AAFA - RSL July Release 3

Transcription

1 AAFA - RSL July Release 3 CAS Number DYES AZO Dyes which, by reductive cleavage of one or more AZO groups, may release one or more of the following aromatic amines Amino azobenzene o -Aminoazotoluene Aminodiphenyl Amino-4-nitrotoluene o -Anisidine Benzidine p -Chloroaniline Chloro-o -toluidine p -Cresidine ,4-Diaminoanisole ,4'-Diamino-diphenylmethane ,3'-Dichlorobenzidine ,3'-Dimethoxybenzidine ,3'-Dimethylbenzidine ,3'-Dimethyl-4,4'-diamino-diphenylmethane ,4'-Methylene-bis-(2-chloroaniline) Naphthylamine ,4'-Oxydianiline ,4'-Thiodianiline ,4-Toluenediamine o-toluidine Not Detected European (below and detection China limits - see test method) Textiles (EU): South Korea Directive 2002/61/EC of EN the European Polyester(EU): Parliament: relating to EN restrictions on the Leather(EU): marketing and use of CEN ISO/TS certain dangerous [detection limit is substances and 30 ppm] preparations Textiles(China) (Azocolourants) GB/T The National Standard [detection limit 20 of the People's ppm] Test Republic of China GB Method for Aminoazobenzene (paab) confirmation 64 LFGB B Page 1 AAFA RSL Final Release 3

2 ,4,5-Trimethylaniline ,4-Xylidine ,6-Xylidine 2 Footnotes: 1. Applicable in the Regulation Only 2. Applicable in the Chinese Regulation only Disperse Dyes Disperse Blue or Disperse Blue Disperse Blue Disperse Blue Disperse Orange Disperse Orange 37/ Disperse Red Disperse Yellow 3 Not Detected (below detection levels - see regulation) Other Dyes Navy Blue 0.1% by mass European Directive 2003/3/EC of the European Parliament: relating to restrictions on the marketing and use of certain dangerous substances and preparations (Azocolourants) Germany 64 LFGB B DIN Disperse Dyes [detection limit is 5 mg/l in extract] Solvent extraction and GC-MS or LC- MS (industry practice - not specified by the regulation) Page 2 AAFA RSL Final Release 3

3 Pentachloroethane Carbon Tetrachloride ,1,1,2-Tetrachloroethane ,1,2,2-Tetrachloroethane SOLVENTS (Aliphatic Chlorohydrocarbons) 0.1% (mass)- TOTAL Germany and Japan Germany - Headspace for Chemikalienverbot components Verordnung (Prohibition of Chemicals Ordinance), section 16 Japan Law for the Control of Household products Containing Harmful Substances Chloroform ,1,2-Trichloroethane ,1-Dichloroethylene ,1,1-Trichloroethane Tetrachloroethylene 3 Footnotes: 3. Applicable in the Japan Regulation Only Page 3 AAFA RSL Final Release 3

4 (2,4,5-trichlorophenoxy) propionic acid, its salts and compounds ,4,5-trichlorophenoxyacetic acid, its salts and compounds Aldrin (both Switzerland and Finland) Chlordane (both Switzerland and Finland) Dichloro-diphenyl-dichloro ethane (DDD) Dichloro-diphenyl-dichloro ethylene (DDE) Not Dectected PESTICIDES Switzerland and Finland (those pesticides without indication are regulated under Switzerland) Switzerland: Art. 9, 11, 35 and 61 Ordinance relating to Environmentally Hazardous Substances(Ordinance on Substances) Finland: Ministry of Environment Government Decree on persistent organic substances (735/2002) U.S. EPA Method 8081A/ 8151A - Japan, South Korea For Dieldrin, PCP, and TeCP, South Korea restrictions apply at different levels for underwear, baby clothing (<24 months) and bedclothes Dichloro-diphenyl-trichloro ethane (DDT) (both Switzerland and Finland) Dieldrin (5) Also Japan, Switzerland, South Korea, and Finland Endrine (both Switzerland and Finland) Heptachlorine (both Switzerland and Finland) Epoxy-heptachlorine Hexachlorobenzene (both Switzerland and Finland) Hexachlorocyclohexane (HCH, all isomers) except gamma-hexachlorocyclohexane (except linande [ ] in medical products) Isodrin Kelevane Kepone (Chlordecone) Lindane Methoxychlor Mirex (Finland only) Perthane Quintozene Strobane Telodrin Toxaphene (both Switzerland and Finland) Page 4 AAFA RSL Final Release 3

