Pilot Studies for Reducing Residual TCE Contaminant Mass
Comparison of EHC, EOS, and Solid Potassium Permanganate Pilot Studies for Reducing Residual TCE Contaminant Mass Defense Distribution Depot San Joaquin-Sharpe Site Lathrop, California Corinne Marks, PE
More informationSafer, More Effective ISCO Remedial Actions Using Non-Extreme Persulfate Activation to Yield Sustained Secondary Treatment
Safer, More Effective ISCO Remedial Actions Using Non-Extreme Persulfate Activation to Yield Sustained Secondary Treatment Michael Scalzi, President Innovative Environmental Technologies, Inc. 6071 Easton
More informationOptimization of ZVI Technology for In-Situ Remediation of Chlorinated Contaminants. Dr. John Freim OnMaterials, LLC Escondido, CA
Dr. John Freim OnMaterials, LLC Escondido, CA Chlorinated Solvent Contamination - Background Dry cleaners PCE used as cleaning agent Many dry cleaning facilities had leaks, spills, improper disposal Former
More informationGroundwater remediation with the use of PRB Technology. PRB TECHNOLOGY haw does it work and when to use it
Groundwater remediation with the use of PRB Technology PRB TECHNOLOGY haw does it work and when to use it Contaminated groundwater is a significant problem for the environment. Halogenated hydrocarbons,
More informationNAVFAC RPM Tech Update: Design Considerations for Enhanced Reductive Dechlorination (ERD)
NAVFAC RPM Tech Update: Design Considerations for Enhanced Reductive Dechlorination (ERD) Distribution Statement A: Approved for Public Release; Distribution is unlimited. Presentation Overview Purpose
More informationCombining Persulfate, In Situ Ferrate Generation and Enhanced Bioremediation for Safer, More Effective Remedial Actions
Combining Persulfate, In Situ Ferrate Generation and Enhanced Bioremediation for Safer, More Effective Remedial Actions Jim Mueller Provectus jim.mueller@provectusenv.com Kevin Finneran Clemson KTF@Clemson.edu
More informationBioremediation Product Series
No. PREX-GEN101007 In-situ Remediation of Contaminated Soil and Groundwater using the Power of Mother Nature Bioremediation Product Series 694-2, Akada, Toyama 939-8064 Japan Phone: +81-76-420-3122 Fax:
More informationEstablishing Contact
ENHANCED IN-SITU BIOREMEDIATION Implementation Design & System Operation CONTACT!!! Impacts of Geology / Contaminant Distribution Delivery system Design / Selection Mike Marley : ~ 1:45 to 3:00pm Establishing
More informationPermeable Reactive Barriers for Petroleum Hydrocarbons. Bruce Tunnicliffe Vertex Environmental Inc.
Permeable Reactive Barriers for Petroleum Hydrocarbons Bruce Tunnicliffe Vertex Environmental Inc. SMART Remediation January 26, 2017 Toronto, Ontario February 16, 2017 O awa, Ontario March 2, 2017 Vancouver,
More informationIn-Situ Chemical Oxidation DOUG HAMILTON, PRINCIPAL HYDROGEOLOGIST ACV ENVIRO
In-Situ Chemical Oxidation DOUG HAMILTON, PRINCIPAL HYDROGEOLOGIST ACV ENVIRO Who am I (or where did I come from)? BS-Geology, BA-Geography Water Resources, MS-Geochemistry Handex mid-1980 s to 1990 hey
More informationEnhanced Reductive Dechlorination to Treat PCE and TCE in a Deep Gravel Aquifer
Enhanced Reductive Dechlorination to Treat PCE and TCE in a Deep Gravel Aquifer Presented by Steven R. Hammer, P.E. SLR International Corp 1800 Blankenship Road #440, West Linn, Oregon MM/DD/YYYY October
