SAFETY DATA SHEET FIRST MARK ENZYMATIC DRAIN MAINTAINER

Transcription

1 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : Other means of identification : not applicable Recommended use : Drain Cleaner Restrictions on use : Reserved for industrial and professional use. Product dilution information :. % -.9 % Company : Performance Food Group 125 West Creek Parkway Richmond, Virginia USA Emergency telephone : Issuing date : 3/18/214 SECTION 2. HAZARDS IDENTIFICATION GHS Classification Skin irritation : Category 2 Eye irritation : Category 2A Not a hazardous substance or mixture. GHS Label element Hazard pictograms : Signal Word Hazard Statements Precautionary Statements Precautionary Statements : Warning : Causes skin irritation. Causes serious eye irritation. : Prevention: Wash skin thoroughly after handling. Wear eye protection/ face protection. Wear protective gloves. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/ attention. If eye irritation persists: Get medical advice/ attention. Take off contaminated clothing and wash before reuse. : Prevention: Wash hands thoroughly after handling / 1

2 Response: Get medical advice/ attention if you feel unwell. Storage: Store in accordance with local regulations. Other hazards : None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Pure substance/mixture : Mixture Chemical Name CAS-No. Concentration (%) benzenesulfonic acid, c1-16-alkyl derivs No hazardous ingredients SECTION 4. FIRST AID MEASURES In case of eye contact In case of skin contact If swallowed If inhaled Protection of first-aiders Notes to physician In case of eye contact In case of skin contact If swallowed If inhaled : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention. : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. : If potential for exposure exists refer to Section 8 for specific personal protective equipment. : Treat symptomatically. : Rinse with plenty of water. : Rinse with plenty of water. : Rinse mouth. Get medical attention if symptoms occur. : Get medical attention if symptoms occur. See toxicological information (Section 11) SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : None known / 1

3 Specific hazards during fire fighting Hazardous combustion products Special protective equipment for fire-fighters Specific extinguishing methods : Not flammable or combustible. : Carbon oxides : Use personal protective equipment. : Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up : Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. : Do not allow contact with soil, surface or ground water. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. : Refer to protective measures listed in sections 7 and 8. : No special environmental precautions required. : Stop leak if safe to do so. Contain spillage, and then collect with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. SECTION 7. HANDLING AND STORAGE Advice on safe handling Conditions for safe storage : Avoid contact with skin and eyes. Wash hands thoroughly after handling. Use only with adequate ventilation. : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. Storage temperature : C to 5 C Advice on safe handling : For personal protection see section 8. Wash hands after handling / 1

4 Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labeled containers. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Ingredients with workplace control parameters Contains no substances with occupational exposure limit values. Engineering measures : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection Hygiene measures Engineering measures : Safety glasses with side-shields : Wear the following personal protective equipment: Standard glove type. Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough. : No special protective equipment required. : No personal respiratory protective equipment normally required. : Remove and wash contaminated clothing before re-use. Wash hands before breaks and immediately after handling the product. Wash face, hands and any exposed skin thoroughly after handling. : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Personal protective equipment Eye protection Hand protection Skin protection Respiratory protection : No special protective equipment required. : No special protective equipment required. : No special protective equipment required. : No personal respiratory protective equipment normally required. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid liquid Color : clear, dark green green Odor : Floral Floral ph : , 1 % 7. Flash point : not applicable, Does not sustain combustion. Odor Threshold Melting point/freezing point Initial boiling point and : > 1 C / 1

5 boiling range Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapor pressure Relative vapor density Relative density : Water solubility Solubility in other solvents Partition coefficient: n- octanol/water Autoignition temperature Thermal decomposition Viscosity, kinematic Explosive properties Oxidizing properties Molecular weight VOC : soluble : The substance or mixture is not classified as oxidizing. SECTION 1. STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products : Stable under normal conditions. : No dangerous reaction known under conditions of normal use. : None known. : None known. : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure : Inhalation, Eye contact, Skin contact Potential Health Effects Eyes Skin Ingestion Inhalation : Causes serious eye irritation. : Causes skin irritation / 1

6 Chronic Exposure Eyes Skin Ingestion Inhalation Chronic Exposure Experience with human exposure Eye contact Skin contact Ingestion Inhalation Eye contact Skin contact Ingestion Inhalation : Redness, Pain, Irritation : Redness, Irritation Toxicity Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Carcinogenicity Reproductive effects Germ cell mutagenicity Teratogenicity STOT-single exposure STOT-repeated exposure Aspiration toxicity Ingredients : Skin irritation / 1

7 Acute oral toxicity Ingredients Acute inhalation toxicity : benzenesulfonic acid, c1-16-alkyl derivs. LD5 rat: 1,249 mg/kg : benzenesulfonic acid, c1-16-alkyl derivs. 4 h LC5 rat: > 1.9 mg/l SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Environmental Effects Product Toxicity to fish Toxicity to daphnia and other aquatic invertebrates Toxicity to algae Ingredients Toxicity to fish : This product has no known ecotoxicological effects. : benzenesulfonic acid, c1-16-alkyl derivs. 96 h LC5 Fish: 5.7 mg/l Persistence and degradability no data available Bioaccumulative potential no data available Mobility in soil no data available Other adverse effects no data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Disposal considerations Disposal methods Disposal considerations : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not reuse empty containers. : Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re / 1

8 SECTION 14. TRANSPORT INFORMATION use empty containers. The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport (DOT) Not dangerous goods Sea transport (IMDG/IMO) Not dangerous goods Not intended for transport. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 34 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 34 EHS RQ. SARA 311/312 Hazards SARA 32 SARA 313 : Acute Health Hazard : SARA 32: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 32. : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproductive defects. The ingredients of this product are reported in the following inventories: 197/26 (EU) : Switzerland. New notified substances and declared preparations : United States TSCA Inventory : On TSCA Inventory Canadian Domestic Substances List (DSL) : All components of this product are on the Canadian DSL / 1

9 Health Health Instability Instability SAFETY DATA SHEET Australia Inventory of Chemical Substances (AICS) : On the inventory, or in compliance with the inventory New Zealand. Inventory of Chemical Substances : Japan. ENCS - Existing and New Chemical Substances Inventory : Japan. ISHL - Inventory of Chemical Substances (METI) : Korea. Korean Existing Chemicals Inventory (KECI) : On the inventory, or in compliance with the inventory Philippines Inventory of Chemicals and Chemical Substances (PICCS) : China. Inventory of Existing Chemical Substances in China (IECSC) : SECTION 16. OTHER INFORMATION NFPA: Flammability HMIS III: HEALTH 2 2 FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic NFPA: Flammability HMIS III: HEALTH FLAMMABILITY PHYSICAL HAZARD Special hazard. = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic Issuing date : 3/18/214 Version : 1. Prepared by : Regulatory Affairs / 1

10 REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text / 1