5 Halogenated biphenyls, including Polycholorinated and biphenyl (PCB) (both Switzerland and Finland) Various Various Halogenated terphenols, including Polychlorinated terphenyl (PCT) Various Various Halogenated naphthalenes Halogenated diarylalkanes Halogenated diphenyl methanes, including Monomethyl-dibromo-diphenyl methane Monomethyl-dichloro-diphenyl methane Monomethyl-tetrachloro-diphenyl methane Pentachlorophenol (PCP), its salts and compounds (also South Korea) Tetrachlorophenol (TeCP), its salts and compounds (also South Korea) Group 1) 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1,2,3,7,8-Pentachlorodibenzo-p-dioxin Sum of Group 1: 1 µg/kg DIOXINS And FURANS Germany German Chemicalienverbots Verordnung (4) Dioxine US EPA ,3,7,8-Tetrachlorodibenzofuran 2,3,4,7,8-Pentachlorodibenzofuran Group 2) 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 1,2,3,7,8-pentachlorodibenzofuran 1,2,3,4,7,8-Hexachlorodibenzofuran 1,2,3,7,8,9-Hexachlorodibenzofuran 1,2,3,6,7,8-Hexachlorodibenzofuran 2,3,4,6,7,8-Hexachlorodibenzofuran Sum of Group 1 & 2: 5 µg/kg Page 5 AAFA RSL Final Release 3

6 Group 3) 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin Sum of Group 1, 2 & 3: ,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin 100 µg/kg ,2,3,4,6,7,8-Heptachlorodibenzofuran ,2,3,4,7,8,9-Heptachlorodibenzofuran 1 1,2,3,4,6,7,8,9-Octachlorodibenzofuran Group 4) 2,3,7,8-Tetrabromodibenzo-p-dioxin Sum of Group 4: ,2,3,7,8-Pentabromodibenzo-p-dioxin 1 µg/kg ,3,7,8-Tetrabromodibenzofuran ,3,4,7,8-Pentabromodibenzofuran no CAS #'s available Group 5) 1,2,3,4,7,8-Hexabromodibenzo-p-dioxin 1,2,3,7,8,9-Hexabromodibenzo-p-dioxin 1,2,3,6,7,8-Hexabromodibenzo-p-dioxin 1,2,3,7,8-Pentabromodibenzofuran Sum of Group 4 & 5: 5 µg/kg Page 6 AAFA RSL Final Release 3

7 ASBESTOS Actinolite Amosite Anthrophyllite Chrysotile Crocidolite Tremolite Not detected European Council Directive 76/769/EEC and 99/77/EC Microscopic examination; minimum magnification 1-250, polarized light filter attached; ratio of fiber length to diameter is at least 3:1- Page 7 AAFA RSL Final Release 3

8 Sulfur hexafluoride - SF 6 Hydrofluorocarbons (HFCs): HFC-23 - CHF HFC-32 - CH 2 F HFC-41 - CH 3 F FLUORINATED GREENHOUSE GASES May Not be Used European Council Directive 2006/842/EC Headspace for components HFC-43-10mee - C 5 H 2 F HFC C 2 HF HFC C 2 H 2 F HFC-134a - CH 2 FCF HFC-152a - C 2 H 4 F HFC C 2 H 3 F HFC-143a - C 2 H 3 F HFC-227ea - C 3 HF HFC-236cb - CH 2 FCF 2 CF HFC-236ea - CHF 2 CHFCF HFC-236fa - C 3 H 2 F HFC-245ca - C 3 H 3 F HFC-245fa - CHF 2 CH 2 CF HFC-365mfc - CF 3 CH 2 CF 2 CH 3 Page 8 AAFA RSL Final Release 3

9 Perfluorocarbons (PFCs): Perfluoromethane - CF Perfluoroethane - C 2 F Perfluoropropane - C 3 F Perfluorobutane - C 4 F Perfluoropentane - C 5 F Perfluorohexane - C 6 F Perfluorocyclobutane - c-c 4 F 8 Page 9 AAFA RSL Final Release 3

10 Chlorinated paraffins (C10-C13) May not be used FLAME RETARDANTS European Solvent extraction Directive 2002/45/EC of and GC-MS or LCthe European MS (industry Parliament: relating to practice - not restrictions on the specified by the marketing and use of regulation) certain dangerous substances and preparations This chemical may also be present in leather and should not exceed 1% for fat liquoring of leather Polybrominated biphenyls (PBBs) May not be used European Directive 76/769/EEC on restrictions on the marketing and use of certain dangerous substances and preparations. European Directive 83/264/EEC Methanol extraction: analysis by GC- MS or LC-MS South Korea Turkey, Switzerland, Canada, and South Korea South Korea requirement applicable only to bedclothes and nightclothes among underwear Penta-bromodiphenyl ether (pentabde) Octa-bromodiphenyl ether (octabde) May not be used European Directive 2003/11/EC of the European Parliament: relating to restrictions on the marketing and use of certain dangerous substances and preparations (PBDE and OBDE). Solvent extraction and analysis by GC-MS or LC-MS United States, Switzerland, and South Korea South Korea requirement applicable only to bedclothes and nightclothes among underwear. Page 10 AAFA RSL Final Release 3

11 Tris (2,3-dibromopropyl) phosphate (TRIS) Not Detected European Directive 76/769/EEC on restrictions on the marketing and use of certain dangerous substances and preparations. Methanol extraction and analysis by LC-MS or GC-MS Turkey, Switzerland, Japan, and South Korea South Korea requirement applicable only to bedclothes and nightclothes among underwear Bis (2,3-dibromopropyl) phosphate Not Detected Japan Japanese law for the control of household products containing harmful substances; Law no. 112, October 12, Partially amended in 1978 and 1981 Solvent extraction and analysis by GC-MS or LC-MS Tris (1-aziridinyl)-phosphine oxide (TEPA) Not Detected European Directive 76/769/EEC on restrictions on the marketing and use of certain dangerous substances and preparations. Directive 83/264/EEC KOH or NaOH Switzerland, digestion Turkey, Japan, and followed by GC- South Korea MS headspace analysis for ethyleneimine Decabromodiphenyl ether (DecaBDE) 0.1% by weight Sweden Swedish Legislation Page 11 AAFA RSL Final Release 3

