SAFETY DATA SHEET Cleanrange Anti-Bacterial Hand Wipes Tub

Transcription

1 Cleanrange Anti-Bacterial Hand Wipes Tub Page 1 of 7 SAFETY DATA SHEET Cleanrange Anti-Bacterial Hand Wipes Tub SDS according to Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), Annex II-EU SECTION 1: Identification of the substance/mixture and of the company/undertaking Date issued Product identifier Product name Article no. Cleanrange Anti-Bacterial Hand Wipes Tub Relevant identified uses of the substance or mixture and uses advised against Use of the substance/preparation Alcohol-based disinfectant. Relevant identified uses Uses advised against 1.3. Details of the supplier of the safety data sheet Distributor Company name Kleinmann GmbH Postal address Am Trieb 13 Postcode D City Sonnenbuehl Country Germany Tel +49(0)7128/ Fax +49(0)7128/ chemie@kleinmann.net Website Enterprise no. DE Emergency telephone number Emergency telephone 8-12, Mo.-Fr.:+49(0)7128/ SU0-2 Other activities related to manufacture and services SU22 Professional uses: publicly accessible (administration, education, entertainment, services, craftsmen) PC39 Cosmetics, personal care products PROC10 Roller application or brushing ERC8A Wide dispersive indoor use of processing aids in open systems ERC8D Wide dispersive outdoor use of processing aids in open systems No specific uses advised against are identified. SECTION 2: Hazards identification 2.1. Classification of substance or mixture Substance / mixture hazardous properties 2.2. Label elements Hazard statements 2.3. Other hazards Environmental effects The product is not classified. EUH 210 Safety data sheet available on request. Not Classified as PBT/vPvB by current EU criteria.

2 Cleanrange Anti-Bacterial Hand Wipes Tub Page 2 of 7 SECTION 3: Composition/information on ingredients 3.2. Mixtures Substance Identification Classification Contents Ethanol CAS no.: Flam. Liq. 2; H % EC no.: Index no.: Synonyms: Ethanol Polyhexamethylenbiguanid CAS no.: Acute tox. 4;H302; Eye Dam. 1;H318; Carc. 2;H351; Skin Sens. 1;H317; STOT RE1;H372; Aquatic Acute 1;H400; Aquatic Chronic 1;H410; < 0,5 % Substance comments The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures General Remove affected person from source of contamination. Inhalation Fresh air. Skin contact The product is intended for skin contact. Eye contact Rinse with water. Contact physician if discomfort continues. Ingestion Drink a few glasses of water or milk. Call a POISON CENTER or doctor/physician if you feel unwell Most important symptoms and effects, both acute and delayed Delayed symptoms and effects No known long term effects Indication of any immediate medical attention and special treatment needed If unconscious: Call an ambulance/physician immediately. Show this Safety Data Sheet. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire and explosion hazards Use fire-extinguishing media appropriate for surrounding materials. This product is not flammable. During fire, gases hazardous to health may be formed Advice for firefighters Personal protective equipment Wear necessary protective equipment. For personal protection, see section 8. Fire fighting procedures Containers close to fire should be removed or cooled with water. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal protection measures Avoid contact with eyes Environmental precautions Environmental precautionary measures Avoid discharge into drains, water courses or onto the ground. Contact local authorities in case of spillage to drain/aquatic environment Methods and material for containment and cleaning up Cleaning method Dam and absorb spillage with sand, sawdust or other absorbent. Flush area with water.

3 Cleanrange Anti-Bacterial Hand Wipes Tub Page 3 of Reference to other sections Other instructions See section 8 and section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Handling No specific usage precautions noted Conditions for safe storage, including any incompatibilities Storage Conditions for safe storage Storage Stabilit Durability: 36 months Specific end use(s) Store in a well-ventilated place. Keep container tightly closed. Store above freezing. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational Exposure limit values Substance Identification Value TWA Year Ethanol CAS no.: EC no.: Index no.: Synonyms: Ethanol Polyhexamethylenbiguanid CAS no.: DNEL / PNEC Summary of risk management measures, human Summary of risk management measures, environment Data lacking. Data lacking Exposure controls Recommended monitoring No recommendation given. procedures Precautionary measures to prevent exposure Appropriate engineering controls No recommendation given. Respiratory protection Respiratory protection Hand protection Hand protection Eye / face protection Eye protection No recommendation given. 8-hour TWA: 1000 ppm 8-hour TWA: 1920 mg/m Under normal conditions of use respiration protection should not be required. Under normal conditions of use gloves are not normally required. Eye protection is not required under normal conditions. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid. Colour Clear Odour Characteristic., ph (as supplied), ph (aqueous solution), Melting point / melting range

