SAFETY DATA SHEET PROTECTON WASH/WAX CAR SHAMPOO

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product number PSW100, PSW Relevant identified uses of the substance or mixture and uses advised against Identified uses Auto shampoo Details of the supplier of the safety data sheet Supplier Manufacturer TETROSYL LIMITED Bury Lancashire England BL9 7NY TETROSYL LIMITED Bury Lancashire England BL9 7NY Emergency telephone number Emergency telephone +44 (0) SECTION 2: Hazards identification 2.1. of the substance or mixture (EC 1272/2008) Physical hazards Not Classified Health hazards Environmental hazards Eye Irrit. 2 - H319 Aquatic Chronic 3 - H412 Human health See Section 11 for additional information on health hazards Label elements 1/9

2 Pictogram Signal word Hazard statements Precautionary statements Detergent labelling Warning H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects. P264 Wash contaminated skin thoroughly after handling. P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice/ attention. P501 Dispose of contents/ container in accordance with national regulations. P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. 5 - < 15% anionic surfactants, < 5% non-ionic surfactants, < 5% perfumes, Contains Benzisothiazolinone, 2-METHYLISOTHIAZOL-3(2H)-ONE 2.3. Other hazards As supplied, the material does not present a health hazard. SECTION 3: Composition/information on ingredients 3.2. Mixtures AMIDES, C8-C18(EVEN NUMBERED) AND C18(UNSATD.), N,N-BIS(HYDROXYETHYL) 2.5-<5.0% CAS number: EC number: REACH registration number: Aquatic Chronic 2 - H411 BENZENESULFONIC ACID, 4-C10-13-SEC-ALKYL DERIVS., COMPDS. WITH TRIETHANOLAMINE 2.5-<5.0% CAS number: REACH registration number: /9

3 ALCOHOLS, C12-14, ETHOXYLATED, SULFATES, SODIUM SALTS 2.5-<5.0% CAS number: EC number: REACH registration number: Aquatic Chronic 3 - H412 DIETHANOLAMINE 0.5-<1% CAS number: EC number: Acute Tox. 4 - H302 STOT RE 2 - H373 AMINES, C12-14 (EVEN NUMBERED) -ALKYLDIMETHYL, N-OXIDES 0.3-<0.5% CAS number: EC number: REACH registration number: 01- M factor (Acute) = Acute Tox. 4 - H302 Aquatic Acute 1 - H400 Aquatic Chronic 2 - H411 GLYCERINE 0.1-<0.3% CAS number: EC number: Not Classified DIPHENYL OXIDE <0.1% CAS number: EC number: Eye Irrit. 2 - H319 Aquatic Chronic 2 - H411 3/9

4 SODIUM HYDROXIDE <0.1% CAS number: EC number: REACH registration number: Met. Corr. 1 - H290 Skin Corr. 1A - H314 The full text for all hazard statements is displayed in Section 16. Composition comments No classified ingredients, or those having occupational exposure limits, present above the levels of disclosure. SECTION 4: First aid measures 4.1. Description of first aid measures General information Inhalation Ingestion Skin contact Eye contact Get medical attention if any discomfort continues. Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. Effects may be delayed. Keep affected person under observation. Unlikely route of exposure as the product does not contain volatile substances. Get medical attention if any discomfort continues. Rinse mouth thoroughly with water. Give plenty of water to drink. Rinse immediately with plenty of water. Remove contaminated clothing. Get medical attention if any discomfort continues. Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Do not rub eye. Get medical attention if any discomfort continues Most important symptoms and effects, both acute and delayed General information Inhalation Ingestion Skin contact Eye contact The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Effects may be delayed. Keep affected person under observation. No specific symptoms known. May cause discomfort if swallowed. May cause stomach pain or vomiting. Prolonged contact may cause redness, irritation and dry skin. May cause temporary eye irritation Indication of any immediate medical attention and special treatment needed Notes for the doctor No specific recommendations. If in doubt, get medical attention promptly. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Use fire-extinguishing media suitable for the surrounding fire. Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Specific hazards Not relevant. No unusual fire or explosion hazards noted. 4/9

5 Hazardous combustion products No known hazardous decomposition products Advice for firefighters Protective actions during firefighting Special protective equipment for firefighters No specific firefighting precautions known. Leave danger zone immediately. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions For personal protection, see Section 8. In case of spills, beware of slippery floors and surfaces Environmental precautions Environmental precautions Avoid discharge to the aquatic environment Methods and material for containment and cleaning up Methods for cleaning up No specific clean-up procedure recommended Reference to other sections Reference to other sections Collect and dispose of spillage as indicated in Section 13. For personal protection, see Section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Read and follow manufacturer's recommendations. Good personal hygiene procedures should be implemented. Wash hands and any other contaminated areas of the body with soap and water before leaving the work site. Avoid contact with eyes. Avoid eating, drinking and smoking when using the product Conditions for safe storage, including any incompatibilities Storage precautions Keep containers upright. Store in tightly-closed, original container Specific end use(s) Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits No exposure limits known for ingredient(s). DIETHANOLAMINE Long-term exposure limit (8-hour TWA): OES 3 ppm 15 mg/m³ Short-term exposure limit (15-minute): OES GLYCERINE Long-term exposure limit (8-hour TWA): WEL 10 mg/m³ DIPHENYL OXIDE mist Long-term exposure limit (8-hour TWA): WEL 1 ppm 7.1 mg/m³ vapour SODIUM HYDROXIDE 5/9