More informationAdvancing the Science of In Situ Groundwater Remediation Petroleum Hydrocarbon Remediation Technologies
Advancing the Science of In Situ Groundwater Remediation Petroleum Hydrocarbon Remediation Technologies RemBind Vadose Zone Treatment Tersus is the exclusive North American distributor for RemBind (US
More informationAdvancing the Science of In Situ Groundwater Remediation Petroleum Hydrocarbon Remediation Technologies
Advancing the Science of In Situ Groundwater Remediation Petroleum Hydrocarbon Remediation Technologies TASK Tersus Advanced Surface Kinetics NAPL Surfactants Tersus is the worldwide distributor of the
More informationTREATMENT OF PERCHLORATE AND 1,1,1-TRICHLOROETHANE IN GROUNDWATER USING EDIBLE OIL SUBSTRATE (EOS )
Paper 4B-1, in: A.R. Gavaskar and A.S.C. Chen (Eds.), Remediation of Chlorinated and Recalcitrant Compounds 24. Proceedings of the Fourth International Conference on Remediation of Chlorinated and Recalcitrant
More informationChemical Oxidation: Lessons Learned from the Remediation of Leaking UST Sites
Chemical Oxidation: Lessons Learned from the Remediation of Leaking UST Sites Jerry Cresap, PE Groundwater & Environmental Services gcresap@gesonline.com Agenda Overview of In-Situ Chemical Oxidation Lessons
More informationOPTIMIZATION OF A CHEMICAL OXIDATION TREATMENT TRAIN PROCESS FOR GROUNDWATER REMEDIATION. Gary Cronk, P.E., CHMM
OPTIMIZATION OF A CHEMICAL OXIDATION TREATMENT TRAIN PROCESS FOR GROUNDWATER REMEDIATION Gary Cronk, P.E., CHMM Presentation at the Battelle 5 th International Conference on Remediation of Chlorinated
More informationConceptual System Design
Conceptual System Design Ryan A. Wymore, P.E., CDM NEWMOA Enhanced In Situ Bioremediation Workshop October 5-6, 2010 Acknowledgements ESTCP ITRC Bioremediation of DNAPLs team Tamzen Macbeth (CDM) Kent
More informationImpacts of a Zero Valent Iron PRB on Downgradient Biodegradation Processes. John E. Vidumsky DuPont Corporate Remediation Group
Impacts of a Zero Valent Iron PRB on Downgradient Biodegradation Processes John E. Vidumsky DuPont Corporate Remediation Group Why is Downgradient Biodegradation Important? Significant contaminant mass
More informationSynergistic Treatment of Chlorinated VOCs Using Reductive Dechlorination and Zero Valent Iron
Synergistic Treatment of Chlorinated VOCs Using Reductive Dechlorination and Zero Valent Iron William H. Reid (whr@paynefirm.com), Michael L. Woodruff and Daniel D. Weed (The Payne Firm, Inc., Cincinnati,
More informationBench- and Pilot-Scale Treatability Testing of ISCO and Surfactant Enhanced Biodegradation of Long Chain Petroleum Hydrocarbons
Bench- and Pilot-Scale Treatability Testing of ISCO and Surfactant Enhanced Biodegradation of Long Chain Petroleum Hydrocarbons Steven R. Hammer, P.E. SLR Consulting October 2014 Our Site Current site
More informationA TECHNOLOGY PLATFORM TO HARNESS SPEED AND CERTAINTY IN GROUNDWATER REMEDIATION
A TECHNOLOGY PLATFORM TO HARNESS SPEED AND CERTAINTY IN GROUNDWATER REMEDIATION Barry Poling, CHMM Regional Manager This presentation is the property of REGENESIS Remediation Products and its owner. You
More informationNew England Storage Tank Conference