12 METALS Restrictions for textiles Cadmium (Cd) 100 ppm Netherlands Cadmium Decree of the Netherlands Total Digestion UK If Cadmium is used as a coloring agent Lead (Pb) 100 ppm Denmark Danish statutory order no of November 13, 2000 on the Prohibition, Sale, Import, and Manufacture of Lead and Products Containing Lead Total Digestion Chromium (Cr+6) - hexavalent Not Detected (below detection limits - see test method) Germany German Food and Commodities Law 30 DIN 53314; C18 filtration and reanalysis of all positive results [limit is 3 ppm] BS EN420 CEN/TS Restrictions for Leather Cadmium (Cd) 100 ppm Netherlands Cadmium Decree of the Netherlands Lead (Pb) 100 ppm Denmark Danish statutory order no of November 13, 2000 on the Prohibition, Sale, Import, and Manufacture of Lead and Products Containing Lead Total Digestion UK If Cadmium is used as a coloring agent Total Digestion Chromium (Cr+6) - hexavalent Not Detected (below detection limits - see test method) Germany German Food and Commodities Law 30 DIN 53314; C18 filtration and reanalysis of all positive results (for leather) [limit is 3 ppm] BS EN420 CEN/TS Page 12 AAFA RSL Final Release 3

13 Restrictions for Metal Parts Lead (Pb) 100 ppm Denmark Danish statutory order no of November 13, 2000 on the Prohibition, Sale, Import, and Manufacture of Lead and Products Containing Lead Total Digestion Nickel (Ni) (in metal items) 0.5 µg/cm 2 /week European Directive 94/27/EC of the European Parliament: relating to restrictions on the marketing and use of certain dangerous substance and preparations and Directive 2004/96/EEC Nickel release by EN 1811 Abrasion of coated items by EN Restrictions for Plastics, Plastic Film, Surface Coatings and Printing Lead (Pb) 100 ppm Denmark Danish statutory order no of November 13, 2000 on the Prohibition, Sale, Import, and Manufacture of Lead and Products Containing Lead Total Digestion Cadmium (Cd) 100 ppm European Directive 91/338/EC EN 1122 (industry practice - not specified by the regulation) Page 13 AAFA RSL Final Release 3

14 Triphenyltin (TPhT) ORGANOTIN COMPOUNDS control of household products containing harmful substances (Law no. 112) Tributyltin (TBT) Not Detected Japan Japanese law for the Performance- TBT - South Korea (0.5 ppm EACH) based method of ethanol extraction derivitization and analysis by GC- MS or LC-MS ISO South Korea also regulates TBT for baby clothing (less than 24 months), for bedclothes, and products that come into skin contact Dibutyltin (DBT) 1 ppm South Korea Self Regulatory Confirmation Notice (Notice No ) issued by Korean Agency for Technology and Standards Applies to baby clothing only (less than 24 months). Page 14 AAFA RSL Final Release 3

15 Formaldehyde 0-36 months old MISCELLANEOUS CHEMICALS Not Detected (below detection limits - see test method) Japan Japanese Law 112 ISO or JIS L1041 (Law 112) or DIN [detection limit is 20 mg/kg] >36 months old (with direct skin contact) 75 ppm Japan Japanese Law 112 ISO or JIS L1041 (Law 112) or DIN [detection limit is 20 mg/kg] Poland, China, Russia, Finland, Norway, France, Netherlands, Austria, Lithuania, Germany, New Zealand, South Korea Poland defines baby products as 0-36 months, other countries including Japan, South Korea, and China define baby products as 0-24 months. South Korea also regulates bedclothes with a limit of of 300 ppm. >36 months old (no direct skin contact) 300 ppm See other countries ISO or JIS L1041 (Law 112) or DIN [detection limit is 20 mg/kg] Perflurooctane sulfomate (PFOS) 1 µg/m 2 European EU Directive 2006/122/EC amending for the thirtieth time 76/769/EEC Solvent Extraction LC-MS - (industry practice - not specified by the regulation) Canada The Canadian Environmental Protection Act, 1999 (CEPA 1999), Registration SOR 2008/178 prohibits the manufacture, use, sale, offer for sale and import of PFOS, as well as products containing PFOS, but does not specify limit. Phthalates Di(ethylhexyl) phthalate (DEHP) Di-n-octyl phthalate (DNOP) Butyl benzyl phthalate (BBP) Dibutyl phthalate (DBP) 0.1% South Korea Self Regulatory Confirmation Notice (Notice No ) issued by Korean Agency for Technology and Standards Applies to baby clothing (less than 24 months). Page 15 AAFA RSL Final Release 3