SAFETY DATA SHEET Glasses cleaner

Transcription

1 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Product name Product use Telephone No. Fax Country Cleaner Company/undertaking identification Manufacturer HG International b.v. Telephone No. +31 (0) Address Damsluisweg 70 Fax +31 (0) EJ Almere Internet Country Netherlands Importer HG UK Address Unit 11 Grange Way Business Park Whitehall Road Industrial Estate Uk Colchester Essex CO2 8HF United Kingdom (UK) Composition/information on ingredients Substance/preparation Preparation United Kingdom (UK) CAS number EC Number % Ethanol F; 11 Classification See section 16 for the full text of the R Phrases declared above * Occupational Exposure Limit(s), if available, are listed in Section 8 3. Hazards identification The preparation is not classified as dangerous according to Directive 1999/45/EC and its amendments. Classification Not classified. See section 11 for more detailed information on health effects and symptoms. 4. First aid measures First aid measures Ingestion Skin Contact Eye contact If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Obtain medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear. In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Clean shoes thoroughly before reuse. Obtain medical attention. In case of contact, immediately flush eyes with a copious amount of water for at least 15 minutes. Get medical attention if irritation occurs. Version Version 1 Page 1/6

2 Notes to physician Specific treatments This safety data sheet is prepared in accordance with EU See section 11 for more detailed information on health effects and symptoms. 5. Firefighting measures Extinguishing media Special exposure hazards Hazardous thermal decomposition products In case of fire, use water spray (fog), foam, dry chemical or CO2 extinguisher or spray. Combustible liquid and vapour. Vapour may cause flash fire. Vapours may accumulate in low or confined areas, travel a considerable distance to a source of ignition and flash back. Runoff to sewer may create fire or explosion hazard. These products are carbon oxides (CO, CO2) Special protective equipment for firefighters Fire fighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full facepiece operated in positive pressure mode. 6. Accidental release measures Personal Precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (Section 8). Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Methods for cleaning up If emergency personnel are unavailable, contain spilled material. For small spills add absorbent (soil may be used in the absence of other suitable materials) scoop up material and place in a sealed, liquidproof container for disposal. For large spills dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. Place spilled material in an appropriate container for disposal. Note see section 8 for personal protective equipment and section 13 for waste disposal. 7. Handling Storage Handling and storage Packaging materials Recommended Specific uses Wash thoroughly after handling. Keep container tightly closed. Keep container in a cool, wellventilated area. Use original container. 8. Exposure controls/personal protection United Kingdom (UK) Respiratory protection Occupational exposure limits Ethanol EH40WEL (United Kingdom (UK), 1/2005). TWA 1920 mg/m 3 8 hour(s). Form All forms TWA 1000 ppm 8 hour(s). Form All forms Exposure controls Occupational exposure controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapours below their respective occupational exposure limits. Ensure that eyewash stations and safety showers are close to the workstation location. A respirator is not needed under normal and intended conditions of product use. Version Version 1 Page 2/6

3 Hand protection Eye protection Chemicalresistant, impervious gloves or gauntlets complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. >8 hour(s) (breakthrough time) Butyl rubber gloves. safety glasses with side shields 9. Skin protection Work uniform or laboratory coat. Physical and chemical properties General information Appearance Physical state Colour Odour ph Flash point Flammability (solid, gas) Explosive properties Explosion Limits Oxidising properties Relative density Solubility Evaporation rate (butyl acetate = 1) Autoignition temperature Liquid. Clear Colourless. Characteristic. Important health, safety and environmental information Melting point Boiling point Other information 10. Stability and reactivity Stability Conditions to Avoid Materials to avoid Hazardous Decomposition Products (Conc. (% w/w) 100) [Basic.] May start to solidify at 0 C (32 F) based on data for Water. Weighted average 2.9 C (26.8 F) The lowest known value is 78 C (172.4 F) (Ethanol). Weighted average C (211 F) Closed cup Between 61 C (142 F) and 93.3 C (200 F). (PenskyMartens.) Not applicable. The greatest known range is Lower 3.4% Upper 19% (Ethanol) g/cm3 (20 C / 68 F) Easily soluble in hot water. Soluble in cold water. 1.7 (Ethanol) compared to Butyl acetate. The lowest known value is 370 C (698 F) (Ethanol). The product is stable. Stable under recommended storage and handling conditions (see section 7). Keep away from heat, sparks and flame. Keep away from sources of ignition. Reactive with acids. Toxicological information These products are carbon oxides (CO, CO2) Potential acute health effects Ingestion Skin Contact Eye contact Version Version 1 Page 3/6

4 Acute toxicity Ethanol Test Result Route Species LDLo LDLo LC mg/kg 3450 mg/kg 6300 mg/kg 15.8 mg/kg 1400 mg/kg 5500 mg/kg 64 (4 hour(s)) Dermal Rat Mouse Rabbit Rabbit human Dog Rat Carcinogenicity Mutagenicity Reproductive toxicity Overexposure signs/symptoms Ingestion Skin Target organs Contains material which causes damage to the following organs blood, the reproductive system, liver, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea. 12. Other adverse effects Ecological information Ecotoxicity data Ethanol Other adverse effects 13. Disposal considerations Species Period Result Daphnia magna (EC50) Daphnia magna (EC50) Daphnia magna (EC50) Pimephales promelas (LC50) Daphnia magna (LC50) Oncorhynchus mykiss (LC50) 48 hour(s) 48 hour(s) 48 hour(s) 96 hour(s) 96 hour(s) 96 hour(s) 2 mg/l 9.3 mg/l >100 mg/l >100 mg/l >100 mg/l mg/l Methods of disposal Waste classification Hazardous waste The generation of waste should be avoided or minimised wherever possible. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Not applicable. To present knowledge of the supplier, this product is not regarded as hazardous waste as defined by EU Directive 91/689/EC. Version Version 1 Page 4/6

5 14. Transport information International transport regulations Regulatory information ADR/RID Class UN number Proper shipping name Class Packing group Label Additional Information Not regulated. ADN Class Not regulated. IMDG Class Not regulated. IATADGR Class Not regulated. 15. Regulatory information EU Regulations 16. Risk Phrases Safety Phrases Other EU regulations Product use Additional warning phrases EC Statistical classification (Tariff Code) Ingredients identification information Other information This product is not classified according to the EU regulations. S2 Keep out of the reach of children. S46 If swallowed, seek medical advice immediately and show this container or label. nonionic surfactants, anionic surfactants Safety data sheet available for professional user on request. Classification and labelling have been performed according to EU directives 67/548/EEC, 1999/45/EC, including amendments and the intended use. Consumer applications less than 5% anionic surfactants.,nonionic surfactants Full text of R phrases referred to in sections 2 and 3 United Kingdom (UK) Full text of classifications referred to in sections 2 and 3 United Kingdom (UK) History Date of printing Version Verified by T. Rutgers. Notice to reader R11 Highly flammable. F Highly flammable Version Version 1 Page 5/6

6 To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Version 1 Page 6/6