New England Storage Tank Conference December 4, 2014 Richard Spiese Vermont Department of Environmental Conservation Waste Management & Prevention Division Sites Management Section 1 National Life Drive-Davis
More informationIn Situ Chemical Oxidation of VOCs and BTEX Plume in Low-Permeability Soils. Amit Haryani, PE, LSRP
In Situ Chemical Oxidation of VOCs and BTEX Plume in Low-Permeability Soils Amit Haryani, PE, LSRP Process Map Maintenance Yard Diesel, gasoline, solvents Client Goals Attain NJ GWQS - Rapidly Challenges
More informationChlorinated Solvent Remediation Technologies
Advancing the Science of In Situ Groundwater Remediation Chlorinated Solvent Remediation Technologies TFE CFC-1113 CFC-123a CFC-113 Other, Dhc, Dhb PCE 1,1,2-TCA Other, Dhc, Dhb TCE Other, Dhb Dhc cdce
More informationLecture 6: In Situ Bioremediation and Natural Attenuation
ENGI 7718 Environmental Geotechniques ENGI 9621 Soil Remediation Engineering Lecture 6: In Situ Bioremediation and Natural Attenuation Spring 2011 Faculty of Engineering & Applied Science 1 6.1 Introduction
More informationI. Van Keer, J. Gemoets, K. Touchant, J. Vos & J. Bronders
16/09/2014 Innovative remediation techniques: THE key to sustainable and green remediation? I. Van Keer, J. Gemoets, K. Touchant, J. Vos & J. Bronders ilse.vankeer@vito.be Shrenk et al (2007) Sustainable
More informationIn Situ Activated Carbon-Based Technology for Groundwater Remediation: Overview, Best Practice and Case Studies
In Situ Activated Carbon-Based Technology for Groundwater Remediation: Overview, Best Practice and Case Studies Dimin Fan, Ph.D. Oak Ridge of Institute for Science and Education Fellow Office of Superfund
More informationChlorinated Solvent Remediation Technologies
Advancing the Science of In Situ Groundwater Remediation Chlorinated Solvent Remediation Technologies TFE CFC-1113 CFC-123a CFC-113 Other, Dhc, Dhb PCE 1,1,2-TCA Other, Dhc, Dhb TCE Other, Dhb Dhc cdce
More informationAshley Cedzo, Northwest District Technical Manager
A TECHNOLOGY PLATFORM TO HARNESS SPEED AND CERTAINTY IN GROUNDWATER REMEDIATION: RAPID RISK REDUCTION AND ACCELERATED BIOREMEDIATION FACILITATED BY A COLLODIAL BIOMATRIX Ashley Cedzo, Northwest District
More informationEmulsified Zero-Valent Iron (EZVI): A Combination Technology for ISCR Source Zone Remediation
Emulsified Zero-Valent Iron (EZVI): A Combination Technology for ISCR Source Zone Remediation Presented by: J. Greg Booth, Ph.D. EZVI - Introduction HISTORY Invention of EZVI Scientists at NASA (KSC) and
More informationAdvancing the Science of In Situ Groundwater Remediation Petroleum Hydrocarbon Remediation Technologies
Advancing the Science of In Situ Groundwater Remediation Petroleum Hydrocarbon Remediation Technologies TASK Tersus Advanced Surface Kinetics NAPL Surfactants Tersus is the worldwide distributor of the
More informationIn-situ Remediation Lessons Learned
Slide 1 In-situ Remediation Lessons Learned John Sankey, P.Eng., True Blue Technologies, Long Beach, CA Vancouver, BC Slide 2 In-situ Remediation Lessons Learned Introduction Case studies LNAPL Remediation
More informationEnhanced Bioremediation Field Experience: Using Observed half Lives in Design and Prediction
