Roman Pit Lime, from Naples

Transcription

1 Revised edition: Version: 3 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Roman Pit Lime, from Naples Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Industry mortar, rendering, lime paints Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) H315 Cat.: 2 H318 Cat.: 1 H335 Cat.: 3 Classification according to Directive No. 67/548/EC or No. 1999/45/EC Irritating (Xi) R37 Irritating (Xi) R38 Irritating (Xi) R41 Skin irritation, hazard category 2 Serious eye damage, hazard category 1 Specific Target Organ Toxicity (single exposure), hazard category 3 Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Irritating to respiratory system. Irritating to skin. Risk of serious damage to eyes Safety Phrases: Possible Environmental Effects: Label Elements See Section 12. Classification according to Regulation 2

2 (EC) No. 1272/2008 (CLP/GHS) Page 2 Hazard designation: GHS05-2 GHS07 Signal word: Hazard designation: Safety designation: H315 H318 H335 P102 P261 P280 P301+P310 P302+P352 P305+P351+P338 P501 Danger Causes skin irritation. Causes serious eye damage. May cause respiratory irritation. Keep out of reach of children. Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. Wear protective gloves/ clothing/ eye/ face protection. If swallowed: Immediately call a poison center or physician. If on skin: Wash with soap and water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses and continue rinsing. Dispose of contents/ container according to regional, national and international regulations Hazardous components for labelling: Other Hazards Composition/Information on Ingredients Substance Mixture Chemical Characterization: Pit lime is preparation of approximately 50 % calcium hydroxide Ca (OH)2 in water. Information on Components / Hazardous Ingredients: Calcium hydroxide (Xi; R ; H ); REACH Reg. No CAS-Nr: EINECS-Nr: EC-Nr: Additional information: First Aid Measures Description of the First Aid Measures General information: Seek medical attention in case of complaints. 3

3 After inhalation: Page 3 Supply fresh air. Consult physician if symptoms persist. After skin contact: After eye contact: Remove contaminated clothing immediately. Wash off immediately with soap and plenty of water and rinse thoroughly. Rinse open eye for several minutes under running water. Consult a physician immediately After ingestion: Most important Symptoms and Effects, both Acute and Delayed Do not induce vomiting. Consult physician immediately. Drink plenty of water. Symptoms: Skin contact: can cause skin irritation. Inhalation: can cause irritation of the respiratory tract. Eye contact: causes serious eye damage. Adverse systemic effects are not expected since the ph effect is the major health hazard Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Product itself does not burn. Foam, CO2, dry extinguishing powder Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known Special hazards: Advice for Firefighters Protective equipment: Product is not flammable. The substance is not flammable and non-combustible, it inhibits the spread of flames. Wear suitable protective clothing. Wear self-contained respiratory protective device. Further information: Not combustible. 4

4 6. Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Page Personal precautions: Environmental Precautions Ensure adequate ventilation. Wear protective clothing. Avoid contact with skin, eyes and clothing Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent spillage of large quantities into drains and surface waters. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Protective clothing, see Section 8. See Section 13 for information on disposal. Wear adequate protective clothing (see para. 8). It is recommended to provide a portable eye rinsing bottle Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Avoid contact with eyes and skin. Do not eat or drink during work. Do not smoke. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Keep container tightly closed Keep product away from children. Store the product in the original container. Unsuitable container material: aluminium. Do not store together with: foodstuffs, beverages and feed. Do not store together with acids and nitro compounds. Storage class (VCI): Further Information: Specific End Use(s) Further information: 5

5 8. Exposure Controls/Personal Protection Parameters to be Controlled Page 5 Parameters to be controlled (DE): Parameters to be controlled: Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): TLV: 1 mg/m3 (inhalable fraction) TLV (A): 2 mg/m3 (inhalable fraction) TLV (CH): 5 mg/m3 (inhalable fraction) 4 mg/m3 (worker/consumer, inhalation, short-term exposition - local effects) 1 mg/m3 (worker/consumer, inhalation, long-term exposition - local effects) Fresh water: 0.49 mg/l Sea water: 0.32 mg/l Sewage treatment system (STP): 3 mg/l Soil: 1080 mg/kg (dw) Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Required in case of insufficient ventilation. Protective gloves (EN 374) Nitrile rubber Safety glasses (EN 166) It is recommended to provide a portable eye rinsing bottle. Protective suit with long sleeves Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent contamination of open water ways and sewage system. Avoid contamination of ground water. 6

