KLARAID CDP2727 SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. 3. Composition/information on ingredients

Transcription

1 Version: 4.0 Effective Date: Aug Previous Date: Jul SAFETY DATA SHEET KLARAID* CDP Identification Product identifier Other means of identification Recommended use Recommended restrictions KLARAID CDP2727 None. Coagulant None known. Company/undertaking identification GE Betz, Inc Somerton Road Trevose, PA T , F Emergency telephone (800) Hazard(s) identification Physical hazards Health hazards OSHA defined hazards Label elements Serious eye damage/eye irritation Category 2 Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Causes serious eye irritation. Wear eye/face protection. Wash thoroughly after handling. Wear eye/face protection. Observe good industrial hygiene practices. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Store in a closed container. Dispose of waste and residues in accordance with local authority requirements. None known. None. 3. Composition/information on ingredients Mixtures Components CAS # Percent Aluminium chlorhydroxide Page: 1 / 7

2 Components CAS # Percent N,N-Dimethyl-N-2-propenyl-2-propen- 1-amonium chloride homopolymer Composition comments 4. First-aid measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions Specific methods General fire hazards Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this SDS for our assessment of the potential hazards of this formulation. Move to fresh air. Wash off with soap and water. Remove contact lenses, if present and easy to do. Immediately flush eyes with plenty of water for at least 15 minutes. Keep eyelids apart. Get medical attention immediately. Get medical attention if symptoms occur. Rinse mouth. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Carbon dioxide, dry chemicals, foam, water spray (fog). Do not use water jet as an extinguisher, as this will spread the fire. Spills produce extremely slippery surfaces. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. In case of fire and/or explosion do not breathe fumes. Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. Cool containers / tanks with water spray. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Flush with plenty of water. Ventilate the area. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. Water contaminated with this product may be sent to a sanitary sewer treatment facility, or a permitted waste treatment facility, in accordance with any local agreements. Avoid contact with eyes. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Product is not compatible with stainless steel. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Do not freeze. If frozen, thaw completely and mix thoroughly prior to use. Page: 2 / 7

3 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Components Aluminium chlorhydroxide (CAS ) US. NIOSH: Pocket Guide to Chemical Hazards Components Aluminium chlorhydroxide (CAS ) Biological limit values Type Value Form TWA 1 mg/m3 Respirable fraction. Type TWA No biological exposure limits noted for the ingredient(s). Value 2 mg/m3 Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Splash proof chemical goggles. Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations 9. Physical and chemical properties Appearance Color Odor Physical state Odor threshold ph (concentrated product) 4.2 Melting point/freezing point Initial boiling point and boiling range Flash point Wear appropriate chemical resistant gloves. The choice of an appropriate glove does not only depend on its material but also on other quality features and is different from one producer to the other. Glove selection must take into account any solvents and other hazards present. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. Wear appropriate thermal protective clothing, when necessary. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Light yellow Liquid < 23 F (< -5 C) 212 F (100 C) Not applicable. Evaporation rate < 1 (Ether = 1) Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor pressure temp. 18 mm Hg 70 F (21 C) Vapor density < 1 (Air = 1) Relative density 1.1 Relative density temperature 70 F (21 C) Page: 3 / 7

4 Solubility(ies) Solubility (water) 100 % Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Viscosity temperature Other information Percent volatile Pour point Specific gravity Stability and reactivity Reactivity Chemical stability 70 F (21 C) 0 (Estimated) < 23 F (< -5 C) The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Incompatible materials Hazardous decomposition products 11. Toxicological information Contact with incompatible materials. None under normal conditions. Strong oxidizing agents. Hydrogen chloride, oxides of carbon and nitrogen evolved in fire. Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. May cause irritation to respiratory organs. Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Components Aluminium chlorhydroxide (CAS ) Acute Dermal LD50 Oral LD50 May cause irritation. Causes serious eye irritation. May cause slight gastrointestinal irritation with possible nausea, vomiting, abdominal discomfort and diarrhea. Causes serious eye irritation. Irritant effects. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Species Rabbit Rat N,N-Dimethyl-N-2-propenyl-2-propen- 1-amonium chloride homopolymer (CAS ) Acute Oral LD50 Rat * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation May be irritating to the skin. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization Skin sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization. Test Results > 2000 mg/kg > 2000 mg/kg 3000 mg/kg Page: 4 / 7

5 Germ cell mutagenicity Carcinogenicity IARC Monographs. Overall Evaluation of Carcinogenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR ) US. National Toxicology Program (NTP) Report on Carcinogens Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects 12. Ecological information Ecotoxicity Product KLARAID CDP2727 (CAS Mixture) Aquatic Crustacea This product is not expected to cause reproductive or developmental effects. Prolonged inhalation may be harmful. The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. LC50 LC50 Species Fathead Minnow Daphnia magna Test Results 1.76 mg/l, Acute Toxicity, 96 hour, (Estimated) 18.5 mg/l, Acute Toxicity, 48 hour, (Estimated) * Estimates for product may be based on additional component data not shown. Bioaccumulative potential Mobility in soil Other adverse effects Persistence and degradability No data available. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. No data is available on the degradability of this product. 13. Disposal considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Page: 5 / 7

6 15. Regulatory information US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) CERCLA Hazardous Substance List (40 CFR 302.4) SARA 304 Emergency release notification All components are on the U.S. EPA TSCA Inventory List. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Yes Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). US state regulations US - Massachusetts RTK - Substance List US - Pennsylvania RTK - Hazardous Substances Aluminium chlorhydroxide (CAS ) US - Rhode Island RTK US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) US. New Jersey Worker and Community Right-to-Know Act US. Pennsylvania Worker and Community Right-to-Know Law Aluminium chlorhydroxide (CAS ) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. No Yes Page: 6 / 7

7 US - California Proposition 65 - CRT: Listed date/carcinogenic substance US - California Proposition 65 - CRT: Listed date/developmental toxin US - California Proposition 65 - CRT: Listed date/female reproductive toxin US - California Proposition 65 - CRT: Listed date/male reproductive toxin 16. Other information, including date of preparation or last revision Issue date Revision date Version # 4.0 List of abbreviations References: Disclaimer Prepared by Aug Aug CAS: Chemical Abstract Service Registration Number TSRN indicates a Trade Secret Registry Number is used in place of the CAS number. ACGIH: American Conference of Governmental Industrial Hygienists NOEL: No Observed Effect Level STEL: Short Term Exposure Limit LC50: Lethal Concentration, 50% TWA: Time Weighted Average BOD: Biochemical Oxygen Demand COD: Chemical Oxygen Demand TOC: Total Organic Carbon IATA: International Air Transport Association IMDG: International Maritime Dangerous Goods Code LD50: Lethal Dose, 50% NFPA: National Fire Protection Association No data available The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. This SDS has been prepared by GE Water & Process Technologies Regulatory Department ( ). * Trademark of General Electric Company. May be registered in one or more countries. Page: 7 / 7