SAFETY DATA SHEET. 1. Product and Company Identification. 2. Hazards Identification

Transcription

1 SAFETY DATA SHEET 1. Product and Company Identification Product identifier Algae Break 9 Other means of identification Not available Recommended use Pool Water Treatment Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Natural Chemistry L.P. Address 4 Richards Ave. Norwalk, CT 6854 United States Telephone Phone: (8) info@naturalchemistry.com Emergency phone number Emergency Phone: CHEMTREC (8) Hazards Identification Physical hazards Health hazards Environmental hazards OSHA defined hazards Label elements Skin corrosion/irritation Serious eye damage/eye irritation Category 2 Category 2B Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) Supplemental information Warning Causes skin irritation. Causes eye irritation. Wash thoroughly after handling. Wear protective gloves. If on skin: Wash with plenty of water/. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see on this label). Take off contaminated clothing and wash before reuse. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. Not applicable. 3. Composition/Information on Ingredients Mixtures Chemical name Common name and synonyms CAS number % 2,2',2''-Nitrilotrisethanol, coppersalt First Aid Measures Inhalation Skin contact Eye contact If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Take off contaminated clothing and wash before reuse. Wash with plenty of soap and water. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. #21568 Page: 1 of 6

2 Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions Specific methods General fire hazards Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Rinse mouth. If ingestion of a large amount does occur, call a poison control center immediately. Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. May cause redness and pain. Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire Fighting Measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. No unusual fire or explosion hazards noted. 6. Accidental Release Measures Keep unnecessary personnel away. Keep out of low areas. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. This product is miscible in water. Stop the flow of material, if this is without risk. Large Spills: Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Avoid discharge into drains, water courses or onto the ground. 7. Handling and Storage Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Use care in handling/storage. Keep container tightly closed. Store away from incompatible materials (see Section 1 of the SDS). 8. Exposure Controls/Personal Protection Occupational exposure limits US. NIOSH: Pocket Guide to Chemical Hazards Components Type 2,2',2''-Nitrilotrisethanol, coppersalt (CAS Biological limit values Appropriate engineering controls Value Form TWA 1 mg/m3 Dust and mist. No biological exposure limits noted for the ingredient(s). Good general ventilation (typically 1 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). #21568 Page: 2 of 6

3 Skin protection Hand protection Other Respiratory protection Thermal hazards General hygiene considerations Wear appropriate chemical resistant gloves. Wear appropriate chemical resistant clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Not applicable. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Appearance Physical state Form Color Odor Odor threshold Clear Liquid. Liquid. Blue Slight ph Melting point/freezing point Initial boiling point and boiling range Pour point 9. Physical and Chemical Properties F (-5.6 C) 212 F (1 C) Specific gravity Partition coefficient (n-octanol/water) Flash point Evaporation rate Flammability (solid, gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Auto-ignition temperature Decomposition temperature Viscosity 17 mmhg Miscible 1. Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products None known. No dangerous reaction known under conditions of normal use. Material is stable under normal conditions. Contact with incompatible materials. Acids. Strong oxidizing agents. Oxides of nitrogen. 11. Toxicological Information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation No adverse effects due to inhalation are expected. #21568 Page: 3 of 6

4 Skin contact Eye contact Symptoms related to the physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Causes skin irritation. Causes eye irritation. Components Species Acute Dermal LD5 Inhalation LC5 Oral LD5 Skin corrosion/irritation Exposure minutes Erythema value Oedema value Serious eye damage/eye irritation Corneal opacity value Iris lesion value Conjunctival reddening value Exposed individuals may experience eye tearing, redness, and discomfort. Skin irritation. May cause redness and pain. Rabbit Not available Rat Causes skin irritation. Causes eye irritation. Conjunctival oedema value Recover days Respiratory or skin sensitization Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity This product is not expected to cause skin sensitization. Test Results > 2 mg/kg 45 mg/kg No data available to indicate product or any components present at greater than.1% are mutagenic or genotoxic. US. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Chronic effects Further information This product is not expected to cause reproductive or developmental effects. None known. 12. Ecological Information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil Mobility in general Other adverse effects The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. No data is available on the degradability of this product. No data available. No data available. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. #21568 Page: 4 of 6

5 13. Disposal Considerations Disposal instructions Local disposal regulations Hazardous waste code Waste from residues / unused products Contaminated packaging Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Dispose in accordance with all applicable regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport Information U.S. Department of Transportation (DOT) Not regulated as dangerous goods. US federal regulations 15. Regulatory Information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export Notification (4 CFR 77, Subpt. D) CERCLA Hazardous Substance List (4 CFR 32.4) US. OSHA Specifically Regulated Substances (29 CFR ) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories SARA 32 Extremely hazardous substance SARA 311/312 Hazardous chemical Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No No SARA 313 (TRI reporting) Chemical name CAS number % by wt. 2,2',2''-Nitrilotrisethanol, coppersalt Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) Safe Drinking Water Act (SDWA) Food and Drug Administration (FDA) US state regulations California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. US - California Hazardous Substances (Director's): Listed substance US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US - Illinois Chemical Safety Act: Listed substance US - Louisiana Spill Reporting List: Reportable quantity (total mass into atmosphere) 1 LBS #21568 Page: 5 of 6

6 US - Louisiana Spill Reporting: Listed substance US - Michigan Critical Materials Register: Parameter number US - New Jersey RTK - Substances: Listed substance US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes *A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s) 16. Other Information Severe Serious Moderate Slight Minimal LEGEND HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 1 X 1 Disclaimer Issue date Further information Other information The information in the sheet was written based on the best knowledge and experience currently available. Information contained herein was obtained from sources considered technically accurate and reliable. While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated. Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments. No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document. 13-May-214 For an updated SDS, please contact the supplier/manufacturer listed on the first page of the document. This Safety Data Sheet was prepared to comply with the current OSHA Hazard Communication Standard (HCS) adoption of the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). Prepared by Dell Tech Laboratories, Ltd. Phone: (519) #21568 Page: 6 of 6