6 Form: paste Page 6 Color: Odor: Odor threshold: ph-value: white odorless No information available (20 C) Melting temperature: 0 C Boiling temperature: 100 C Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: not flammable no information available no information available 2.3 kpa (20 C) Vapor density: 0.62 Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: 1.3 g/ml 65 g/l mg/l (EU A.6) No relative auto-ignition temperature below 400 C (EU A.16 Method) When heated above 580 C, calcium hydroxide decomposes to calcium oxide (CaO) and water (H20). not determined Product is not explosive. not oxidizing Bulk density: 7

7 9. 2. Further Information Page Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects No further information. Calcium hydroxide dissociates into calcium cations and hydroxyl anions in aqueous media. Stable if used according to specifications. Exothermic reaction with acids. No further information available. When heated above 580 C, calcium hydroxide decomposes to calcium oxide (CaO) and water (H20). Reacts with acids: heat development. None known. Calcium hydroxide is not toxic. Calcium hydroxide: LD50: > 2000 mg/kg bw (rat; OECD 425) Calcium hydroxide: LD50: > 2500 mg/kg bw (rabbit; OECD 402) No information available. Irritant effect on skin: 8

8 Irritating (rabbit) Page Irritant effect on eyes: Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Irritating effect (rabbit). No information available. No information available No sensitizing effects known. Not mutagenic (OECD 471 Bacterial Reverse Mutation Test) In vitro Mammalian Cell Gene Mutation Test (OECD 476): negative Not considered to be toxic to reproduction. No cancerogenic effect (rat). No information available. Single exposure: From the data from studies in humans it can be concluded that Ca(OH)2 irritates the respiratory tract. As recommended in the SCOEL (Anonymus, 2008), calcium dihydroxide is classified as irritating to the respiratory tract (R37, Irritating to the resp. system; STOT SE 3 (H335). By analogy, these results can be applied for the product itself. Repeated exposure: no toxicological effects. Aspiration hazard: Calcium hyroxide: LC50: 457 mg/l (96h; seawater fish) Calcium hyroxide: LC50: 50.6 mg/l (96h; freshwater fish) Calcium hydroxide: LC50: 158 mg/l (96h; Daphnia magna) Calcium hydroxide: EC50: 49.1 mg/l (48h; Daphnia magna) Calcium hydroxide: NOEC: 32 mg/l (14d) Bacteria toxicity: At high concentrations, the product causes an increse of the ph value. This effect is used for the purification of sewage sludge. Toxicity to soil dwelling organisms: Calcium hydroxide: EC10/LC50/NOEC: 2000 mg/kg soil dw (macro-organisms) Calcium hydroxide: EC10/LC50/NOEC: mg/kg soil dw 9

9 (micro-organisms) Page Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): Uncleaned packaging: Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: Calcium hydroxide: EC50: mg/l (72h, freshwater algae) Calcium hydroxide: NOEC: 48 mg/l (72h, freshwater algae) Inorganic substance. Biological degradability is not affected. Bioaccumulation is not to be expected. Weak solubility and mobility. Inorganic substance: does not comply with the criteria for the classification as PBT or vpvb. 1, slightly hazardous Do not allow undiluted product or large quantities of it to reach ground water, waterways or sewage system. Harmful to aquatic organisms caused by a ph shift. Acute ph Effect. Although this product can be used to neutralize acidified water, water organisms can be damaged when 1 g/l is exceeded. The ph value > 12 is rapidly reduced due to dilution and carbonization. Dispose of product residues according to the waste disposal guidelines 2008/98/EC as well as according to official national and local regulations. Dispose of according to official local regulations. No hazardous goods according to ADR (land transportation). IMDG/IATA: 10

10 No hazardous goods according to IMDG Transport Hazard Classes Page 10 ADR Class: Hazard no.: Classification code: Tunnel restriction code: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User none known Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 1, slightly hazardous for water (German Regulation) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information This product contains substances for which a Chemical Safety Assessment has been carried out. Seveso Directive: not regulated / Regulation (EC) 850/ Persistent organic pollutants and amending Directive 79/117/EEC: not regulated / Regulation (EC) 2037/ Substances that Deplete next the page: Ozone 11

11 16. Other Information Layer: not regulated / Page 11 This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.