SAFETY DATA SHEET Revised edition no : 0 SDS/MSDS Date : 4 / 12 / 2012 : SODIUM HYDROXIDE 2MOL/L(2N) : 5901F. : Industrial. For professional use only.

Transcription

1 Page : 1 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name Product code : : 1.2. Relevant identified uses of the substance or mixture and uses advised against Use : Industrial. For professional use only Details of the supplier of the safety data sheet Company identification : 107 Wode House Road, Jehangir Villa, Colaba Mumbai INDIA 1.4. Emergency telephone number Phone nr : (9:00am - 6:00 pm) [ Office hours ] 2. Hazards identification -DSD 2.1. Classification of the substance or mixture Classification EC 67/548 or EC 1999/45 Classification : C; R34 Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP) Health hazards : Skin corrosion - Category 1A - Danger (CLP : Skin Corr. 1A) H Label elements Labelling EC 67/548 or EC 1999/45 Symbol(s) Symbol(s) êc : C : Corrosive

2 Page : 2 2. Hazards identification -DSD (continued) R Phrase(s) S Phrase(s) Contains : R34 : Causes burns. : S24 : Avoid contact with skin. S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 : After contact with skin, wash immediately with S35 : This material and its container must be disposed of in a safe way. S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection. S45 : In case of accident or if you feel unwell, seek medical advice immediately ( show the label when possible). S59 : Refer to manufacturer/supplier for information on recovery/recycling. : Water - Hidróxido de sodio Labelling Regulation EC 1272/2008 (CLP) Hazard pictograms Signal words Hazard statements Precautionary statements Prevention Response Storage Disposal considerations Contains M» : Danger : H314 : Causes severe skin burns and eye damage. : P280: Wear protective gloves, protective clothing, eye protection, face protection. P260: Do not breathe dust, fume, gas, mist, vapours, spray. P264: Wash thoroughly after handling. : P301+P330+P331: IF SWALLOWED : Rinse mouth. Do NOT induce vomiting. P305+P351+P338: IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340: IF INHALED : Remove to fresh air and keep at rest in a position comfortable for breathing. P303+P361+P353: IF ON SKIN (or hair) : Remove immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. : P405: Store locked up. : P501: Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. : Water - Hidróxido de sodio 2.3. Other hazards Other hazards : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH.

3 Page : 3 3. Composition/information on ingredients Substance / Preparation Hazardous component(s) : Preparation. : This product is hazardous. Substance name Contents CAS No EC No Annex No REACH Ref. Classification Hidróxido de sodio : > 5 < 10 % C; R Skin Corr. 1A _ H314 Water : > 75 < 99 % Not classified (DSD/DPD) Not classified (GHS) 4. First aid measures 4.1. Description of first aid measures Inhalation Skin contact Eye contact Ingestion : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor. : Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing. Immediately call a POISON CENTER or doctor. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. : Immediately call a POISON CENTER or doctor. Rinse mouth. Do NOT induce vomiting Most important symptoms and effects, both acute and delayed Symptoms relating to use : Causes severe skin burns and eye damage Indication of any immediate medical attention and special treatment needed General information : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). 5. Fire-fighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Surrounding fires : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. : Use water spray or fog for cooling exposed containers Special hazards arising from the substance or mixture Hazardous combustion products : Under fire conditions, hazardous fumes will be present. Thermal decomposition generates : Corrosive vapours Advice for fire-fighters

4 Page : 4 5. Fire-fighting measures (continued) Protection against fire Special procedures : Do not enter fire area without proper protective equipment, including respiratory protection. : Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For emergency responders For non-emergency personnel : Equip cleanup crew with proper protection. Ventilate area. : Evacuate unnecessary personnel Environmental precautions Environmental precautions : Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters Methods and material for containment and cleaning up Clean up methods : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Reference to other sections See section 8. Exposure controls/personal protection 7. Handling and storage 7.1. Precautions for safe handling Handling Technical protective measures : Do not breathe dust, fume, gas, mist, vapours, spray. Avoid contact during pregnancy or while nursing. Wash thoroughly after handling. : Provide good ventilation in process area to prevent formation of vapour Conditions for safe storage, including any incompatibilities Storage Storage regulation Storage - away from : Keep only in the original container in a cool, well ventilated place. Keep container closed when not in use. : Comply with applicable regulations. : Strong bases. Strong acids. Sources of ignition. Direct sunlight Specific end use(s)

5 Page : 5 7. Handling and storage (continued) Specific end use(s) : None. 8. Exposure controls/personal protection 8.1. Exposure controls Personal protection Personal protection Respiratory protection Hand protection Skin protection Eye protection Others 8= ± : Avoid all unnecessary exposure. : Wear approved mask. : Wear protective gloves. : Wear suitable protective clothing. : Chemical goggles or face shield. : When using, do not eat, drink or smoke Control parameters Occupational Exposure Limits 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state at 20 C Colour Odour Odour threshold ph value Melting point [ C] Decomposition point [ C] Critical temperature [ C] Auto-ignition temperature [ C] Flammability (solid, gas) Flash point [ C] Boiling point [ C] Initial boiling point [ C] Final boiling point [ C] : Liquid. : Colorless : Characteristic.

