Scaling Up CO 2 Capture Technologies for Commercial Use. ICEF 5 th Annual Meeting Tokyo, Japan October 11, 2018

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1 Scaling Up CO 2 Capture Technologies for Commercial Use ICEF 5 th Annual Meeting Tokyo, Japan October 11, 2018

2 World Largest Post Combustion CO 2 Capture Project: Petra Nova in Texas (4,776 Metric Ton CO 2 /D) January 2017 Owner s PR: NRG Energy, JX Nippon complete world s largest post-combustion carbon capture facility on-budget and on-schedule NRG press release:

3 MHI s KM CDR Process Basic Concepts Proprietary amine and equipment Low energy consumption Low solvent consumption Enlarge the scale with compact equipment COMPRESSION and DEHYDRASION KM CDR Process is a registered trademark of Mitsubishi Heavy Industries, Ltd., in Japan, the United States of America, European Union (CTM), Norway, Australia, and China. 3

4 KM CDR Process Worldwide Commercial Experience MHI s experienced CO 2 utilizations are not only CO 2 EOR but also Urea, Methanol Synthesis and general use Plants in operation Plants under construction Bahrain 450 Mt/d for Urea 2010 UAE 400 Mt/d for Urea & Boiler Russia 1250 Mt/d for Urea India (Aonla) 450 Mt/d for Urea 2006 India (Phulpur) 450 Mt/d for Urea Japan 283 Mt/d for General Use U.S.A (WA Parish) 4,776 Mt/d for EOR Coal Boiler 2014 Qatar 500 Mt/d for MeOH Japan 330 Mt/d General Use Oil / NG Boiler Pakistan 340 Mt/d for Urea 2009 India (Kakinada) 450 Mt/d for Urea Vietnam 240 Mt/d for Urea 1999 Malaysia 210 Mt/d for Urea 2012 India (Vijaipur) 450 Mt/d for Urea 4

5 MHI s KM CDR Process - R&D History Solvent Screening and Laboratory Testing (1990 Present) The first flue gas CO 2 capture R&D in the world aiming for Global Warming Mitigation. More than 200 solvents tested The Kansai Electric Power Co. Nanko Power Station Testing (1991 Present) > 20 solvents tested in 2 tpd pilot unit Downselected to KS-1 formulation for commercial projects 14,000 hours of direct testing to date MHI Hiroshima R&D Center ( ) Extensive testing in MHI s R&D center Facility includes coal boiler, AQCS, and 1 tpd CO 2 capture system Evaluated effects of coal PM, SOx, NOx, metals, and aerosols on solvent and process Facility currently being relocated to MHI Nagasaki R&D center J-Power Matsushima Station (2006) More than 6,000 hours of testing with 10 tpd CO 2 capture pilot plant from slip stream of 500 MW utility coal boiler Demonstrated long-term performance of solvent and process counter measures to coal fired flue gas impurities Plant Barry, Alabama Large Scale Demo ( ) Next slides 5

6 Large-Scale Coal Demonstration Project at Plant Barry (25MWeq) Proved technical performance of CCS on coal flue gas through joint demo. Funding for capture system from Southern Company, MHI and EPRI. CO 2 storage was part of Phase III: Anthropogenic CO 2 Injection into Aquifer Tests by SECARB. Designed to capture 500 metric tons per day of CO 2 at 90% capture efficiency. From : over 12,000 hours, over 250,000 metric tons captured, over 125,000 metric tons injected Verified Long-term Performance of KM CDR Process on Coal-fired Power Plants Confirmed constructability and operational performance of rectangular absorber design Confirmed utilities consumption and CO 2 product quality Confirmed VOC emissions and solvent consumption Confirmed long-term stable system operation Verified system performance under various flue gas conditions, coal characteristics, etc. 6

7 Plant Barry Demonstration, Con t Verified Process Improvements Energy Saving System Deployed and verified an optimized system for reduced steam consumption Automatic Load Adjustment System and Minimize Energy Consumption Automatic Load Adjustment System Deployed and verified dynamic response simulator and automatic control system for load following Amine Purification System Verified performance of reclaiming and automatic filtration operation to remove coal combustion impurities from solvent (a) Manual operation (b) Control system (CO 2 production control mode) Automatic system control including solvent circulation and steam use depending on plant load, flue gas condition, and CO 2 demand Minimize energy consumption by automatic optimization Allows rapid response to changing system conditions and turndown to 50% 7

8 Petra Nova Project: Overview The world s largest CO 2 capture plant on coal-fired flue gas has been under commercial operation since December Plant location NRG WA Parish Power Plant (Thompsons, TX) Absorber Project owner Plant scale CO 2 capacity CO 2 conc. Petra Nova partnership between NRG Energy and JX Nippon Oil & Gas 240 MW eq 4,776 TPD (1.4 MMtonne/year) 11.5 mol%-wet CO₂ Compressor Cooling Tower Regenerator CO 2 removal 90% CO 2 Used for CO 2 -EOR Pipeline 12 in diameter, ~81 miles Flue Gas Quencher Injection Site West Ranch Oil Field Flue Gas Duct *U.S. Department of Energy W.A. Parish Post-Combustion CO2 Capture and Sequestration Project Final Environmental Impact Statement Volume I (Feb, 2013), DOE/EIS

9 Petra Nova Project: Heat and power integration No modification is needed for coal fired power plant. Coal-fired boiler Electricity sale Flue gas CO 2 Capture CO 2 CO 2 Comp. & Dehydration Oil field CO 2 Pipeline Oil production Electricity Electricity Steam NGCC Electricity sale Natural gas 9

10 Petra Nova Project: Construction Quencher and Absorber Construction Rectangular steel towers and modular construction Speedy and flexible Construction method Module lift up Laydown area Transportation CCS Area BOP Area 10

11 Petra Nova Project: CO 2 for EOR CO 2 Captured for Enhanced Oil Recovery (EOR) (Owner s scope) Compressed CO 2 is delivered by 81 mile CO 2 pipeline to the West Ranch oil field. Up to 1.4 million metric ton of CO 2 is annually injected into the West Ranch oil field. 11

12 Development of a Utility-Scale CO 2 Capture System Full-scale utility CO 2 capture is now available with KM CDR Process Full Scale 5,000 TPD (Petra Nova Project etc.) Pilot 2 TPD Scale Small Scale Demonstration 10 TPD Scale Large Scale Demonstration 500 TPD Know-how and Lesson learned from commercial plants Contactor Test Mihara 36 L x 18 W x 105 H Simulators (CFD etc.) Large Scale experiences for FGD Large amount of flue gas >200 commercial plants CO2 Recovery (CDR) Plant IFFCO Aonla Unit (India) CO2 Recovery (CDR) Plant IFFCO Phulpur Unit (India) 12

13 Technical Key Massages 5,000 Metric Ton / D CO 2 capture Plant is available with commercial basis. MHI continue the efforts to reduce CO 2 capture costs. 99% CO 2 capture can be technically achieved. Biomass fired (or Coal Co Fired) plants with CCS is the only the practical solution for negative CO 2 emission. Therefore coal fired plants have to be left for future purposes. 13

14 Political Key Massages Incentives such as US Section 45Q tax credit are essential for commercial implementation of CCUS. CO 2 pipeline infrastructure prepared by Governmental sector will give great flexibility for both sellers and buyers of CO 2. Government support of reduced carbon energy products (i.e. oil production with CO 2 EOR, CO 2 free fuel (ammonia), low carbon electricity) with premiums or incentives. 14

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