HIGH STRENGTH THREADLOCKER STICK 268 MSDS-No. : V001.4 Revision: printing date:

Transcription

1 Safety Data Sheet Page 1 of 6 HIGH STRENGTH THREADLOCKER STICK 268 MSDS-No. : Revision: printing date: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: HIGH STRENGTH THREADLOCKER STICK 268 Identification of manufacturer, importer or distributor Importer: Henkel Malaysia Sdn Bhd 46th Floor, Menara TM, Jalan Pantai Baharu, Kuala Lumpur, Malaysia. Phone : Fax : address of person responsible for Safety Data Sheet: ap-ua-psra.sea@henkel.com Section 2. Composition / information on ingredients General chemical description: Threadlocker Stick Declaration of ingredients: EINECS content Classification Polyamide wax~ 1-10 % R53 N,N-dimethyl-o-toluidine ,1-1 % T - Toxic; R23 Xn - Harmful; R21/22, R48/20/22 C - Corrosive; R34 O - Oxidizing; R7 N - Dangerous for the environment; R51/ ,1-1 % Toxic for reproduction - category 2.; R61 Xi - Irritant; R36/37/ ,1-1 % T - Toxic; R23/24/25 R33 R52/ ,1-1 % R10 Xn - Harmful; R65 Xi - Irritant; R37 N - Dangerous for the environment; R51/53 Section 3. Hazards identification Hazard classification: Not required according to the regulations. Section 4. First aid measures Inhalation: Skin contact: Move to fresh air. If symptoms persist, seek medical advice. Rinse with running water and soap. Obtain medical attention if irritation persists.

2 Eye contact: Ingestion: HIGH STRENGTH THREADLOCKER STICK 268 Page 2 of 6 Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Section 5. Fire fighting measures Suitable extinguishing media: Special protection equipment for firefighters: Particular danger/case of fire: Carbon dioxide, foam, powder Fine water spray Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. In case of fire, keep containers cool with water spray. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid skin and eye contact. Ensure adequate ventilation. Waste disposal with the approval of the responsible local authority. For small spills wipe up with paper towel and place in container for disposal. Section 7. Handling and storage Handling: Storage: Use only in well-ventilated areas. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided Ensure good ventilation/extraction. Store in a cool, well-ventilated place. Section 8. controls / personal protection Components with specific control parameters for workplace: Ingredient Type ppm mg/m 3 Remarks CUMENE Time Weighted Average 50 ACGIH (TWA): CUMENE Time Weighted Average MY OEL (TWA): CUMENE Skin designation: MY OEL Can be absorbed through the skin.

3 Respiratory protection: HIGH STRENGTH THREADLOCKER STICK 268 Page 3 of 6 Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Wear protective glasses. Wear suitable protective clothing. Hygienic measures: Good industrial hygiene practices should be observed. Do not eat, drink or smoke while working. Wash hands before work breaks and after finishing work. Section 9. Physical and chemical properties Appearance: red wax, solid material Odor: Mild Specific gravity: 1,0687 ph: not applicable Boiling point: > 149 C (> F) Flash point: Not applicable Vapor pressure: < 6,67 mbar (; 20 C (68 F)) Density: 1,07 g/cm3 Solubility: Solvent: Water, Slight Solvent: Acetone, Not applicable VOC content < 3 % (1999/13/EC) Section 10. Stability and reactivity Conditions to avoid: Materials to avoid: Stable under recommended storage conditions. No decomposition if used according to specifications. Strong oxidizing agents. Hazardous decomposition products: carbon oxides. Section 11. Toxicological information Inhalative toxicity: Skin irritation: May cause irritation to respiratory system. Prolonged or repeated contact may cause skin irritation.

4 Eye irritation: HIGH STRENGTH THREADLOCKER STICK 268 Page 4 of 6 Prolonged or repeated contact may cause eye irritation. toxicity: Polyamide wax~ Value type Value Route of application Species oralinhalationder mal LD mg/kg oral rat LD50 LC50 LD mg/kg > 5,1 mg/l mg/kg oral inhalation dermal 4 h rat rat rabbit BASF Test OECD Guideline 403 ( Inhalation Toxicity) Skin corrosion/irritation: Result Species corrosive rabbit Draize Test moderately irritating human slightly irritating rabbit BASF Test Serious eye damage/irritation: Result Species irritating rabbit BASF Test Germ cell mutagenicity: Repeated dose toxicity Mobility: Result Type of study / Route of administration positive bacterial reverse mutation assay (e.g Ames test) Metabolic activation / without Species negative dermal mouse Result Route of application / Species Frequency of treatment 6 h/d 5 d/w rat inhalation: aerosol NOAEL=0,5 mg/l inhalation 90 days 6 hrs/day, 5 days/wk rat Section 12. Ecological information Cured adhesives are immobile. OECD Guideline 471 (Bacterial Reverse Mutation Assay) OECD Guideline 413 (Subchronic Inhalation Toxicity: 90-Day) General ecological information: Ecotoxicity: In the cured state contribution of this product to Environmental Hazards is insignificant in comparison to articles in which it is used. Do not empty into drains / surface water / ground water.

5 HIGH STRENGTH THREADLOCKER STICK 268 Page 5 of 6 Toxicity: Value type Value Toxicity Study Species LC50 3,9 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Toxicity EC50 18 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation ErC50 3,1 mg/l Algae 72 h Pseudokirchnerella subcapitata OECD Guideline 201 (Alga, Growth Inhibition LC mg/l Fish 96 h Leuciscus idus DIN EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC50 > 500 mg/l Algae 72 h Scenedesmus subspicatus (new DIN name: Desmodesmus subspicatus) LC50 4,8 mg/l Fish 96 h Oncorhynchus mykiss OECD Guideline 203 (Fish, Toxicity EC50 4 mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Immobilisation EC50 2,6 mg/l Algae 72 h Selenastrum capricornutum (new name: Pseudokirchnerella subcapitata) OECD Guideline 201 (Alga, Growth Inhibition Persistence and degradability: Result Route of Degradability application Polyamide wax~ no data 24 % OECD 301 A - F no data 0 % OECD Guideline 301 B (Ready Biodegradability: CO2 Evolution aerobic 92 % OECD Guideline 301 C (Ready Biodegradability: Modified MITI Test (I)) aerobic 86 % ISO (BODIS- Bioaccumulative potential / Mobility in soil: LogKow Bioconcentration factor (BCF) Species Temperature

6 HIGH STRENGTH THREADLOCKER STICK 268 Page 6 of 6 Polyamide wax~ > 6,5 22 C OECD Guideline 117 (Partition Coefficient (noctanol / water), HPLC ) 2,16-0,11 9,1 calculation OECD Guideline 305 (Bioconcentration: Flowthrough Fish 35,5 Carassius auratus OECD Guideline 305 (Bioconcentration: Flowthrough Fish 3,55 23 C OECD Guideline 107 (Partition Coefficient (noctanol / water), Shake Flask ) Section 13. Disposal considerations Product of disposal: Packaging Disposal for uncleaned package: Dispose of in accordance with local and national regulations. Contribution of this product to waste is very insignificant in comparison to article in which it is used After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Disposal must be made according to official regulations. Section 14. Transport information General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR. Section 15. Regulations - classification and identification Indication of danger: Not required according to the regulations. Global inventory status: Regulatory list TSCA AICS DSL KECI (KR) PICCS (PH) IECSC Notification Section 16. Other information Issue date: Disclaimer This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties. This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and Commission Directive 1999/45/EC.