6 Page : 6 9. Physical and chemical properties (continued) Evaporation rate Vapour pressure [20 C] Vapour pressure mm/hg Vapour density Density [g/cm3] : 1,09 Relative density, gas (air=1) Relative density, liquid (water=1) Solubility in water [% weight] : Soluble in water Solubility in water Log Pow octanol / water at 20 C Solubility : 13.8 Viscosity at 40 C [mm2/s] 9.2. Other information Explosive properties Explosion limits - upper [%] Explosion limits - lower [%] Oxidising properties 10. Stability and reactivity Reactivity Reactivity : Not established Chemical stability Chemical stability : Stable under recommended storage conditions Possibility of hazardous reactions Hazardous reactions : Not established Conditions to avoid Conditions to avoid : Direct sunlight. Extremely high or low temperatures Incompatible materials Materials to avoid : Strong acids. Strong bases Hazardous decomposition products

7 Page : Stability and reactivity (continued) Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapours. 11. Toxicological information Information on toxicological effects Toxicity information Acute toxicity Inhalation Dermal Ingestion Corrosion Irritation Sensitization Mutagenicity Carcinogenicity Toxic for reproduction STOT-single exposure STOT-repeated exposure Aspiration hazard : The product has been not fully tested. The calculated risk has been done under the requirements of the EU regulations. : Causes severe skin burns and eye damage. 12. Ecological information Toxicity Toxicity information : The product has been not fully tested. The calculated risk has been done under the requirements of the EU regulations Persistence - degradability Persistence - degradability : Biodegradable Bioaccumulative potential Bioaccumulative potential : Not established Mobility in soil Mobility in soil : Not established.

8 Page : Ecological information (continued) Results of PBT and vpvb assessment Results of PBT and vpvb assessment : The substance does not fulfil the criteria to be identified as PBT substance or vpvb substance according to Annex XIII of Regulation REACH Other adverse effects Environmental precautions : Avoid release to the environment. 13. Disposal considerations Waste treatment methods General : Avoid release to the environment. Dispose in a safe manner in accordance with local/national regulations. Dispose of this material and its container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 14. Transport information Land transport (ADR-RID) Proper shipping name : SODIUM HYDROXIDE SOLUTION UN N : 1824 H.I. nr :80 ADR - Class :8 Labelling - Transport : 8 : Corrosive substance. { ADR - Classification code :C5 ADR - Group :II ADR - Packing instructions : P001 ADR - Limited Quantity :1 L ADR - Tunnel code : E : Passage forbidden through tunnels of category E.»

9 Page : Transport information (continued) Sea transport (IMDG) [English only] Proper shipping name : SODIUM HYDROXIDE SOLUTION UN N : 1824 IMO-IMDG - Class or division : 8 : Corrosive substance. IMO-IMDG - Packing group :II IMO- IMDG - Packing instructions : P001 IMO-IMDG - Limited quantities :1 L IMO-IMDG - Marine pollution :No EMS-Nr : F-A S-B Air transport (ICAO-IATA) [English only] Proper shipping name : SODIUM HYDROXIDE SOLUTION UN N : 1824 IATA - Class or division : 8 : Corrosive substance. IATA - Packing group :II IATA - Passenger and Cargo Aircraft : ALLOWED - Passenger and Cargo - Packing : 851 instruction - Passenger and Cargo - Maximum :1 L Quantity/Packing IATA - Cargo only : ALLOWED - Cargo only - Packing instruction : Cargo only - Maximum Quantity/ : 30 L Packing IATA - Limited Quantites ERG-Nr :8L : 0.5 L 15. Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Safety, health and environmental : Ensure all national/local regulations are observed. regulations/legislation specific for the substance or mixture REACH Restrictions - Annex XVII : The components of this product are not subject to restrictions. REACH Authorisation - Annex XIV : The components of this product are not subject to authorization Chemical Safety Assessment

10 Page : Regulatory information (continued) Chemical Safety Assessment : It has not been carried out. 16. Other information Revision : Revision - See : * Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic. vpvb: very persistent and very bioaccumulative Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 List of relevant R phrases (heading 3) : R35 : Causes severe burns. List of full text of H-statements in : H314 : Causes severe skin burns and eye damage. section 3 Further information : None. In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation (CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. End of document