SAFETY DATA SHEET. Creation Date 11-Feb-2010 Revision Date 16-Jul-2014 Revision Number Identification

Transcription

1 SAFETY DATA SHEET Creation Date 11-Feb-2010 Revision Number 1 Product Name 1. Identification Magnesium carbonate Cat. : M26-3; M27-212; M Synonyms Recommended Use Magnesite.; Carbonic acid magnesium salt; Carbonate magnesium (Powder/Laboratory/USP/FCC) Laboratory chemicals. Uses advised against Information available Details of the supplier of the safety data sheet Company Fisher Scientific One Reagent Lane Fair Lawn, NJ Tel: (201) Emergency Telephone Number CHEMTREC, Inside the USA: CHEMTREC, Outside the USA: Hazard(s) identification Classification Classification under 2012 OSHA Hazard Communication Standard (29 CFR ) Based on available data, the classification criteria are not met Label Elements ne required Hazards not otherwise classified (HNOC) ne identified Unknown Acute Toxicity.? % of the mixture consists of ingredients of unknown toxicity. 3. Composition / information on ingredients Component CAS- Weight % Magnesium carbonate >95 Page 1 / 6

2 4. First-aid measures Eye Contact Skin Contact Inhalation Ingestion Most important symptoms/effects tes to Physician Suitable Extinguishing Media Unsuitable Extinguishing Media Flash Point Method - Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Obtain medical attention. Wash off immediately with plenty of water for at least 15 minutes. Get medical attention immediately if symptoms occur. Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. Do not induce vomiting. Obtain medical attention.. Treat symptomatically 5. Fire-fighting measures Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Autoignition Temperature Explosion Limits Upper data available Lower data available Sensitivity to Mechanical Impact Sensitivity to Static Discharge Specific Hazards Arising from the Chemical Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Carbon monoxide (CO) Carbon dioxide (CO2) Magnesium oxides Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health 1 Flammability 0 Instability 0 Physical hazards N/A Personal Precautions Environmental Precautions 6. Accidental release measures Ensure adequate ventilation. Use personal protective equipment. Avoid dust formation. Should not be released into the environment. Methods for Containment and Clean Sweep up or vacuum up spillage and collect in suitable container for disposal. Avoid dust Up formation. Handling Storage 7. Handling and storage Wear personal protective equipment. Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Avoid ingestion and inhalation. Avoid dust formation. Keep containers tightly closed in a dry, cool and well-ventilated place. Page 2 / 6

3 Exposure Guidelines 8. Exposure controls / personal protection This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Engineering Measures Personal Protective Equipment Eye/face Protection Skin and body protection Respiratory Protection Hygiene Measures Ensure that eyewash stations and safety showers are close to the workstation location. Ensure adequate ventilation, especially in confined areas. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR or European Standard EN166. Wear appropriate protective gloves and clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Handle in accordance with good industrial hygiene and safety practice. 9. Physical and chemical properties Physical State Solid Appearance White Odor Odorless Odor Threshold ph Melting Point/Range 350 C / 662 F Boiling Point/Range Flash Point Evaporation Rate Flammability (solid,gas) Flammability or explosive limits Upper data available Lower data available Vapor Pressure Vapor Density Relative Density Solubility Insoluble in water Partition coefficient; n-octanol/water data available Autoignition Temperature Decomposition temperature Viscosity Molecular Formula C Mg O3 Molecular Weight Stability and reactivity Reactive Hazard Stability Conditions to Avoid Incompatible Materials ne known, based on information available Stable under normal conditions. Incompatible products. Excess heat. Avoid dust formation. Strong oxidizing agents Hazardous Decomposition Products Carbon monoxide (CO), Carbon dioxide (CO2), Magnesium oxides Hazardous Polymerization Hazardous Reactions Hazardous polymerization does not occur. ne under normal processing. Page 3 / 6

4 Acute Toxicity 11. Toxicological information Product Information acute toxicity information is available for this product Oral LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Dermal LD50 Based on ATE data, the classification criteria are not met. ATE > 2000 mg/kg. Mist LC50 Based on ATE data, the classification criteria are not met. ATE > 5 mg/l. Component Information Toxicologically Synergistic Products Delayed and immediate effects as well as chronic effects from short and long-term exposure Irritation Sensitization Carcinogenicity May cause irritation The table below indicates whether each agency has listed any ingredient as a carcinogen. Component CAS- IARC NTP ACGIH OSHA Mexico Magnesium carbonate t listed t listed t listed t listed t listed Mutagenic Effects Reproductive Effects Developmental Effects Teratogenicity STOT - single exposure STOT - repeated exposure Aspiration hazard Symptoms / effects, both acute and delayed Endocrine Disruptor Information Other Adverse Effects Ecotoxicity Do not empty into drains. Persistence and Degradability Bioaccumulation/ Accumulation Mobility Waste Disposal Methods DOT... ne known ne known See actual entry in RTECS for complete information. The toxicological properties have not been fully investigated. 12. Ecological information Disposal considerations Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. Chemical waste generators must also consult local, regional, and national hazardous waste regulations to ensure complete and accurate classification. 14. Transport information t regulated Page 4 / 6

5 TDG IATA IMDG/IMO t regulated t regulated t regulated 15. Regulatory information International Inventories Component TSCA DSL NDSL EINECS ELINCS NLP PICCS ENCS AICS IECSC KECL Magnesium carbonate X - X X - Legend: X - Listed E - Indicates a substance that is the subject of a Section 5(e) Consent order under TSCA. F - Indicates a substance that is the subject of a Section 5(f) Rule under TSCA. N - Indicates a polymeric substance containing no free-radical initiator in its inventory name but is considered to cover the designated polymer made with any free-radical initiator regardless of the amount used. P - Indicates a commenced PMN substance R - Indicates a substance that is the subject of a Section 6 risk management rule under TSCA. S - Indicates a substance that is identified in a proposed or final Significant New Use Rule T - Indicates a substance that is the subject of a Section 4 test rule under TSCA. XU - Indicates a substance exempt from reporting under the Inventory Update Rule, i.e. Partial Updating of the TSCA Inventory Data Base Production and Site Reports (40 CFR 710(B). Y1 - Indicates an exempt polymer that has a number-average molecular weight of 1,000 or greater. Y2 - Indicates an exempt polymer that is a polyester and is made only from reactants included in a specified list of low concern reactants that comprises one of the eligibility criteria for the exemption rule. U.S. Federal Regulations TSCA 12(b) SARA 313 SARA 311/312 Hazardous Categorization Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act Clean Air Act OSHA Occupational Safety and Health Administration CERCLA California Proposition 65 State Right-to-Know This product does not contain any Proposition 65 chemicals U.S. Department of Transportation Reportable Quantity (RQ): DOT Marine Pollutant DOT Severe Marine Pollutant N N N U.S. Department of Homeland Security This product does not contain any DHS chemicals. Other International Regulations Page 5 / 6

6 Mexico - Grade Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR WHMIS Hazard Class Prepared By Creation Date Revision Date Print Date Revision Summary n-controlled 16. Other information Regulatory Affairs Thermo Fisher Scientific EMSDS.RA@thermofisher.com 11-Feb Jul Jul-2014 This document has been updated to comply with the US OSHA HazCom 2012 Standard replacing the current legislation under 29 CFR to align with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS) Disclaimer The information provided on this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of SDS Page 6 / 6