6 Short-term exposure limit (15-minute): WEL 2 mg/m³ WEL = Workplace Exposure Limit 8.2. Exposure controls Protective equipment Appropriate engineering controls Eye/face protection Hand protection Other skin and body protection Hygiene measures Respiratory protection No specific ventilation requirements. This product must not be handled in a confined space without adequate ventilation. Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. Unless the assessment indicates a higher degree of protection is required, the following protection should be worn: Tight-fitting safety glasses. Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. Wear suitable protective clothing as protection against splashing or contamination. Use engineering controls to reduce air contamination to permissible exposure level. Respiratory protection not required. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colour Odour Odour threshold Creamy liquid. Cream. Perfume. ph ph (concentrated solution): Melting point Initial boiling point and range Flash point Evaporation rate Upper/lower flammability or explosive limits Vapour pressure Vapour density >100 >100 C Relative density 20 C Solubility(ies) Partition coefficient Auto-ignition temperature Decomposition Temperature Soluble in water. 6/9

7 Viscosity C Oxidising properties 9.2. Other information Other information None. Volatility 16% - 18% SECTION 10: Stability and reactivity Reactivity Reactivity There are no known reactivity hazards associated with this product Chemical stability Stability No particular stability concerns Possibility of hazardous reactions Possibility of hazardous reactions Conditions to avoid Conditions to avoid Not relevant Incompatible materials Materials to avoid No specific material or group of materials is likely to react with the product to produce a hazardous situation Hazardous decomposition products Hazardous decomposition products Does not decompose when used and stored as recommended. SECTION 11: Toxicological information Information on toxicological effects Toxicological effects No information available. Inhalation Ingestion Skin contact Eye contact Acute and chronic health hazards No specific health hazards known. May cause discomfort if swallowed. Prolonged and frequent contact may cause redness and irritation. Causes serious eye irritation. Because of the product's quantity and composition, the health hazard is regarded as low. SECTION 12: Ecological Information Ecotoxicity Harmful to aquatic life with long lasting effects Toxicity Acute toxicity - fish Acute toxicity - aquatic invertebrates Not available. Not available. 7/9

8 12.2. Persistence and degradability Persistence and degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential Partition coefficient No data available on bioaccumulation Mobility in soil Adsorption/desorption coefficient Not available Results of PBT and vpvb assessment Results of PBT and vpvb assessment This substance is not classified as PBT or vpvb according to current EU criteria Other adverse effects Other adverse effects Not available. SECTION 13: Disposal considerations Waste treatment methods General information Disposal methods When handling waste, the safety precautions applying to handling of the product should be considered. Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. Absorb in vermiculite, dry sand or earth and place into containers. Dispose of waste via a licensed waste disposal contractor. SECTION 14: Transport information General The product is not covered by international regulations on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN number UN proper shipping name Transport hazard class(es) No transport warning sign required Packing group Environmental hazards Environmentally hazardous substance/marine pollutant No Special precautions for user Transport in bulk according to Annex II of MARPOL and the IBC Code 8/9

9 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations Surfactantul (surfactanţii) din acest preparat corespunde (corespund) criteriilor de biodegradabilitate din Regulamentul (CE) nr. 648/2004 privind detergenţii. Date în sprijinul acestei afirmaţii se află la dispoziţia autorităţilor abilitate ale statelor membre şi pot fi puse la dispoziţie la cererea lor expresă sau la solicitarea unui producător de detergenţi. EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) (as amended) Chemical safety assessment No chemical safety assessment has been carried out. SECTION 16: Other information Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision. Revision date 06/06/2016 Revision 2 Supersedes date 28/09/2015 SDS number SDS status Hazard statements in full Approved. H290 May be corrosive to metals. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. The information provided in this document has been compiled on the basis of our current knowledge and is believed to be in accordance with the requirements of the Dangerous Substances Directive, Dangerous Preparations Directive and Safety Data Sheets Directive. The information relates to the specific material designated and may not be valid for such material used in combination with any other materials or in any particular conditions or process. The conditions and extent of storage and use of material are outside of our control and within the control of the possessor or user. Consequently it is the responsibility of the possessor or user to satisfy themselves as to the completeness of such information and the suitability of the material for their own particular circumstances, conditions or use. 9/9