: CW106-SR Passivation

Transcription

1 Date of issue: 05/18/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : : CW106-SR Passivation 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Dober Chemical Corp 333 W. 195th Street Glenwood, IL US T F regulatory@dobergroup.com Emergency telephone number : Water Treatment Dispersant Emergency number : / ChemTel SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Irrit. 2 H315 Aquatic Acute 3 H402 Aquatic Chronic 3 H412 Full text of H-phrases: see section Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H315 - Causes skin irritation H402 - Harmful to aquatic life H412 - Harmful to aquatic life with long lasting effects : P264 - Wash hands, forearms and face thoroughly after handling P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - If on skin: Wash with plenty of soap and water P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse P501 - Dispose in a safe manner in accordance with local/national regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 05/18/2015 EN (English) Page 1

2 Name Product identifier % GHS-US classification Sulfamic Acid (CAS No) Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Aquatic Acute 3, H402 Aquatic Chronic 3, H412 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : Causes skin irritation Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Wash hands, forearms and face thoroughly after handling. 05/18/2015 EN (English) 2/7

3 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep only in the original container in a cool, well-ventilated place. Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters CW106-SR Passivation ACGIH OSHA ACGIH OSHA 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection Other information : Wear protective gloves/protective clothing/eye protection/face protection protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : Off- White Odour Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility : Water: 100 % Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 05/18/2015 EN (English) 3/7

4 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Not established Possibility of hazardous reactions Not established Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong bases Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms Symptoms/injuries after skin contact SECTION 12: Ecological information Toxicity Ecology - water LC50 fishes mg/kg mg/kg bodyweight : Causes skin irritation. : Based on available data, the classification criteria are not met. : Causes skin irritation. : Harmful to aquatic life. Harmful to aquatic life with long lasting effects mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) Persistence and degradability CW106-SR Passivation Persistence and degradability May cause long-term adverse effects in the environment Bioaccumulative potential CW106-SR Passivation Bioaccumulative potential Not established. 05/18/2015 EN (English) 4/7

5 12.4. Mobility in soil Other adverse effects Effect on the global warming Other information : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information : Dispose in a safe manner in accordance with local/national regulations. Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. UN-No.(DOT) : UN2967 UN-No. (IMDG) : 2967 UN-No.(IATA) : UN proper shipping name Proper Shipping Name (DOT) : Sulfamic acid Proper Shipping Name (IMDG) Proper Shipping Name (IATA) : SULPHAMIC ACID : SULPHAMIC ACID Transport hazard class(es) Department of Transportation (DOT) Hazard Classes Hazard labels (DOT) : 8 : 8 - Corrosive : Transport hazard class(es) (IMDG) : 8 Danger labels (IMDG) : 8 : Transport hazard class(es) (IATA) : 8 Hazard labels (IATA) : 8 : Packing group Packing group (DOT) : III 05/18/2015 EN (English) 5/7

6 Packing group (IMDG) Packing group (IATA) : III : III Environmental hazards Marine pollutant(dot) Marine pollutant(imdg) Marine pollutant(iata) : No : No : No SECTION 15: Regulatory information US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR (a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part International regulations CANADA Listed on the Canadian DSL (Domestic Sustances List) WHMIS Classification Class E - Corrosive Material US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer and/or reproductive harm SECTION 16: Other information Other information : None. Full text of H-phrases:: Acute Tox. 4 (Oral) Acute toxicity (oral), Category Aquatic Acute 3 Hazardous to the aquatic environment Acute Hazard, Category Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category Skin Irrit. 2 Skin corrosion/irritation, Category H302 Harmful if swallowed H315 Causes skin irritation H402 Harmful to aquatic life H412 Harmful to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. : NA - Not Applicable 05/18/2015 EN (English) 6/7

7 HMIS III Rating Health Flammability : 0 Physical : 0 Personal Protection Dober SDS US : 3 - Major injury likely unless prompt action is taken and medical treatment is given : B To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 05/18/2015 EN (English) 7/7