SAFETY DATA SHEET. 1. Identification. 2. Hazard(s) identification. 3. Composition/information on ingredients. 4. First-aid measures

Transcription

1 SAFETY DATA SHEET 1. Identification Product identifier Other means of identification Recommended use Curing agent Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Company Name LATICRETE International Address 1 Laticrete Park, N Bethany, CT Telephone (203) Contact person Steve Fine Website Emergency phone number Call CHEMTREC day or night USA/Canada Mexico Outside USA/Canada Hazard(s) identification Physical hazards Health Hazards OSHA defined hazards Label elements Hazard symbol Signal word Hazard statement Precautionary statement Prevention Response Storage Disposal Hazard(s) not otherwise classified (HNOC) None. None. None. Observe good industrial hygiene practices. No specific first aid measures noted. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. None known. 3. Composition/information on ingredients Mixtures Chemical name Slack wax (petroleum) 1,2,4-Trimethylbenzene CAS number % Composition comments 4. First-aid measures Inhalation Skin contact Eye contact All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if any discomfort continues. Wash skin with soap and water. Get medical attention if symptoms occur. Flush eyes thoroughly with water for at least 15 minutes. Get medical attention if symptoms persist Version #: 01 Revision date: - Issue date: 01-October / 6

2 Ingestion Most important symptoms/effects, acute and delayed Indication of immediate medical attention and special treatment needed General information 5. Fire-fighting measures Suitable extinguishing media Unsuitable extinguishing media Specific hazards arising from the chemical Special protective equipment and precautions for firefighters Fire fighting equipment/instructions General fire hazards Rinse mouth. Do not induce vomiting. Get medical attention if any discomfort continues. Symptoms include redness, itching and pain. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Water fog. Dry chemical powder. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Methods and materials for containment and cleaning up Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Environmental precautions 7. Handling and storage Precautions for safe handling Conditions for safe storage, including any incompatibilities Never return spills in original containers for re-use. For waste disposal, see Section 13 of the SDS. Avoid release to the environment. Environmental manager must be informed of all major releases. Do not breathe mist or vapor. Do not get in eyes, on skin, on clothing. Do not handle until all safety precautions have been read and understood. Use with adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Keep container tightly closed. Store in a cool and well-ventilated place. 8. Exposure controls/personal protection Occupational exposure limits US. ACGIH Threshold Limit Values Type 1,2,4-Trimethylbenzene TWA (CAS ) US. NIOSH: Pocket Guide to Chemical Hazards Value 25 ppm 1,2,4-Trimethylbenzene (CAS ) Biological limit values Appropriate engineering controls Type Value TWA 125 mg/m3 25 ppm No biological exposure limits noted for the ingredient(s). Provide adequate ventilation and minimize the risk of inhalation of vapors Version #: 01 Revision date: - Issue date: 01-October / 6

3 Individual protection measures, such as personal protective equipment Eye/face protection Risk of contact: Wear approved safety glasses or goggles. Skin protection Hand protection Wear appropriate chemical resistant gloves. Rubber gloves are recommended. Other Wear appropriate chemical resistant clothing. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color White Odor Odor threshold ph 8 Melting point/freezing point Initial boiling point and boiling 212 F (100 C) range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Vapor pressure Vapor density Relative density Solubility(ies) Solubility (water) Soluble in water. Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products The product is stable and non-reactive under normal conditions of use, storage and transport. Material is stable under normal conditions. Will not occur. Heat, flames and sparks. Oxidizing agents. Carbon dioxide (CO2). Carbon monoxide. 11. Toxicological information Information on likely routes of exposure Inhalation In high concentrations, vapors may be irritating to the respiratory system Version #: 01 Revision date: - Issue date: 01-October / 6

4 Skin contact Eye contact Ingestion Symptoms related to the physical, chemical and toxicological characteristics May cause skin irritation. May cause eye irritation. May cause discomfort if swallowed. Symptoms include redness, itching and pain. Information on toxicological effects Acute toxicity May cause discomfort if swallowed. Species Acute Dermal LD50 Inhalation LC50 Rabbit Rat Oral LD50 Rat Slack wax (petroleum) (CAS ) Acute Dermal LD50 Rabbit Test Results > 3160 mg/kg mg/m3, 4 Hours 6000 mg/kg > 2000 mg/kg, 24 Hours Skin corrosion/irritation May cause skin irritation on prolonged or repeated contact. Serious eye damage/eye May cause eye irritation on direct contact. irritation Respiratory or skin sensitization Respiratory sensitization No data available. Skin sensitization Not a skin sensitizer. Germ cell mutagenicity No data available. Carcinogenicity OSHA Specifically Regulated Substances (29 CFR ) Reproductive toxicity No data available. Specific target organ toxicity - No data available. single exposure Specific target organ toxicity - No data available. repeated exposure Aspiration hazard Chronic effects Prolonged or repeated contact with skin may cause redness, itching, irritation, eczema/chapping and oil acne. Further information No other specific acute or chronic health impact noted. 12. Ecological information Ecotoxicity Aquatic Fish LC50 Persistence and degradability Bioaccumulative potential Mobility in soil Mobility in general The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Species Fathead minnow (Pimephales promelas) No data is available on the degradability of this product. No data available for this product. No data available. The product is soluble in water. Test Results mg/l, 96 hours Version #: 01 Revision date: - Issue date: 01-October / 6

5 Other adverse effects No data available. 13. Disposal considerations Disposal instructions Hazardous waste code Waste from residues / unused products Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Dispose of in accordance with local regulations. Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Not applicable. US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) OSHA Specifically Regulated Substances (29 CFR ) CERCLA Hazardous Substance List (40 CFR 302.4) Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance SARA 311/312 Hazardous No chemical SARA 313 (TRI reporting) Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR ) Safe Drinking Water Act (SDWA) US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List US. New Jersey Worker and Community Right-to-Know Act Version #: 01 Revision date: - Issue date: 01-October / 6

6 US. Pennsylvania Worker and Community Right-to-Know Law US. Rhode Island RTK US. California Proposition 65 US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance International Inventories Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) Canada Domestic Substances List (DSL) Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Europe European Inventory of Existing Commercial Chemical Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Korea Existing Chemicals List (ECL) New Zealand New Zealand Inventory Philippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "" indicates this product complies with the inventory requirements administered by the governing country(s). A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 01-October-2014 Revision date - Version # 01 NFPA ratings References Disclaimer HSDB - Hazardous Substances Data Bank Registry of Toxic Effects of Chemical Substances (RTECS) The information in this (M)SDS was obtained from sources which we believe are reliable but cannot guarantee. Additionally, your use of this information is beyond our control and may be beyond our knowledge. Therefore, the information is provided without any representation or warranty express or implied Version #: 01 Revision date: - Issue date: 01-October / 6