SAFETY DATA SHEET MANTLE

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1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number PHP003/ Relevant identified uses of the substance or mixture and uses advised against Identified uses Foliar micronutrient fertiliser 1.3. Details of the supplier of the safety data sheet Supplier Contact person Headland Amenity Ltd 1 Burr Elm Court Main Street Caldecote Cambridge Cambridgeshire CB23 7NU Tel. +44 (0) sds.enquiries@headlandamenity.com Wendy Johnson 1.4. Emergency telephone number Emergency telephone +44 (0) ( GMT Mon-Fri) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (EC 1272/2008) Physical hazards Not Classified Health hazards Environmental hazards Eye Dam. 1 - H318 STOT RE 2 - H373 Aquatic Chronic 2 - H Label elements Pictogram Signal word Hazard statements Danger H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure. H411 Toxic to aquatic life with long lasting effects. 1/8

2 Precautionary statements Contains P260 Do not breathe dust. P273 Avoid release to the environment. P280 Wear protective gloves, protective clothing and eye protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER/ doctor. P314 Get medical advice/ attention if you feel unwell. P391 Collect spillage. P501 Dispose of contents/ container in accordance with national regulations. MANGANESE SULPHATE, ZINC SULPHATE HEXAHYDRATE 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures MANGANESE SULPHATE 50-70% CAS number: EC number: Classification STOT RE 2 - H373 Aquatic Chronic 2 - H411 Classification (67/548/EEC or 1999/45/EC) Xn; R48/20/21/22. N; R51/53 ZINC SULPHATE HEXAHYDRATE 10-30% CAS number: EC number: M factor (Acute) = 1 M factor (Chronic) = 1 Classification Acute Tox. 4 - H302 Eye Dam. 1 - H318 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Ingestion Skin contact Eye contact Remove affected person from source of contamination. Get medical attention. Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attention. Remove contaminated clothing immediately and wash skin with soap and water. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Continue to rinse for at least 15 minutes Most important symptoms and effects, both acute and delayed Inhalation Ingestion Skin contact There may be irritation of the throat with a feeling of tightness in the chest. There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. Skin contact may cause redness and irritation. 2/8

3 Eye contact There may be pain and redness. Profuse watering of the eyes. May cause blurred vision and serious eye damage Indication of any immediate medical attention and special treatment needed Specific treatments Eye bathing equipment should be available on the premises. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Use fire-extinguishing media suitable for the surrounding environment. None known Special hazards arising from the substance or mixture Hazardous combustion products Toxic gases or vapours Advice for firefighters Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Avoid generation of dust. Treat the spilled material according to the instructions in the cleanup section. Wear protective clothing as described in Section 8 of this safety data sheet Environmental precautions Environmental precautions Avoid discharge into drains and the aquatic environment Methods and material for containment and cleaning up Methods for cleaning up Place waste in labelled, sealed containers Reference to other sections Reference to other sections For personal protection, see Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Advice on general occupational hygiene Avoid any direct contact with the substance. Provide adequate ventilation. Avoid generation and spreading of dust. Do not eat, drink or smoke when using this product. Wash hands thoroughly after handling. Promptly remove any clothing that becomes contaminated Conditions for safe storage, including any incompatibilities Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits MANGANESE SULPHATE 3/8