Enhanced Bioremediation Field Experience: Using Observed half Lives in Design and Prediction NDIA Environment, Energy & Sustainability Symposium & Exhibition. May 4-7, 2009, Denver, CO. Authors: Joanna
More informationBASICS OF PETROLEUM REMEDIATION Rick Fraxedas, PE. October 2, 2009
BASICS OF PETROLEUM REMEDIATION - 101 Rick Fraxedas, PE October 2, 2009 REMEDIATION PROCESS Assessment Design Installation Operation Monitoring Closure ASSESSMENT PROCESS Identify Sources Define Horizontal
More informationEmulsified Zero-Valent Iron (EZVI): A Combination Technology for Source Zone Remediation
Emulsified Zero-Valent Iron (EZVI): A Combination Technology for Source Zone Remediation Prepared by: Dr. Ing. Lorenzo Sacchetti Carus Remediation Technologies Director, Europe, Middle East and Africa
More informationPresenters' Contact Information
Presenters' Contact Information Paul Ranieri Conestoga-Rovers & Associates 2055 Niagara Falls Blvd. Suite Three, Niagara Falls, New York 14304 Phone: 716-297-2160 Email: pranieri@craworld.com CHEMICAL
More informationIn Situ Chemical Reduction of CVOCs and Chromium Facilitated Redevelopment of an Industrial Property
Re3 Conference November 14, 2102 12:00 to 12:30 pm In Situ Chemical Reduction of CVOCs and Chromium Facilitated Redevelopment of an Industrial Property Jim Mueller FMC Chicago, IL jim.mueller@fmc Doug
More informationFull-Scale ISCR and EISB to Treat Chlorinated Solvents in Unsaturated Soils at a Former Chlorinated Solvents Manufacturing Plant
Full-Scale ISCR and EISB to Treat Chlorinated Solvents in Unsaturated Soils at a Former Chlorinated Solvents Manufacturing Plant John Daniels, PG, CAPM Mark Motylewski Groundwater & Environmental Services,
More informationUse of Remox SR+ Cylinders in Treatment for Chlorinated Solvents in Groundwater. Grant Walsom XCG. SMART Remediation Ottawa, ON February 15, 2018
Use of Remox SR+ Cylinders in Treatment for Chlorinated Solvents in Groundwater Grant Walsom XCG SMART Remediation Ottawa, ON February 15, 2018 SMART is Powered by: www.vertexenvironmental.ca Subtitle
More informationSite Profiles - View. General Information. Contaminants: Site Name and Location: Description: Historical activity that resulted in contamination.
Site Profiles - View General Information Site Name and Location: Description: Historical activity that resulted in contamination. Contaminants: Contaminants: Contaminants present and the highest amount
More informationAlternative Cleanup Methods for Chlorinated VOCs
Slide 1 Alternative Cleanup Methods for Chlorinated VOCs Getting beyond pump and treat Slide 2 Soil Vapor Extraction Vacuum is applied through extraction wells Creates a pressure gradient that induces
More informationState of the Practice versus State of the Art in Chemical Oxidation / Reduction Technologies.
State of the Practice versus State of the Art in Chemical Oxidation / Reduction Technologies. Presented by: Mike Marley Principal and Founder Advances in Oxidation and Reduction Technologies for Remediation
More informationRemediation of 1, 4-Dioxane
Do it Right, Do it once Remediation of 1, 4-Dioxane Presented by Mike Marley February 12, 2016 Agenda Basic properties of 1,4-dioxane with respect to remediation A discussion of applicable reliable remedial
