MATERIAL SAFETY DATA SHEET. Product Name. Pool Lab Sparkle Blue

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1 ZODIAC POOL CARE SOUTH AFRICA Reg No. 1987/001774/07 Private Bag X 127, Halfway House, Slate Road, N1 Business Park Old Johannesburg & Tolkwa Streets, KOSMOSDAL Tel : +27 (0) Fax : +27 (0) MATERIAL SAFETY DATA SHEET Product Name Pool Lab Sparkle Blue 1. Chemical Product / Company Identification 1.1 Product Name APCA-WT 1.2 Chemical Name: Polyamine 1.3 Chemical Family: Amines and derivatives UN No Composition / Information on ingredients: Substance / preparation: preparation All ingredients classified as Hazardous to health or the environment, within the current knowledge of the supplier and in the concentrations applicable, have been reported above, in compliance with the Occupational Health & Safety Act 85 of 1993 Please refer to section 3 for the classification of the final product as supplied. 3. Hazard Identification The product is classified as dangerous according to Directive 1999/45/EC and its amendments Classification Xn,R22 N,R50 Human Health Hazards Harmful if swallowed Environmental hazards Very Toxic to Aquatic organisms Flammability Not Available Product in the eye: 4. First Aid Measures Immediately flush the eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 15 minutes. Get medical attention of irritation occurs. Issue:06/06/20134 Product Name: Poly quarternary ammonium chloride Page 1 of 5

2 Product on the skin: Product ingested: Product Inhaled: Wash exposed area with plenty of water. Repeat washing. Remove contaminated clothing and shoes, and wash thoroughly before re-use. If irritation persists, consult a physician. DO NOT INDUCE VOMITING: Rinse with copious amounts of water or milk first. Irrigate the oesophagus and dilute stomach contents by slowly giving one (1) or two (2) glasses of water or milk. Avoid giving alcohol or alcohol related products. In cases where the individual is semi-comatose, comatose or convulsing, DO NOT GIVE FLUIDS BY MOUTH. In case of intentional ingestion of the product, seek medical assistance immediately; take individual to nearest medical facility. Move exposed person to fresh air. Keep the person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. NOTE TO PHYSICIAN; No product specific antidote is known. Probable mucosal damage may contraindicate the use of gastric lavage. Treat symptoms. For specialist medical advice in the event of an emergency contact or Fire Fighting Measures Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical powder. Special Hazards: Protective clothing: None known Body-protective clothing 6. Accidental Release Measures Personal Precautions: Environmental Precaution: Spills: Rubber gloves and safety glasses or goggles required. Eye wash fountains in the work place are strongly recommended. Bodyprotective clothing and shoes are recommended. Do not discharge concentrated, undiluted product into lakes, streams, ponds, estuaries, oceans and other waters. Liquids: Dam area to prevent spill from spreading. Clay, soil or commercially available absorbents may be used to recover any material that cannot be recovered as pure product. Liquids/Solids/Powder: Minimise adverse effects on the environment. Recover as much as possible of the pure product into appropriate containers. Later, determine if this recovered product can be used for its intended purpose. Dispose of in an approved landfill. 7. Handling and Storage Suitable Material: The concentrated product can be handled and stored in stainless steel, aluminium, and most plastic materials of construction. Handling/Storage Issue:06/06/20134 Product Name: Poly quarternary ammonium chloride Page 2 of 5

3 Precautions: The handling precautions for this product are based on the characteristics of the neat product unless otherwise specified. Store in a cool dry place. Rubber gloves and safety goggles are required. Bodyprotective clothing and safety shoes are required. Eye-wash fountains in the work place are strongly recommended. 8. Exposure Controls / Personal Protection Occupational Exposure Limits: None Engineering Control Measures: Provide adequate ventilation in the work place. Personal Protection Respiratory: Use respiratory protection where misting may occur. Personal Protection Hand: Rubber gloves Personal Protection Eye: Safety goggles are required. Personal Protection Skin: Body-protective clothing and safety shoes are recommended. Where splashing can occur, a protective face-shield is required. Other Protection: Eye wash fountain in the workplace is strongly recommended. 9. Physical and Chemical Properties Appearance: Pale yellow liquid Odour: Slight PH: (1% soln.) Boiling Point: >100 C Melting Point: Flash Point: Closed Cup 100 C (Tagliabue C.C.) Flammability: NFPA Rating: 1 Autoflammability: Explosive properties: Oxidising properties: Vapour Pressure: Density: g/ml Solubility in Water: Completely soluble in water Viscosity Dynamic: 250 to 1000mPa s ( 250 to 100 cp) Neurotoxicity 10. Stability and Reactivity Stability Conditions to avoid: Incompatible materials: The product is stable. Avoid release to the environment Anionic Polymers Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced 11. Toxicological Information Issue:06/06/20134 Product Name: Poly quarternary ammonium chloride Page 3 of 5

4 Acute Toxicity: Skin and Eye Contact: Chronic Toxicity Carcinogenicity: Mutagenicity: Reproduction Hazard: Oral LD50 :1 865 mg/kg Dermal LD50 : > mg/kg Irritating to eyes The effects of chronic exposure have not been evaluated Not listed in any of OSHA standard, section sources as carcinogenic., Inc. 12. Ecological Information Aquatic Toxicity Fish: Aquatic Toxicity: Aquatic Toxicity algae Avian Toxicity: Biodegradability: Bio-Accumulation: Mobility: German wgk: 96 Hr. LC50 : Bluegill sunfish = 0.28 mg/l ; 96 Hr. LC50: Rainbow trout = mg/l 1 = low hazard to waters 13. Disposal Considerations Disposal Method: Disposal of Packaging: Dispose in accordance with local/national Regulations governing the disposal of waste materials. Dispose of drums through a registered drum re-conditioning company. Dispose of packaging other than drums, e.g. Flexibags, through a registered waste disposal company in an approved landfill. 14. Transport Information UN No.: Substance Identity No.: Dot Class ADR/RID Class: ADR/RID Item Number: ADR/RID Hazard Identity Number: IMDG Shipping Name: IMDG Page: IMDG Class: IMDG Packaging Group: IMDG Marine Pollutant: EMS No.: MFAG Table No. : IATA Shipping Name: IATA Class: IATA Subsidiary risk(s): ADNR Class UK Description: UK Emergency Action Class: UK Classification: Tremcard No.: III None BSN1055 Issue:06/06/20134 Product Name: Poly quarternary ammonium chloride Page 4 of 5

5 15. Regulatory Information EEC Hazard Classification: Risk Phrases: Safety Phrases: National Legislation: Not Listed R36 S26 None known FDA Approvals: Other Information There is no other information available DISCLAIMER Zodiac Pool Care SA (Pty) Limited believes that this information is correct at date of publication but does not warrant the accuracy thereof. The use of the product designated herein will be at the sole risk of the user and Zodiac Pool Care SA (Pty) Limited will not accept any liability for any loss or damage, including consequential loss, howsoever caused by or arising from the use of this information of the use, application, adaption or processing of the product described herein or its use in combination with any other product, material or in any process. Date of General Update- 20 June 2014 Issue:06/06/20134 Product Name: Poly quarternary ammonium chloride Page 5 of 5

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