Safety Data Sheet Copper-Glycinate Revision date : 2016/05/10 Page: 1/10

Transcription

1 Revision date : 2016/05/10 Page: 1/10 1. Identification Product identifier used on the label Recommended use of the chemical and restriction on use Recommended use*: feed additive(s) * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Synonyms: Bis(glycinato)copper 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Acute Tox. 4 (oral) Acute toxicity Skin Corr./Irrit. 2 Skin corrosion/irritation Eye Dam./Irrit. 2A Serious eye damage/eye irritation Aquatic Acute 1 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic Label elements Pictogram:

2 Revision date : 2016/05/10 Page: 2/10 Signal Word: Warning Hazard Statement: H319 H315 H302 H412 H400 Causes serious eye irritation. Causes skin irritation. Harmful if swallowed. Harmful to aquatic life with long lasting effects. Very toxic to aquatic life. Precautionary Statements (Prevention): P280 Wear protective gloves and eye/face protection. P273 Avoid release to the environment. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P303 + P352 IF ON SKIN (or hair): Wash with plenty of soap and water. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P332 + P313 If skin irritation occurs: Get medical advice/attention. P391 Collect spillage. P337 + P311 If eye irritation persists: Call a POISON CENTER or doctor/physician. P362 + P364 Take off contaminated clothing and wash it before reuse. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vpvb (very persistent/very bioaccumulative) criteria. Labeling of special preparations (GHS): The following percentage of the mixture consists of components(s) with unknown hazards regarding the acute toxicity: 6 % 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name % Sulfuric acid copper(2+) salt (1:1) % Copper, bis(glycinato-.kappa.n,.kappa.o)-

3 Revision date : 2016/05/10 Page: 3/10 4. First-Aid Measures Description of first aid measures General advice: Remove contaminated clothing. If inhaled: Keep patient calm, remove to fresh air, seek medical attention. If on skin: Wash thoroughly with soap and water. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Immediately rinse mouth and then drink ml of water, seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: Further important symptoms and effects are so far not known., The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, foam, dry powder, carbon dioxide Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Hazards during fire-fighting: harmful vapours, carbon oxides Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Burning produces harmful and toxic fumes. Advice for fire-fighters Protective equipment for fire-fighting: Wear self-contained breathing apparatus and chemical-protective clothing.

4 Revision date : 2016/05/10 Page: 4/10 Further information: Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. Cool endangered containers with water-spray. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Information regarding personal protective measures see, section 8. Avoid dust formation. Ensure adequate ventilation. Do not breathe dust. Avoid contact with the skin, eyes and clothing. Environmental precautions Do not discharge into drains/surface waters/groundwater. Inform authorities in the event of product spillage to water courses or sewage systems. Methods and material for containment and cleaning up For large amounts: Sweep/shovel up. Collect waste in suitable containers, which can be labeled and sealed. For residues: Sweep/shovel up. Dispose of absorbed material in accordance with regulations. Avoid raising dust. Cleaning operations should be carried out only while wearing breathing apparatus. 7. Handling and Storage Precautions for safe handling Ensure thorough ventilation of stores and work areas. Wear suitable protective clothing and eye/face protection. Avoid contact with the skin, eyes and clothing. Keep container tightly sealed. Protection against fire and explosion: Take precautionary measures against static discharges. Avoid all sources of ignition: heat, sparks, open flame. Conditions for safe storage, including any incompatibilities Suitable materials for containers: Paper/Fibreboard, High density polyethylene (HDPE), Low density polyethylene (LDPE), Polypropylene (PP) Further information on storage conditions: Keep container tightly closed and dry; store in a cool place. Keep only in the original container. 8. Exposure Controls/Personal Protection Components with occupational exposure limits Sulfuric acid copper(2+) salt (1:1) ACGIH TLV TWA value 1 mg/m3 Dust and mist (copper (Cu)); TWA value 0.2 mg/m3 fumes/smoke (copper (Cu)); Copper, bis(glycinato-.kappa.n,.kappa.o)- ACGIH TLV TWA value 0.2 mg/m3 fumes/smoke (copper (Cu)); TWA value 1 mg/m3 Dust and mist (copper (Cu));

5 Revision date : 2016/05/10 Page: 5/10 Personal protective equipment Respiratory protection: Breathing protection if dusts are formed. Wear a NIOSH-certified (or equivalent) respirator as necessary. Hand protection: Wear chemical resistant protective gloves. Eye protection: Wear safety goggles (chemical goggles) if there is potential for airborne dust exposures. Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with skin. Avoid contact with eyes. No eating, drinking, smoking or tobacco use at the place of work. Hands and/or face should be washed before breaks and at the end of the shift. Store work clothing separately. 9. Physical and Chemical Properties Form: free flowing, Microgranule (MG) Odour: odourless Odour threshold: not applicable, odour not perceivable Colour: bluish ph value: 3-5 ( 10 %(m)) decomposition point: approx. 200 C Boiling point: dropped Flash point: not applicable, the product is a solid Flammability: not highly flammable (UN Test N.1 (ready combustible solids)) Lower explosion limit: For solids not relevant for classification and labelling. Upper explosion limit: For solids not relevant for classification and labelling. Vapour pressure: negligible Density: No data available. Bulk density: 800-1,100 kg/m3 Vapour density: not applicable Partitioning coefficient n- not applicable for mixtures octanol/water (log Pow): Self-ignition temperature: Based on its structural properties the product is not classified as selfigniting. Thermal decomposition: (SADT, Test H.4, ) Not a substance liable to self-decomposition according to UN transport regulations, class 4.1. Viscosity, dynamic: Solubility in water: Molar mass: not applicable, the product is a solid ( 20 C) soluble g/mol