More informationAnaerobic Benzene Biodegradation - Insights from Treatability Studies and Molecular Tools. Sandra Dworatzek
Anaerobic Benzene Biodegradation - Insights from Treatability Studies and Molecular Tools Sandra Dworatzek Outline Introduction BTEX degradation and bioremediation Aerobic vs anaerobic Benzene degrading
More informationLance I. Robinson, PE
BASICS OF PETROLEUM REMEDIATION - 101 Lance I. Robinson, PE November 6, 2009 REMEDIATION PROCESS Assessment Design Installation Operation Monitoring Closure ASSESSMENT PROCESS Identify Sources Define Horizontal
More informationTerra Systems Capabilities Document Research Product Development Manufacturing Distribution
Terra Systems Capabilities Document Research Product Development Manufacturing Distribution Core Competencies 1. Operates its own U.S. manufacturing plant with a full time U.S. production staff 2. Flexible
More informationORIN Remediation Technologies Chemical Treatments
ORIN Remediation Technologies Chemical Treatments By: Larry Kinsman ORIN s Services In-house Treatability Remediation Services laboratory Construction Management GC- VOC s In-situ and Ex-situ ICP treatment
More informationCatalyzed Persulfate Remediation of Chlorinated and Recalcitrant Compounds in Soil
Catalyzed Persulfate Remediation of Chlorinated and Recalcitrant Compounds in Soil Shanna Thompson, E.I.T. (shanna.thompson@erm.com), Jack Riggenbach, P.E., DEE (ERM, Kennesaw, GA), Richard A. Brown, PhD
More informationBioremediation of Comingled 1,4-Dioxane and Chlorinated Solvent Plumes
Bioremediation of Comingled 1,4-Dioxane and Chlorinated Solvent Plumes Bilgen Yuncu, PhD, PE; Jessica L. Keener, PG and Robert C. Borden, PhD, PE Solutions-IES, Inc., Raleigh, NC TCE PCE Stephen D. Richardson,
More informationPhytoremediation Technology Evaluation and Preliminary Design
Phytoremediation Technology Evaluation and Preliminary Design Chlorinated and Petroleum Hydrocarbon Groundwater Plume at Former Gas Liquids Extraction Facility, Colorado November 13, 2012 Dustin Krajewski
More informationBASICS OF PETROLEUM REMEDIATION Geoff Schaefer, PE. October 29, 2009
BASICS OF PETROLEUM REMEDIATION - 101 Geoff Schaefer, PE October 29, 2009 REMEDIATION PROCESS Assessment Design Installation Operation Monitoring Closure ASSESSMENT PROCESS Identify Sources Define Horizontal
More informationTHE USE OF VEGETABLE OIL SUBSTRATE S IN THE TREATMENT OF CONTAMINATED GROUNDWATER
THE USE OF VEGETABLE OIL SUBSTRATE S IN THE TREATMENT OF CONTAMINATED GROUNDWATER M. Pienaar 1, S. Labuschagne and D. Duthe 2 1 SRK Consulting, IBM House, 54 Norfolk Terrace, Westville, Durban, KwaZulu
More informationAn Investigation on Remediation of Transformer Oil Contaminated Soil by Chemical Oxidation Using Hydrogen Peroxide
An Investigation on Remediation of Transformer Oil Contaminated Soil by Chemical Oxidation Using Hydrogen Peroxide Y. Chang,, G. Achari and C.H. Langford University of Calgary, Calgary Alberta Canada Biological
More informationCASE STUDY COMPARISON OF MULTIPLE ACTIVATION METHODS FOR SODIUM PERSULFATE ISCO TREATMENT
CASE STUDY COMPARISON OF MULTIPLE ACTIVATION METHODS FOR SODIUM PERSULFATE ISCO TREATMENT Gary Cronk, P.E. (JAG Consulting Group) Presentation at the Battelle 6 th International Conference on Remediation
More informationVertex Environmental Inc.