4 Cleanrange Anti-Bacterial Hand Wipes Tub Page 4 of 7, Boiling point / boiling range, Flash point, Evaporation rate, Explosion limit, Vapour pressure, Vapour density, Specific gravity, Bulk density Solubility description, Partition coefficient: n- octanol / water, Spontaneous combustability, Decomposition temperature, Viscosity Explosive properties Oxidising properties 9.2. Other information Completely soluble in water. Not explosive. Does not meet the criteria for oxidising. SECTION 10: Stability and reactivity Reactivity Reactivity Chemical stability Stability Possibility of hazardous reactions Possibility of hazardous reactions See section 10.4 and section Conditions to avoid Conditions to avoid No data recorded Incompatible materials Materials to avoid Not determined Hazardous decomposition products Hazardous decomposition products During fire, toxic gases (CO, CO2, NOx) are formed. SECTION 11: Toxicological information Information on toxicological effects Toxicological Information: Other toxicological data Toxicological data for substances Substance Polyhexamethylenbiguanid LC50 inhalation Value: 10-<20 mg/l Respiratory or skin sensitisation Result: Sensitising. Other information regarding health hazards General Irritating to eyes. Potential acute effects Inhalation Skin contact Eye contact Ingestion There are no known reactivity hazards associated with this product. Stable under normal temperature conditions and recommended use. Toxicological tests on the product has not been performed. No specific health warnings noted. Skin irritation is not anticipated when used normally. May cause temporary eye irritation. Ingestion of large quantities may cause stomach ache, nausea and diarrhoea.

5 Cleanrange Anti-Bacterial Hand Wipes Tub Page 5 of 7 SECTION 12: Ecological information Toxicity Aquatic, comments No data recorded. Toxicological data for substances Substance Polyhexamethylenbiguanid Acute aquatic, fish Value: 0,026 mg/l Method of testing: LC50 Species: Oncorhynchus mykiss Duration: 96 h Acute aquatic, algae Value: 0,0191 mg/l Method of testing: ErC50, OECD TG 201 Species: Pseudokirchneriella subcapitata Duration: 72 h Acute aquatic, Daphnia Value: 0,09 mg/l Method of testing: EC50, OECD TG 202 Species: Daphnia magna Duration: 48 h Aquatic, comments EC50: 0,01-0,1 mg/l. M-faktor=10. Mobility, description Mobility, description: The product is partly miscible with water and may spread in the aquatic environment. Persistence and degradability The product is not readily biodegradable. Biodegradability Value: 13,5% Test period: 28d Method of testing: OECD 301D Bioaccumulation Accumulates in soil and sediment. Result of PBT assessment for the Not Classified as PBT/vPvB by current EU criteria. substance Persistence and degradability Persistence and degradability The product is easily biodegradable Bioaccumulative potential Bioaccumulative potential Bioaccumulation: Is not expected to be bioaccumulable Mobility in soil Mobility The product contains substances, which are water soluble and may spread in water systems Results of PBT and vpvb assessment PBT assessment results Not Classified as PBT/vPvB by current EU criteria Other adverse effects Environmental details, summation SECTION 13: Disposal considerations Waste treatment methods Specify the appropriate methods of disposal Product classified as hazardous waste Packaging classified as hazardous waste EWC waste code For this product no classification is required for environmental hazards. Do not empty into drains; dispose of this material and its container at hazardous or special waste collection point. Dispose of waste and residues in accordance with local authority requirements. No No EWC: 0706 wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics Waste code applies to product remnants in pure form. When handling waste,

6 Cleanrange Anti-Bacterial Hand Wipes Tub Page 6 of 7 SECTION 14: Transport information UN number consideration should be made to the safety precautions applying to handling of the product. The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID) UN proper shipping name Transport hazard class(es) Packing group Environmental hazards Special precautions for user Special safety precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Additional information. Additional information. The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA, ADR/RID). SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Legislation and regulations Chemical safety assessment Chemical safety assessment performed EH40/2005, Workplace exposure limits 2005, with amendments. The List of Wastes (England) (Amendment) Regulations (SI 2005 No. 895). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. The Cosmetic Products (Safety) Regulations 2003 (S.I 2003 No. 835). REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. REGULATION (EC) No 648/2004 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 31 March 2004 on detergents. No SECTION 16: Other information List of relevant H-phrases (Section 2 and 3). H318 Causes Serious eye damage. H302 Harmful if swallowed. H400 Very toxic to aquatic life. H317 May cause an allergic skin reaction. H351 Suspected of causing cancer

7 Cleanrange Anti-Bacterial Hand Wipes Tub Page 7 of 7 Training advice Information which has been added, deleted or revised Version 1 Responsible for safety data sheet Kleinmann GmbH Prepared by ALM H225 Highly flammable liquid and vapour. H410 Very toxic to aquatic life with long lasting effects. H372 Causes damage to organs through prolonged or repeated exposure No particular training or education is required but the user must be familiar with this SDS. New safety data sheet.