6 Revision date : 2016/05/10 Page: 6/10 Evaporation rate: 10. Stability and Reactivity negligible Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: No data available. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Minimum ignition energy: The product is not capable of a dust explosion. Chemical stability The product is stable if stored and handled as prescribed/indicated. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated. Conditions to avoid See MSDS section 7 - Handling and storage. Incompatible materials None known during use and storage if used according to instructions. Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: (SADT, Test H.4, ) Not a substance liable to self-decomposition according to UN transport regulations, class Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Of moderate toxicity after single ingestion. Virtually nontoxic after a single skin contact. Oral Type of value: LD50 Species: rat

7 Revision date : 2016/05/10 Page: 7/10 Value: 482 mg/kg (similar to OECD guideline 401) The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Dermal Type of value: LD50 Species: rat Value: > 2,000 mg/kg No mortality was observed. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Assessment other acute effects Based on available Data, the classification criteria are not met. Irritation / corrosion Assessment of irritating effects: Irritating to eyes and skin. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Sensitization Assessment of sensitization: Skin sensitizing effects were not observed in animal studies. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Aspiration Hazard No aspiration hazard expected. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The substance may cause damage to the kidney after repeated ingestion of high doses, as shown in animal studies. The substance may cause damage to the liver after repeated ingestion of high doses, as shown in animal studies. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Genetic toxicity Assessment of mutagenicity: Most of the results from the available studies show no evidence of a mutagenic effect. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Carcinogenicity Assessment of carcinogenicity: No data available. Reproductive toxicity Assessment of reproduction toxicity: The results of animal studies gave no indication of a fertility impairing effect. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Teratogenicity Assessment of teratogenicity: Causes developmental effects in animals at high, maternally toxic doses. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition. Other Information Based on our experience and the information available, no adverse health effects are expected if handled as recommended with suitable precautions for designated uses. The product has not been tested. The statements on toxicology have been derived from the properties of the individual components.

8 Revision date : 2016/05/10 Page: 8/10 Symptoms of Exposure Further important symptoms and effects are so far not known., The most important known symptoms and effects are described in the labelling (see section 2) and/or in section Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Depending on local conditions and existing concentrations, disturbances in the biodegradation process of activated sludge are possible. Harmful to aquatic life with long lasting effects. Very toxic to aquatic life. Toxicity to fish LC50 (96 h) mg/l, Oncorhynchus mykiss (OECD Guideline 203) Analogous: Assessment derived from products with similar chemical character. Aquatic invertebrates EC50 (48 h) mg/l, Ceriodaphnia dubia Analogous: Assessment derived from products with similar chemical character. Aquatic plants EC50 (72 h) mg/l (growth rate), Pseudokirchneriella subcapitata (OECD Guideline 201) Analogous: Assessment derived from products with similar chemical character. Persistence and degradability Assessment biodegradation and elimination (H2O) Information on: Copper, bis(glycinato-.kappa.n,.kappa.o)- Inorganic product which cannot be eliminated from water by biological purification processes. The organic component of the product is biodegradable. The product has not been tested. The statement has been derived from the structure of the product. Information on: Sulfuric acid copper(2+) salt (1:1) Not applicable for inorganic substances. Inorganic product which cannot be eliminated from water by biological purification processes Assessment of stability in water According to structural properties, hydrolysis is not expected/probable. Bioaccumulative potential Assessment bioaccumulation potential Significant accumulation in organisms is not to be expected. Assessment bioaccumulation potential Information on: Copper, bis(glycinato-.kappa.n,.kappa.o)-

9 Revision date : 2016/05/10 Page: 9/10 Significant accumulation in organisms is not to be expected. The product has not been tested. The statement has been derived from the structure of the product. Information on: Sulfuric acid copper(2+) salt (1:1) Based on a weight of evidence, the compound will not bioaccumulate Mobility in soil Assessment transport between environmental compartments not determined Information on: Sulfuric acid copper(2+) salt (1:1) No data available. Adsorption to solid soil phase is possible Additional information Other ecotoxicological advice: The product has not been tested. The statements on ecotoxicology have been derived from the structure of the product. 13. Disposal considerations Waste disposal of substance: Observe national and local legal requirements. Container disposal: Dispose of in accordance with national, state and local regulations. 14. Transport Information Land transport TDG Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BIS(GLYCINATO)COPPER) Sea transport IMDG Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Marine pollutant: YES Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.

10 Revision date : 2016/05/10 Page: 10/10 (contains BIS(GLYCINATO)COPPER) Air transport IATA/ICAO Hazard class: 9 Packing group: III ID number: UN 3077 Hazard label: 9, EHSM Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BIS(GLYCINATO)COPPER) 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released; restriction on quantity / not listed Feed DSL, CA released; restriction on quantity / not listed Assessment of the hazard classes according to UN GHS criteria (most recent version): Aquatic Acute 1 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic Acute Tox. 4 (oral) Acute toxicity Skin Corr./Irrit. 2 Skin corrosion/irritation Eye Dam./Irrit. 2A Serious eye damage/eye irritation 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2016/05/10 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. Attention - The product has not yet been fully tested. END OF DATA SHEET