Vertex Environmental Inc. Optimizing Oxidant Delivery for In-Situ Remediation Remediation Technologies Symposium 2012 Banff, Alberta October 19, 2012 Bruce Tunnicliffe Overview Background Purpose of Talk
More informationIN-SITU BIOLOGICALLY MEDIATED REMEDIATION. Margy Gentile September 30, 2016
IN-SITU BIOLOGICALLY MEDIATED REMEDIATION Margy Gentile September 30, 2016 Disclaimers and Notices The materials herein are intended to furnish viewers with a summary and overview of general information
More informationBioremediation Approaches and Tools for Anaerobic Benzene Remediation. Sandra Dworatzek SiREM. SMART Remediation Toronto, ON January 26, 2017
Bioremediation Approaches and Tools for Anaerobic Benzene Remediation Sandra Dworatzek SiREM SMART Remediation Toronto, ON January 26, 2017 SMART is Powered by: www.vertexenvironmental.ca Bioremediation
More informationCase Study Catalyzed Hydrogen Peroxide Treatment of a TCE DNAPL Plume
Case Study Catalyzed Hydrogen Peroxide Treatment of a TCE DNAPL Plume - 10073 Steven L. Thompson, Paul Cross and Del R. Baird CDM, Piketon, Ohio 45661 ABSTRACT The U.S. Department of Energy (DOE) is responsible
More informationBeyond Dig and Haul: A survey of Remedial Technologies. NYS Department of Environmental Conservation
Beyond Dig and Haul: A survey of Remedial Technologies Agenda (20 Minutes) Excavations Bioremediation ISCO SVE Thermal treatment Remedy Selection Do not select the remedy before you investigate the site
More informationBioremediation Approaches and Tools for Anaerobic Benzene Remediation. SMART Remediation Ottawa, ON February 16, 2017
Bioremediation Approaches and Tools for Anaerobic Benzene Remediation Phil Dennis SiREM SMART Remediation Ottawa, ON February 16, 2017 SMART is Powered by: www.vertexenvironmental.ca Bioremediation Approaches
More informationIn Situ Chemical Reduction (ISCR) Fundamentals related to selection, design and distribution of ISCR technologies at contaminated sites
In Situ Chemical Reduction (ISCR) Fundamentals related to selection, design and distribution of ISCR technologies at contaminated sites Ravi Srirangam P.E., Ph.D. PeroxyChem Environmental Solutions Design
More informationEnhanced Bio Remediation of Heavy PHCs and PAHs Through Dedicated Endogenous Micro Organisms Biostimulation. Charles Lamontagne Chemco, Inc.
Enhanced Bio Remediation of Heavy PHCs and PAHs Through Dedicated Endogenous Micro Organisms Biostimulation Charles Lamontagne Chemco, Inc. SMART Remediation O awa, ON February 15, 2018 SMART is Powered
More informationEnvironmental Solutions. Klozur CR. Combined Chemical and Bio-Remediation
Combined Chemical and Bio-Remediation Klozur CR A combination mixture that supports a two fold mechanism for treating contaminates of concern, short term In Situ Chemical Oxidation (ISCO), with alkaline
More informationENVIRONMENTAL GEOLOGY - GEOL 406/506
ENVIRONMENTAL GEOLOGY - GEOL 406/506 Glossary of useful Terms: 1. Abiotic: not living. 2. A b s o r p t i o n: the penetration of atoms, ions, or molecules into the bulk mass of substrate. 3. Acclimation:
More informationPlume Cut-Off Treatment Example
Page 1 of 5 H R C T E C H N I C A L B U L L E T I N # 2. 5. 2 Plume Cut-Off Treatment Example A biologically active barrier treatment zone can be constructed by applying HRC in rows of injection points.
More informationRecent Field Applications of Activated Persulfate Including Petroleum Sites
Recent Field Applications of Activated Persulfate Including Petroleum Sites Philip Block, PhD FMC Corporation Presentation Outline Brief Introduction to Persulfate Chemistry Activated Persulfate Treatment
More informationS-ISCO REMEDIATION OF COAL TAR
Case Study Site Former Roofing Products Manufacturer, Queens, New York Contaminants of Concern VOCs (BTEX) & SVOCs (PAHs and naphthalene) related to MGP coal tar in soil & groundwater East River S-ISCO
More informationAnaerobic Bioremediation of Chlorinated Solvents in Groundwater Using Edible Oil Substrate EOS
Anaerobic Bioremediation of Chlorinated Solvents in Groundwater Using Edible Oil Substrate EOS Matt Sedor, M.S., Yonathon Yoseph, P.G., C.H.G. (Remediation Sciences, Inc.) Jeff Baker (Vironex, Inc. ),
More informationAnnemarie L. Douglas, Ph.D. R&D Coordinator HydroQual Laboratories Ltd.