4 Long-term exposure limit (8-hour TWA): WEL 0.5 mg/m³ WEL = Workplace Exposure Limit respirable dust MANGANESE SULPHATE (CAS: ) DNEL PNEC Workers - Dermal; systemic effects: mg/kg/day Workers - Inhalation; systemic effects: 0.2 mg/m³ Consumer - Dermal; systemic effects: mg/kg/day Consumer - Inhalation; systemic effects: mg/m³ - Fresh water; mg/l - Marine water; mg/l - Sediment (Freshwater); mg/kg - Sediment (Marinewater); mg/kg - Soil; 25.1 mg/kg - STP; 56 mg/l ZINC SULPHATE HEXAHYDRATE (CAS: ) DNEL PNEC Workers - Inhalation; systemic effects: 1 mg/m³ Workers - Dermal; systemic effects: 8.3 mg/kg Consumer - Oral; systemic effects: 0.83 mg/kg Consumer - Dermal; systemic effects: 8.3 mg/kg - Fresh water; mg/l - Marine water; mg/l - Sediment (Freshwater); mg/kg - Sediment (Marinewater); 113 mg/kg - Soil; mg/kg - STP; mg/l 8.2. Exposure controls Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Respiratory protection Provide adequate ventilation. Wear tight-fitting, chemical splash goggles or face shield. Ensure eye bath is available. Wear protective gloves. Wear protective clothing. Self-contained breathing apparatus must be available in case of emergency. Respiratory protective device with particle filter. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour ph Melting point Initial boiling point and range Flash point Solid. Brown. 4/8

5 Evaporation rate Vapour pressure Relative density Solubility(ies) Partition coefficient Viscosity Oxidising properties Not known Other information Other information No other relevant information available. SECTION 10: Stability and reactivity Reactivity Reactivity Stable under recommended transport or storage conditions Chemical stability Stability Stable under normal conditions Possibility of hazardous reactions Possibility of hazardous reactions Under normal conditions of storage and use, no hazardous reactions will occur Conditions to avoid Conditions to avoid Avoid heat Incompatible materials Materials to avoid Strong oxidising agents. Strong acids Hazardous decomposition products Hazardous decomposition products In combustion emits toxic fumes. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity - oral ATE oral (mg/kg) 3, Inhalation Ingestion Skin contact Eye contact There may be irritation of the throat with a feeling of tightness in the chest. There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. There may be irritation and redness at the site of contact. There may be pain and redness. Profuse watering of the eyes. May cause blurred vision and serious eye damage. SECTION 12: Ecological Information Toxicity Persistence and degradability 5/8

6 Persistence and degradability The product is biodegradable Bioaccumulative potential Bioaccumulative potential Partition coefficient Bioaccumulation is unlikely Mobility in soil Results of PBT and vpvb assessment Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria Other adverse effects SECTION 13: Disposal considerations Waste treatment methods General information Disposal methods Dispose of waste product or used containers in accordance with local regulations Residues and empty containers should be taken care of as hazardous waste according to local and national provisions. Dispose of waste product or used containers in accordance with local regulations SECTION 14: Transport information UN number UN No. (ADR/RID) 3077 UN No. (IMDG) 3077 UN No. (ICAO) 3077 UN No. (ADN) UN proper shipping name Proper shipping name (ADR/RID) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS MANGANESE SULPHATE, ZINC SULPHATE HEXAHYDRATE) Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS MANGANESE SULPHATE, ZINC SULPHATE HEXAHYDRATE) Proper shipping name (ICAO) Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS MANGANESE SULPHATE, ZINC SULPHATE HEXAHYDRATE) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (CONTAINS MANGANESE SULPHATE, ZINC SULPHATE HEXAHYDRATE) Transport hazard class(es) ADR/RID class 9 ADR/RID classification code M7 ADR/RID label 9 IMDG class 9 ICAO class/division 9 ADN class 9 6/8

7 Transport labels Packing group ADR/RID packing group IMDG packing group ADN packing group ICAO packing group III III III III Environmental hazards Environmentally hazardous substance/marine pollutant Special precautions for user EmS F-A, S-F ADR transport category 3 Emergency Action Code Hazard Identification Number (ADR/RID) Tunnel restriction code 2Z 90 (E) Transport in bulk according to Annex II of MARPOL and the IBC Code Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU legislation Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures (as amended) Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Revision comments This is first issue. Revision date 01/11/2016 Revision 1 SDS number /8

8 Hazard statements in full H302 Harmful if swallowed. H318 Causes serious eye damage. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. 8/8