SAFETY DATA SHEET. 1. Product and Company Identification. 2. Hazards Identification

Transcription

1 SAFETY DATA SHEET 1. Product and Company Identification Product identifier Other means of identification Recommended use Recommended restrictions Manufacturer information Supplier Hands Fresh Alcohol-Free Foam Sanitizer - Antiseptic cleaner ne known. NWL Netherlands Services BV Newell Rubbermaid Amperestraat HB Hillegom, Netherlands Phone + 31 () Kruger Products L.P Minnesota Court Mississauga, Ontario L5N 5R5 Canada Emergency Phone: Fax: Phone: Hazards Identification Physical hazards Health hazards Environmental hazards WHMIS 215 defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal WHMIS 215: Health Hazard(s) not otherwise classified (HHNOC) WHMIS 215: Physical Hazard(s) not otherwise classified (PHNOC) Hazard(s) not otherwise classified (HNOC) Supplemental information t classified. t classified. t classified. t classified ne. ne. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. ne known ne known ne known. CANADA: This product is not subject to the Hazardous Products Act (HPA) Part II (Hazardous Products) as per paragraph 12(j); Schedule 1 (n-application of Part II). This restriction states that Part II does not apply in respect of the sale or importation of anything listed in Schedule 1 which includes any pest control product as defined in subsection 2(1) of the Pest Control Products Act, any explosive as defined in section 2 of the Explosives Act, any cosmetic, device, drug or food, as defined in section 2 of the Food and Drugs Act, any consumer product as defined in section 2 of the Canada Consumer Product Safety Act and any wood or product made of wood. US: This is a registered EPA product. The product labeling is in compliance with EPA regulations and guidelines. 3. Composition/Information on Ingredients Mixture Chemical name Benzalkonium Chloride Common name and synonyms CAS number % All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. #2522 Page: 1 of 6

2 4. First Aid Measures Inhalation Skin contact Eye contact Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information t a normal route of harmful exposure. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Product intended to be used on skin. In case of skin irritation, discontinue use of product. When using this product avoid contact with eyes. In case of eye contact, flush with water. Stop use and ask a doctor, if irritation of redness persist or if condition persist. Do not ingest. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Get medical attention. Treat patient symptomatically. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Keep out of reach of children. Avoid contact with eyes. 5. Fire Fighting Measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Hazardous combustion products Dry chemical. Carbon dioxide. Water spray. Alcohol foam. Sand. During fire, gases hazardous to health may be formed. Firefighters should wear full protective clothing including self contained breathing apparatus. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. unusual fire or explosion hazards noted. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Hydrogen chloride. 6. Accidental Release Measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. For personal protection, see section 8 of the SDS. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Do not discharge into lakes, streams, ponds or public waters. 7. Handling and Storage Precautions for safe handling Conditions for safe storage, including any incompatibilities For external use only. Do not ingest. DO NOT get in eyes. Use according to package label instructions. Use good industrial hygiene practices in handling this material. Store in original tightly closed container. Keep out of reach of children. 8. Exposure Controls/Personal Protection Occupational exposure limits Biological limit values Exposure guidelines Appropriate engineering controls exposure limits noted for ingredient(s). biological exposure limits noted for the ingredient(s). This material does not have established exposure limits. General ventilation normally adequate. #2522 Page: 2 of 6

3 Individual protection measures, such as personal protective equipment Eye/face protection t normally required when used as directed. Skin protection Hand protection t applicable. In case of skin irritation, discontinue use of product. Other As required by employer code. Respiratory protection t normally required. Thermal hazards t applicable. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do not eat or drink. Appearance Physical state Form Color Odor Odor threshold 9. Physical and Chemical Properties Clear, Transparent Liquid. Liquid. Colourless to slightly yellow Fragrant ph 4-6 Melting point/freezing point Initial boiling point and boiling range Pour point Specific gravity Partition coefficient (n-octanol/water) Flash point Evaporation rate Flammability (solid, gas) t applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Auto-ignition temperature Decomposition temperature Viscosity 1-12 seconds (DIN 53211) Other information Explosive properties Oxidizing properties t explosive. t oxidizing. 1. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products This product may react with strong oxidizing agents. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Caustics. Acids. Oxidizers. May include and are not limited to: Hydrogen chloride. Oxides of carbon. Oxides of nitrogen. #2522 Page: 3 of 6