The Use of DNA Technologies in Determining the Biotreatability of Chlorinated Aliphatic Hydrocarbons Annemarie L. Douglas, Ph.D. R&D Coordinator HydroQual Laboratories Ltd. HydroQual Laboratories Ltd Wholly-owned
More informationTreatability Testing--Fate of Chromium During Oxidation of Chlorinated Solvents
Treatability Testing--Fate of Chromium During Oxidation of Chlorinated Solvents Jane Chambers, Alan Leavitt, Caryl Walti (Northgate Environmental Management, Oakland, California, USA) Cindy G. Schreier
More informationDr. Henning Wallner. Soil Contamination Study Meeting. Antalya. March 22 nd 2017
Implementation of Auxiliary-Substrates to enhance the Degradation of Chlorinated Hydrocarbons in anaerobic Systems (Experiences with ARDEC based on a Case Study) Dr. Henning Wallner Soil Contamination
More informationJames Studer, 2 Barry Ronellenfitch, 2 Adam Mabbott, 2 Heather Murdoch, 2 Greg Whyte, and 3 Ian Hakes. REMTECH 2008 at Banff, Alberta
PILOT TEST OF ISCO TECHNOLOGIES LEADS TO IMPROVED UNDERSTANDING OF IMMEDIATE AND MID-TERM GEOCHEMICAL RESPONSE AND CONTAMINANT DESTRUCTION WITHIN PETROLEUM HYDROCARBON PLUME 1 James Studer, 2 Barry Ronellenfitch,
More informationOverburden and Bedrock Remediation Using Activated Carbon Based Injectates. Mike Mazzarese AST Environmental, Inc.
Overburden and Bedrock Remediation Using Activated Carbon Based Injectates Mike Mazzarese AST Environmental, Inc. SMART Remediation Toronto, ON SMART is Powered by: www.vertexenvironmental.ca Overburden
More informationZero-Valent Iron for Groundwater Remediation Lessons Learned over 20 years of Technology Use. Andrzej Przepiora and Jeff Roberts
Zero-Valent Iron for Groundwater Remediation Lessons Learned over 20 years of Technology Use Andrzej Przepiora and Jeff Roberts RemTech 2016 Oct. 12-14, 2016 ZVI-Based Remediation Milestones Extensive
More informationFIELD IMPLIMENTATION OF ANAEROBIC DECHLORINATION UTILIZING ZERO-VALENT IRON WITH AN ORGANIC HYDROGEN DONOR
FIELD IMPLIMENTATION OF ANAEROBIC DECHLORINATION UTILIZING ZERO-VALENT IRON WITH AN ORGANIC HYDROGEN DONOR Michael Scalzi (IET@IET-INC.NET) (Innovative Environmental Technologies, Pipersville, PA, USA)
More informationBiological Treatment of Residual DNAPL
Biological Treatment of Residual DNAPL Scott B. Wilson President Regenesis In Situ Treatment of Groundwater Contaminated with Non-Aqueous Phase Liquids: Fundamentals and Case Studies EPA TIO, EPA Region
More informationKentucky and Beyond BOS 200 Success Story. The RPI Group Approach to In-situ Petroleum Hydrocarbon Remediation
Kentucky and Beyond BOS 200 Success Story The RPI Group Approach to In-situ Petroleum Hydrocarbon Remediation 20 Years Serving the Environmental Industry Health and Safety is the number one priority at
More information4 major challenges in the source zone!!! Source Zone Remediation with innovative Technologies. Very large reductions wanted/needed
Source zone & plumes Source Zone Remediation with innovative Technologies Tom Heron Geologist & Head of Department Stockholm Aalborg Århus Esbjerg København Odense Poznan Warszwa Krakóv Helsinki Sofia
More informationDelivery Approaches for Groundwater Amendments
Delivery Approaches for Groundwater Amendments Tom Krug 1, Michaye McMaster 1, Evan Cox 1, Jamey Rosen 1, Carl Elder 2, Robert Borch 3, and Neal Durant 4 Consultants, Guelph 1 Boston 2, Portland 3, Columbia
More information