SAFETY DATA SHEET BUD1208, BUDENE 1208

Transcription

1 SAFETY DATA SHEET SDS No. G0063B EU / EN BUD1208, BUDENE 1208 Effective Date 05/15/2006 Revision: 05/17/ IDENTIFICATION of the SUBSTANCE and COMPANY Trade Name BUD1208, BUDENE 1208 Chemical Name Synonym(s): Polybutadiene PBD Miscellaneous Information: Company Identification The Goodyear Tire & Rubber Company Akron, Ohio U.S.A. Goodyear Canada, Inc. Etobicoke, Ontario M8Z 5E1 Canada Emergency Phone Numbers Chemical Transportation Emergency Assistance, CHEMTREC (USA) (Canada) MSDS Information ISSUED BY - Global Chemical Material Management - Akron, Ohio Technical Assistance HAZARDS IDENTIFICATION EC Classification Designation This substance is classified as dangerous according to Council Directive 67/548/EEC. Emergency Overview If ignited by excessive heat or open flame, this product will burn. During fire conditions fumes are irritating to eyes and respiratory tract. APPEARANCE: Amber solid ODOR: Rubber Potential Health Effects --- PRIMARY ROUTES OF ENTRY --- Dermal Contact - Inhalation --- SHORT-TERM EXPOSURE --- Vapors generated during processing may be irritating to the eyes, skin or respiratory system. --- LONG-TERM EXPOSURE --- None known for product as produced. Page 1 of 5

2 3. COMPOSITION / INFORMATION on the COMPONENTS Chemical Name Polybutadiene. Synonym(s): PBD Product Description: Polymer Non-hazardous information Chemical name Percentage by wt. CAS-No EC Number EU Classification 1,3-Butadiene, homopolymer NE Regulatory CAS Notes: REACH Registration Number(s): (1,3 butadiene) 4. FIRST AID MEASURES Eye Contact For fumes generated during high heat procedures: For irritation, flush eyes with copious amounts of water. If irritation persists, seek medical attention. Skin Contact Wash with soap and water. Inhalation For fumes generated during high heat procedures: If overcome by exposure, remove victim to fresh air. Ingestion Seek immediate medical attention. 5. FIRE-FIGHTING MEASURES --- EXTINGUISHING MEDIA --- Water, all purpose (ABC) dry chemical, CO2, foam --- SPECIAL INTERVENTION METHODS --- During emergency conditions, overexposure to thermal decomposition products may cause a health hazard. An approved, self-contained breathing apparatus should be worn. --- SPECIAL EXPOSURE HAZARDS --- Not easily ignited. However, when ignited, and particularly in bulk storage, a hot and difficult to control fire may develop. This material emits acrid smoke and fumes when burning. 6. ACCIDENTAL RELEASE MEASURES ---AFTER SPILLAGE/LEAKAGE --- (methods for cleaning up) Wear personal protective equipment. Prevent spill from entering sanitary sewers and waterways. Place in closed container for recycle or disposal. 7. HANDLING and STORAGE --- PRECAUTIONS --- Keep away from excessive heat and open flame. --- HANDLING --- Avoid eye contact. Avoid skin contact. Avoid inhalation. --- STORAGE --- Store in a cool dry place away from excessive heat or open flame. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Page 2 of 5

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION --- VENTILATION PROTECTION --- When this material is heated, provide enough fresh air and/or exhaust to remove the hot processing vapors from the work area. Observe the Occupational Exposure Limit of 3 mg/m3 (Threshold Limit Value - 8 hour time weighted average) for insoluble respirable particulates, not otherwise classified. --- RESPIRATION PROTECTION --- Under normal conditions of use, respiratory protection should not be required. --- SKIN PROTECTION --- Employees who have prolonged contact with this material should practice good personal hygiene by frequent washing of hands and arms with soap and water. --- EYE PROTECTION --- Safety glasses --- PROTECTIVE GLOVES --- Heavy cotton or impervious if practical. --- OTHER PROTECTION --- Practice good personal hygiene. 9. PHYSICAL and CHEMICAL PROPERTIES APPEARANCE: Amber solid ODOR: Rubber ph FLASH POINT and METHOD FLAMMABLE LIMITS LEL UEL THERMAL DECOMPOSITION AUTO-IGNITION TEMP INITIAL BOILING POINT MELT POINT SPECIFIC GRAVITY 0.91 SOLUBILITY IN WATER Insoluble 10. STABILITY and REACTIVITY --- CONDITIONS TO AVOID --- Material is stable. --- MATERIALS TO AVOID --- If nitrosating agents (i.e. NOx) are present during processing nitrosamines may be formed. Nitrosamines are animal carcinogens. --- HAZARDOUS DECOMPOSITION PRODUCTS --- Carbon monoxide, Carbon dioxide. 11. TOXICOLOGY INFORMATION ORAL LD50 DERMAL LD50 INHALATION LC ECOLOGICAL INFORMATION Page 3 of 5

4 G0063B - BUD1208, BUDENE 1208 Revision: 05/17/ ECOLOGICAL INFORMATION Component Information: Data for components given below. --- OTHER --- This product has not been tested for ecological (physical and/or biological) hazards or the data is not available or not known. 13. DISPOSAL CONSIDERATIONS --- DISPOSAL --- Incinerate or landfill in accordance with applicable environmental control regulations. Recycle if possible. 14. TRANSPORTATION INFORMATION Hazard Class - Not classified. No labelling required according to current transport legislation. 15. REGULATORY INFORMATION EC Classification Designation This substance is classified as dangerous according to Council Directive 67/548/EEC. ---EC LABELLING--- No labelling required according to criteria of European Directive 67/548/EEC and its subsequent amendments. --- INTERNATIONAL --- EINECS TSCA CANADIAN (DSL) AICS ENCS KECL PICCS CHINA New Zealand One or more ingredients are not on EINECS Page 4 of 5

5 16. OTHER INFORMATION / ADDITIONAL COMMENTS Revision: 05/17/2012 Revision summary The SDS has been updated to meet the requirements stipulated in commission regulation (EU) 453/2010. Goodyear believes that the information herein is correct at the date that this Material Safety Data Sheet was prepared. The data may not be exhaustive and should only be used as a guide to determine the best conditions for the safe use of the product. Goodyear is not responsible for any injury or liability resulting from misuse of this product. --- END of DOCUMENT --- Page 5 of 5