4 Routes of exposure Information on likely routes of exposure Ingestion Inhalation Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Skin corrosion/irritation Exposure minutes Erythema value Oedema value Serious eye damage/eye irritation Corneal opacity value Iris lesion value Conjunctival reddening value Conjunctival oedema value Recover days Respiratory or skin sensitization Respiratory sensitization Skin sensitization Mutagenicity Carcinogenicity 11. Toxicological Information Eye, Skin contact, Inhalation, Ingestion. Expected to be a low ingestion hazard. May cause stomach distress, nausea or vomiting. adverse effects due to inhalation are expected. adverse effects due to skin contact are expected. Prolonged skin contact may cause temporary irritation. t a respiratory sensitizer. This product is not expected to cause skin sensitization. See below. US. OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity Teratogenicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects t classified. t classified. t an aspiration hazard. 12. Ecological Information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Mobility in general Other adverse effects data is available on the degradability of this product. data available. other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal Considerations Disposal instructions Local disposal regulations Hazardous waste code Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. #2522 Page: 4 of 6

5 Waste from residues / unused products Contaminated packaging Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Transport of Dangerous Goods (TDG) Proof of Classification U.S. Department of Transportation (DOT) t regulated as dangerous goods. Transportation of Dangerous Goods (TDG - Canada) t regulated as dangerous goods. 14. Transport Information In accordance with Part (SOR/ ) of the Transportation of Dangerous Goods Regulations, we certify that the classification of this product is correct as of the SDS date of issue. 15. Regulatory Information Canadian federal regulations This product is not subject to the Hazardous Products Act (HPA) Part II (Hazardous Products) as per paragraph 12(j); Schedule 1 (n-application of Part II). This restriction states that Part II does not apply in respect of the sale or importation of anything listed in Schedule 1 which includes any pest control product as defined in subsection 2(1) of the Pest Control Products Act, any explosive as defined in section 2 of the Explosives Act, any cosmetic, device, drug or food, as defined in section 2 of the Food and Drugs Act, any consumer product as defined in section 2 of the Canada Consumer Product Safety Act and any wood or product made of wood. Export Control List (CEPA 1999, Schedule 3) Greenhouse Gases Precursor Control Regulations WHMIS 215 Exemptions US federal regulations Exempt - Registered product - (DIN ). WARNINGS: FOR EXTERNAL USE ONLY. WHEN USING THIS PRODUCT AVOID CONTACT WITH EYES. In case of eye contact, flush with water. Stop use and ask a doctor, if irritation of redness persist or if condition persist. Do not ingest. KEEP OUT OF REACH OF CHILDREN. If swallowed, DO NOT induce vomiting. Get medical attention. t applicable TSCA Section 12(b) Export tification (4 CFR 77, Subpt. D) CERCLA Hazardous Substance List (4 CFR 32.4) US. OSHA Specifically Regulated Substances (29 CFR ) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 32 Extremely hazardous substance SARA 311/312 Hazardous chemical SARA 313 (TRI reporting) Other federal regulations Immediate Hazard - Delayed Hazard - Fire Hazard - Pressure Hazard - Reactivity Hazard - Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) #2522 Page: 5 of 6

6 US state regulations US - Texas Effects Screening Levels: Listed substance Benzalkonium Chloride (CAS ) US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act Listed. US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Inventory status Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Canada n-domestic Substances List (NDSL) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16. Other Information Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 1 X 1 Disclaimer Issue date Version # 1 Effective date Prepared by Other information Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. The information in the sheet was written based on the best knowledge and experience currently available. 19-September September-216 Dell Tech Laboratories, Ltd. Phone: (519) For an updated SDS, please contact the supplier/manufacturer listed on the first page of the document. #2522 Page: 6 of 6